Retention and dispersion of buoyant plastic debris in a well-mixed estuary from drifter observations.

Buoyant plastics enter estuaries largely from urban streams and an unknown fraction is retained before further transport to the open ocean. Plastic drifters were launched in a well-mixed estuary to simulate the movement of surface buoyant plastics. Two experiments were conducted, one during spring tides and one during neap tides, both with similar river flows and winds. Stronger tidal currents during spring tides resulted in larger dispersion and further downstream transport of the drifters. Half of the drifters were grounded within two tidal cycles. During the neap experiment, even more of the drifters (87%) were retained in the estuary. The grounding of such a high proportion of drifters suggests that much of the plastic pollution in estuaries of this type remains close to the riverine source. These findings imply that local clean-up programs removing grounded litter can reduce over half of the plastic pollution input to these estuaries.

Autonomous optimisation of a nanoparticle catalysed reduction reaction in continuous flow.

An automated continuous flow reactor system equipped with inline analysis, was developed and applied in the self-optimisation of a nanoparticle catalysed reaction. The system was used to optimise the experimental conditions of a gold nanoparticle catalysed 4-nitrophenol reduction reaction, towards maximum conversion in under 2.5 hours. The data obtained from this optimisation was then used to generate a kinetic model, allowing us to predict the outcome of the reaction under different conditions. By combining continuous flow nanoparticle synthesis with this approach, the development timeline for these emerging catalysts could be significantly accelerated.

Direct Synthesis of Multiplexed Metal-Nanowire-Based Devices by Using Carbon Nanotubes as Vector Templates.

We present the synthesis of metal nanowires in a multiplexed device configuration using single-walled carbon nanotubes (SWNTs) as nanoscale vector templates. The SWNT templates control the dimensionality of the wires, allowing precise control of their size, shape, and orientation; moreover, a solution-processable approach enables their linear deposition between specific electrode pairs in electronic devices. Electrical characterization demonstrated the successful fabrication of metal nanowire electronic devices, while multiscale characterization of the different fabrication steps revealed details of the structure and charge transfer between the material encapsulated and the carbon nanotube. Overall the strategy presented allows facile, low-cost, and direct synthesis of multiplexed metal nanowire devices for nanoelectronic applications.