1.
Acta Crystallogr B Struct Sci Cryst Eng Mater
; 79(Pt 6): 432-436, 2023 Dec 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-37811771
RESUMEN
Tetrakis-4-(4-pyridyl)phenylmethane (TPPM) is a tetrahedral rigid molecule that crystallizes forming a dynamically responsive supramolecular organic framework (SOF). When exposed to different stimuli, this supramolecular network can reversibly switch from an empty to a filled solvated solid phase. This article describes a novel expanded form of a TPPM-based SOF that has been mechanochemically synthesized and whose crystal structure has been determined by 3D electron diffraction analysis using a novel electron diffractometer.