RESUMEN
Nitrate-induced spallation of lead-bearing solder particles into drinking water is not sufficiently controlled by phosphate-based inhibitors, although adding zinc can improve their performance. Studies using copper coupons coated with new lead-tin solder in water with up to 12 mg/L nitrate demonstrated that zinc orthophosphate reduced lead release by more than 90% and outperformed orthophosphate alone. Lead release and spallation from harvested pipes with decades-old lead-tin solder in a high nitrate water were improved but not eliminated with zinc orthophosphate over a period of months. When applied at a water utility with high source water nitrate, monthly in-home field sampling showed that 90th percentile lead levels dropped below the action level after dosing zinc orthophosphate at full scale for 6 months. Scanning electron microscopy (SEM) analysis of pipe scales revealed that zinc and orthophosphate codeposit at the copper-solder interface and may act as a mixed inhibitor, with zinc inhibiting the cathodic reaction on the copper pipe, phosphate limiting the anodic reaction, and an added benefit of zinc orthophosphate preferentially precipitating at the galvanic interface between the anode and the cathode. Updates to corrosion control guidance for waters with higher nitrate due to seasonal runoff or source water changes are needed.
RESUMEN
After a utility switched its source water from ground to surface water in 2017, first draw water lead levels spiked due to increased lead solder corrosion that could not be explained by existing knowledge. When lead release was not adequately reduced with a 90:10 orthophosphate/polyphosphate corrosion inhibitor blend or even high levels of 100% orthophosphate, an in-depth investigation of possible causes revealed a strong correlation between 90th percentile lead and seasonal fluctuations in surface water nitrate levels. Complementary bench-scale studies that tested new copper coupons with lead solder and harvested pipes from a worst case home verified a strong relationship between nitrate and elevated lead. Lead release in the presence of nitrate became increasingly erratic with time, resulting in the spalling of large lead solder particulates up to 7 mm in length into the water. Lead levels were occasionally >1000 ppb in homes and >100000 ppb in the bench experiments with harvested pipe. Orthophosphate was unable to sufficiently reduce lead levels below the action level during periods with high nitrate levels in the bench studies. Water utilities and regulators should proactively consider possible unintended consequences of higher nitrate levels on lead release when changing source waters or during seasonal runoff events.