Ultrafiltration (UF) is extensively used for algae removal because of its ability to retain algal cells with high efficiency, but it still faces the problem of membrane fouling and low retention capacity of dissolved organics. Hence, a strategy of coagulation with chitosan quaternary ammonium salt (HTCC) enhanced by sodium percarbonate (SPC) pre-oxidation was proposed to improve the UF performance. The fouling resistances were calculated by a resistance-in-series model based on Darcy's formula, and the membrane fouling mechanism was evaluated using a pore plugging-cake filtration model. The effect of SPC-HTCC treatment on the properties of algal foulants was explored, and the result showed that the water quality was improved with the maximum removal rates of 78.8 %, 52.4 % and 79.5 % for algal cells, dissolved organic carbon and turbidity, respectively. The SPC could achieve a mild oxidation effect that degraded the electronegative organics attached to algal cells without destroying the cell integrity, making the algal pollutants easier to agglomerate through subsequent HTCC coagulation by forming larger flocs. In terms of membrane filtration, the terminal normalized flux was increased from 0.25 to 0.71, with the reversible and irreversible resistances reduced by 90.8 % and 40.2 %, individually. The synergistic treatment reduced the accumulation of algal cells and algae-derived organics on the membrane surface as inferred from the interface fouling characteristics. The interfacial free energy analysis showed that the synergistic treatment reduced the adhesion of contaminants to the membrane surface, as well as the attraction among pollutants. Overall, the proposed process has high application prospects for algae-laden water purification.
Ammonium Compounds , Chitosan , Water Purification , Ultrafiltration , Membranes, Artificial
Forward osmosis (FO) is a high-efficiency and low-energy consumption way for algae-laden water treatment, whereas membrane fouling is still an unavoidable problem in its practical application. In this work, a strategy of ferrous-activated calcium peroxide (Fe(II)/CaO2) was proposed to control FO membrane fouling in the purification of algae-laden water. With the treatment of Fe(II)/CaO2, the aggregation of algal contaminants was promoted, the cell viability and integrity were well preserved, and the fluorescent organics were efficiently removed. With respect to the fouling of FO membrane, the flux decline was generally alleviated, and the flux recovery was promoted to varying degrees under different process conditions. It could be revealed through the extended Derjaguin-Landau-Verwey-Overbeek theory that the adhesion of contaminants and membrane surfaces was reduced by Fe(II)/CaO2 treatment. The interface morphologies and functional groups of membrane verified that Fe(II)/CaO2 could mitigate the fouling by reducing the amount of algal contaminants adhering to the FO membrane. The co-coagulation of in-situ Fe(III) together with Ca(OH)2, as well as the oxidation of â¢OH were the main mechanisms for fouling mitigation. In sum, the Fe(II)/CaO2 process could effectively improve the efficiency of FO for algae-laden water treatment, and has broad application prospects.
Ferric Compounds , Ferrous Compounds
Algal blooms and eutrophication in natural surface water not only pose a threat to human health, but also adversely affect the water purification process. Ultrafiltration (UF) has been proved to be effective for the retention of algal cells, but its further application is still restricted by the relatively limited removal of algal organics and membrane fouling. To enhance the UF performance, a synergistic process using calcium peroxide and ferrous sulfate (CaO2/FeSO4) was proposed for the treatment of Microcystis aeruginosa-laden water. The results suggested that the removal of algal cells and organics, fluorescent components were effectively increased with the synergism of CaO2 and FeSO4. The particle size distribution and morphology revealed that the size of algal pollutants apparently increased due to the formation of algal flocs. With CaO2/FeSO4 pretreatment, the terminal specific flux of polyethersulfone and polyvinylidene fluoride membranes were increased by 75.0% and 56.5%, individually. The fouling resistances were significantly reduced, and the fouling mechanism transition to cake filtration was delayed. The membrane interface properties including morphologies and functional groups were characterized, further verifying the effectiveness. The in-situ formed Fe3+ integrated with Ca(OH)2 showed excellent coagulation effect, thus promoting the agglomeration of algal foulants. Simultaneously, the generated hydroxyl radical could improve the oxidative degradation of algal organics. In conclusion, the CaO2/FeSO4 strategy has great advantages and application prospects in enhancing UF performance for Microcystis aeruginosa-laden water treatment.
Microcystis , Water Purification , Humans , Iron , Membranes, Artificial , Peroxides , Ultrafiltration
To alleviate algal fouling in membrane water treatment processes, conventional technologies such as coagulation with poly aluminum chloride (PACl) has been widely adopted by many drinking water treatment plants. However, coagulation alone exhibited relatively weak removal effect for algal pollutants, and the coagulant residues due to the excess dosage also raised concerns. Thus, a novel process of coupling sodium percarbonate (SPC) oxidation and PACl coagulation was proposed, integrated with membrane filtration for algae-laden water treatment. The dosages of PACl and SPC were optimized, and the SPC dosing strategies were systematically compared. The changes in the characteristics of algal pollutants were investigated, and the results revealed that the resistance of algal foulants to aggregation was decreased, and the particle size of algal foulants became larger. With the synergism of coagulation and oxidation, the degradation of fluorescent organics was strengthened, and macromolecular biopolymers were decomposed into low molecular weight organics. The fouling control efficiency was further explored, and the results indicated that both irreversible and reversible fouling were effectively controlled, among which PACl/SPC (simultaneous treatment) performed best with the irreversible fouling reduced by 90.5%, while the efficiency of SPC-PACl (SPC followed by PACl) was relatively lower (57.3%). The fouling mechanism was altered by slowing the formation of cake filtration, and the reduction of algal cells played a more important role for the fouling alleviation. The interface properties of contaminated membranes (i.e., functional groups, images, and micromorphology) were characterized, and the efficiency of the proposed strategy was further verified. The proposed strategy exhibits great application values for improving membrane performance during algae-laden water treatment.
Filtration , Water Purification , Carbonates , Membranes , Oxidation-Reduction
Powdered activated carbon (PAC) has turned out to be an efficient adsorbent in drinking water treatment, whereas its application integrated with membrane filtration is still controversial because of the combined fouling effect between organic pollutants and PAC. To this end, an integrated process of combining PAC adsorption-catalytic oxidation and membrane filtration was proposed for natural surface water treatment. The synergistic effect of PAC and peroxymonosulfate (PMS) was confirmed through the generation of reactive oxidation species, and both radical oxidative pathways (â¢OH, SO4â¢- and O2â¢-) and nonradical (1O2 and PMS) pathways involved in the process. The removal efficiency of DOC and UV254 was significantly strengthened by PAC/PMS, with removal rates of 56.1% and 64.9%, respectively. The integration of PAC and PMS could significantly enhance the reduction of fluorescent organics, and pollutants with varying molecular weights. The fouling condition of membrane was dramatically alleviated, with the flux increased by 38.9%, and the reversible and irreversible resistances declined by 79.7% and 48.3%, respectively. The major fouling mechanism was significantly changed, and complete pore blocking always played a dominant role, rather than cake filtration. The effectiveness of PAC/PMS was further verified by the characterization of membrane surface morphologies and functional groups. Moreover, the attractive interactions between foulants and membrane were converted to repulsive interactions with the pretreatment of PAC/PMS. The proposed synergistic process was efficient and convenient, which could significantly improve the purification efficiency of conventional PAC-UF system in drinking water treatment.
Ultrafiltration , Water Purification , Adsorption , Charcoal , Membranes, Artificial , Powders , Water
