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Black carbon (BC) significantly affects climate, environmental quality, and human health. This study utilised Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2), which can compensate for the shortcomings of ground BC monitoring in spatial-temporal distribution to study the pollution characteristics of BC and potential pollution sources in a typical industrial city (Xinxiang) with serious air pollution in northern China. The results showed that average daily ground observation and MERRA-2 concentration of BC of 7.33 µg m-3 and 9.52 µg m-3. The mean BC concentration derived from MERRA-2 reanalysis data was higher than ground measurement due to resolution limitations and pollution from the northern regions. The reliability of the MERRA-2 data was confirmed through correlation analysis. Consideration of the spatial distribution of BC from MERRA-2 and incorporating the potential source contribution function (PSCF), concentration-weighted trajectory (CWT), and emission inventory, other possible source areas and primary sources of BC in Xinxiang were investigated. The results indicated that implementing transportation and residential emission control measures in Henan Province and its surrounding provinces, such as Hebei Province, will effectively decrease the BC level in Xinxiang City. A passively smoked cigarettes model was used to evaluate the risk of BC exposure. The percentage of lung function decrement (PLFD) was the highest in school-age children, while the impact on lung cancer (LC) health risk was comparatively lower. Notably, the BC health risk in Xinxiang was lower than in most cities across Asia.
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Contaminantes Atmosféricos , Contaminación del Aire , Niño , Humanos , Ciudades , Contaminantes Atmosféricos/análisis , Estudios Retrospectivos , Reproducibilidad de los Resultados , Monitoreo del Ambiente , China , Contaminación del Aire/análisis , Hollín , Carbono/análisis , Material Particulado/análisisRESUMEN
Herein, the trapping effectiveness of N95, filter KN95, medical surgical masks (MSMs), and disposable medical masks (DMMs) against 19 airborne traditional and novel organophosphate esters (OPEs) was evaluated. Laboratory simulations (n = 24 for each type of mask) showed that time-dependent accumulation of ∑19OPEs on the four types of masks ranged between 30.1 and 86.6 ng in 24 h, with the highest and lowest median amounts trapped by the N95 masks (53.3 ng) and DMMs (43.2 ng), respectively. The trapping efficiency of the four types of masks for ∑19OPEs decreased over time from 84 % to 39 % in 24 h, with N95 masks showing the highest median efficiency (70 %). Further, field investigations were conducted in five types of microenvironments (train, hospital, bus, supermarket, and canteen), and an analysis of 200 samples showed that ∑19OPEs were accumulated in the masks with a variable amount from 3.7 to 117 ng/mask. Consistent with the laboratory simulations, the N95 masks (29.0 ng/mask) exhibited the highest hourly median amount of trapped OPEs, followed by the KN95 masks (24.5 ng/mask), MSMSs (17.4 ng/mask), and DMMs (15.8 ng/mask). Triethyl phosphate (TEP), tris(1-chloro-2-propyl) phosphate (TCIPP), tri-n-butyl phosphate (TNBP), and cresyl diphenyl phosphate (CDP) as well as 4-isopropylphenyl diphenyl phosphate (4IPPDPP) and 2,4-diisopropylphenyl diphenyl phosphate (24DIPPDPP) were the most commonly detected traditional and novel OPEs. Based on the amount of OPEs trapped on the masks, we estimated the concentration of ∑19OPEs in the train microenvironment to be the highest (222 ng/m3), which is approximately 2-5 times higher than that in the other microenvironments. The results of this study prove that masks can effectively protect humans from exposure to OPEs and act as low-cost indicators of indoor contamination.
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Compuestos de Bifenilo , Retardadores de Llama , Máscaras , Humanos , Retardadores de Llama/análisis , Ésteres/análisis , Organofosfatos/análisis , Fosfatos/análisis , Monitoreo del Ambiente , ChinaRESUMEN
To fill the knowledge gaps regarding the global patterns of human exposure to flame retardants (FRs) (i.e., brominated flame retardants (BFRs) and organophosphorus flame retardants (OPFRs)), data on the levels and distributions of FRs in external and internal exposure mediums, including indoor dust, indoor air, skin wipe, serum and urine, were summarized and analysed. Comparatively, FR levels were relatively higher in developed regions in all mediums, and significant positive correlations between FR contamination and economic development level were observed in indoor dust and air. Over time, the concentration of BFRs showed a slightly decreasing trend in all mediums worldwide, whereas OPFRs represented an upward tendency in some regions (e.g., the USA and China). The occurrence levels of FRs and their metabolites in all external and internal media were generally correlated, implying a mutual indicative role among them. Dermal absorption generally contributed >60% of the total exposure of most FR monomers, and dust ingestion was dominant for several low volatile compounds, while inhalation was found to be negligible. The high-risk FR monomers (BDE-47, BDE-99 and TCIPP) identified by external exposure assessment showed similarity to the major FRs or metabolites observed in internal exposure mediums, suggesting the feasibility of using these methods to characterize human exposure and the contribution of indoor exposure to the human burden of FRs. This review highlights the significant importance of exposure assessment based on multiple mediums for future studies.
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Contaminación del Aire Interior , Retardadores de Llama , Humanos , Exposición a Riesgos Ambientales/análisis , Retardadores de Llama/análisis , Contaminación del Aire Interior/análisis , Polvo/análisis , Éteres Difenilos Halogenados/análisis , China , Medios de Cultivo/análisis , Organofosfatos/análisis , Monitoreo del AmbienteRESUMEN
The floating catkins generated by willow and poplar trees have been criticized for spreading germ and causing fire for decades. It has been found that catkins are with a hollow tubular structure, which made us wonder if the floating catkins can adsorb atmospheric pollutions. Thus, we conducted a project in Harbin, China to investigate whether and how willow catkins could adsorb atmospheric polycyclic aromatic hydrocarbons (PAHs). The results suggest that both the catkins floating in the air and on the ground preferred to adsorb gaseous PAHs rather than particulate PAHs. Moreover, 3- and 4-ring PAHs were the dominating compositions adsorbed by catkins, which significantly increased with exposure time. The gas/catkins partition (KCG) was defined, which explained why 3-ring PAHs are more easily adsorbed by catkins than by airborne particles when their subcooled liquid vapor pressure is high (log PL > -1.73). The removal loading of atmospheric PAHs by catkins were estimated as 1.03 kg/year in the center city of Harbin, which may well explain the phenomenon that levels of gaseous and total (particle + gas) PAHs are relatively low in the months with catkins floating reported in peer-reviewed papers.
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The occurrence and distribution of 10 brominated flame retardants (BFRs) and 10 organophosphate flame retardants (OPFRs) were investigated in indoor dust, total suspended particles (TSP), and vapour phase from offices (n = 10), homes (n = 9), and day-care centres (n = 10) in Beijing, China. Three types of samples were collected biweekly from one office and one home over a year to examine temporal trends. BFRs in dust significantly correlated with those in TSP, while OPFRs significantly correlated among all three matrices. In addition, BFRs in dust (ng/g) and TSP (pg/m3) exhibited similar temporal trends with higher levels in the cold season, whereas OPFRs in TSP and vapour phase (pg/m3) showed similar temporal trends with higher levels in the warm season. The geometric mean concentrations of BFRs and OPFRs in the three matrices from the above mentioned three types of indoor microenvironments were used for exposure and health risk estimation, and ∑7OPFRs showed much higher hazard index (HI) values than ∑10BFRs for all subpopulations, and inhalation of OPFRs was a major risk source. With the volatility of flame retardants (FRs) decreasing, the contribution of dust ingestion and dermal absorption showed an increasing trend, and the contribution of inhalation exhibited a gradual decreasing trend, which implied the dominant exposure pathway to FRs is strongly related to the vapour pressure (25 °C, Pa) of these substances. Using a single type of microenvironment or the collection of samples at a single point in time can lead to overestimation or underestimation of overall exposure and risk for people to some extent. The correlations of FRs in dust, TSP, and vapour phase from indoor microenvironments, as well as their temporal trends were first reported in this study, which will provide a basis for more accurate FR exposure assessments in the future.
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Retardadores de Llama , Humanos , Polvo , Beijing , ChinaRESUMEN
Exploration of multiple sources of brominated (BFRs) and organophosphate flame retardants (OPFRs) for children promotes the understanding of exposure pathways and health risk. 10 BFRs and 9 OPFRs were measured in skin wipes from hands, forehead, and arms of 30 children, and surface wipe samples from sills, toys, desks and floors, and indoor air samples of kindergartens from Xinxiang, China. Higher ∑9OPFRs concentrations were observed in the forehead (1840 ng/m2), followed by hand (1420 ng/m2) and arm wipes (1130 ng/m2), and the ∑8BFRs concentrations in forehead, hand and arm wipes were 116, 315 and 165 ng/m2, respectively. The total concentration of OPFRs and BFRs in floor wipes (66.1 and 24.5 ng/m2) were lower than those in toy (205 and 535 ng/m2), sill (227 and 30.1 ng/m2) and desk (84.4 and 139 ng/m2) wipes. Concentrations of FRs in forehead wipes were significantly correlated with those in gaseous air (p < 0.05), moderate correlations were found between the hand wipes and surface wipes (p = 0.054). We estimated the daily average dosages (DADs) of children exposure to FRs via multiple pathways. Compared to DADs via inhalation and hand-to-mouth transfer, dermal exposure was determined to be the predominant exposure pathway to ∑9OPFRs and ∑8BFRs.
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Contaminación del Aire Interior , Retardadores de Llama , Contaminación del Aire Interior/análisis , Niño , Polvo , Exposición a Riesgos Ambientales/análisis , Retardadores de Llama/análisis , Pisos y Cubiertas de Piso , Éteres Difenilos Halogenados/análisis , Mano , Humanos , Organofosfatos/análisisRESUMEN
In this study, we investigated the distribution of brominated and organophosphate flame retardants (BFRs and OPFRs) in the paired gaseous and nine size-segregated particulate samples collected from 8 typical indoor compartments and monthly outdoor in Xinxiang, China, respectively. For the indoor environments, total concentrations of FRs (Σ19FRs) in bulk air ranged from 3.9 ng/m3 to 37.5 ng/m3, with that in children recreation center (37.5 ng/m3) and furniture store (28.7 ng/m3) showing highest levels. In the outdoor air, Σ19FRs ranged from 3.1 ng/m3 to 13.6 ng/m3 among the 12 months, with that from late spring and summer being the highest. OPFRs had higher concentration than BFRs, with the total concentration of OPFRs accounting for 77%-99% of ∑19FRs. TCIPP (tris(chloroiso-propyl) phosphate), TCEP (tris(2-chloroethyl) phosphate), TEP (triethyl phosphate) and DBDPE (decabromodiphenyl ethane), BDE-209 (decabromodiphenyl ether) were the predominant analogs. Specifically, BFRs tended to enrich in gas phase indoors and coarse particles (aerodynamic diameters >3.3 µm) outdoors, but OPFRs mainly distributed in coarse particles both indoors and outdoors. The size distribution patterns varied among FRs, with the higher volatile FRs (e.g., TCEP, TCIPP) distributed more uniformly across particulate size. Although the distribution patterns of FRs in air were driven by multiple factors, organic carbon and element carbon in particulate matter had an influence to a certain extent. Health risks from exposure to FRs were characterized via the hazard quotient approaches. The total noncarcinogenic risks of ∑16FRs from inhalation were higher than that from air to skin transport, and the risks resulted from coarse particle-bound ∑16FRs (>3.3 µm) and gas phase were both significantly higher than that from fine fraction (<3.3 µm) in all scenarios, implying that FRs in coarse particles should not be underestimated.
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Contaminación del Aire Interior , Retardadores de Llama , Contaminación del Aire Interior/análisis , Niño , Polvo/análisis , Exposición a Riesgos Ambientales/análisis , Monitoreo del Ambiente , Retardadores de Llama/análisis , Gases , Éteres Difenilos Halogenados/análisis , Humanos , Organofosfatos/análisis , Material Particulado/análisisRESUMEN
Gas/particle (G/P) partitioning is an important influencing factor for the environmental fate of semi-volatile organic compounds (SVOCs). The G/P partitioning of polycyclic aromatic hydrocarbons (PAHs) is an integrated complex process due to its formation and growth concurrently with particles. Based on the large dataset of gaseous and particulate samples in a wide ambient temperature range of 50 °C, the simple empirical equations based on ambient temperature were established to predict the G/P partitioning quotient (KP) of PAHs at the temperature range from 252 K to 307 K (-21 °C to 34 °C). The performance of the empirical equations was validated by comparison with the monitoring KP of PAHs worldwide. The empirical equations exhibited good performance for the prediction of KP of PAHs based on ambient temperature. Two deviations with the prediction lines of the previous G/P partitioning models from the monitoring data of KP were observed. It was found that the deviations might be attributed to some non-considered influencing factors with the previous G/P partitioning prediction models. Therefore, further research should be conducted to study the mechanism of the G/P partitioning of PAHs, and more influencing factors should be introduced into the establishment of G/P partitioning models of PAHs. In summary, the result of the present study provided a convenient method for the prediction of KP of PAHs, which should be useful for the study of environmental fate of PAHs in atmosphere.
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Contaminantes Atmosféricos , Hidrocarburos Policíclicos Aromáticos , Contaminantes Atmosféricos/análisis , Monitoreo del Ambiente , Gases/análisis , Hidrocarburos Policíclicos Aromáticos/análisis , TemperaturaRESUMEN
The risk of human exposure to particulate novel brominated flame retardants (NBFRs) in the atmosphere has received increasing attention from scientists and the public, but currently, there is no reliable approach to predict the intake of these compounds on the basis of their size distribution. Here, we develop a reliable approach to predict the size-dependent inhalation intake of particulate NBFRs, based on the gas/particle (G/P) partitioning behavior of the NBFRs. We analyzed the concentrations of eight NBFRs in 363 size-segregated particulate samples and 99 paired samples of gaseous and bulk particles. Using these data, we developed an equation to predict the G/P partitioning quotients of NBFRs in particles in different size ranges (KPi) based on particle size. This equation was then successfully applied to predict the size-dependent inhalation intake of particulate NBFRs in combination with an inhalation exposure model. This new approach provides the first demonstration of the effects of the temperature-dependent octanol-air partitioning coefficient (KOA) and total suspended particle concentration (TSP) on the intake of particulate NBFRs by inhalation. In an illustrative case where TSP = 100 µg m-3, inhalation intake of particulate NBFRs exceeded the intake of gaseous NBFRs when log KOA > 11.4.
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Retardadores de Llama , Atmósfera , Polvo/análisis , Monitoreo del Ambiente , Retardadores de Llama/análisis , Éteres Difenilos Halogenados/análisis , HumanosRESUMEN
Multimedia fugacity models have long been used to address the fate of toxic organic chemical emissions by providing a quantitative account of the sources, transport processes, and sinks. Recently, we have examined three level-III fugacity models (E4F (equilibrium six-compartment four-fugacity), S6F (steady-state six-compartment six-fugacity) and S4F (steady-state six-compartment four-fugacity) Models), in the context of their performance set against real-world data, and their practicality of application. Here, we discuss how the balance between gaseous and aerosol phases of emissions assumed for initial conditions affects the different model outcomes. Our results show that the S6F Model predictions closely match those of the S4F Model when chemical emissions are entirely in the gas-phase. As the particulate proportion of the emission increases, the S6F Model predictions diverge from those of the S4F Model and approach those of the E4F Model. Once the particulate portion reaches 100%, the S6F and E4F Models produce identical results: an internally inconsistent system where chemicals are not in a steady state between air and aerosols, and mass balance for both air and aerosols is not achieved. Thus, in terms of practicality, internal consistency, chemical mass balance and agreement with observations, the S4F Model is clearly the best choice.
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Contaminantes Atmosféricos , Compuestos Orgánicos Volátiles , Contaminantes Atmosféricos/análisis , Polvo , Gases , Multimedia , Compuestos Orgánicos Volátiles/análisisRESUMEN
The atmosphere is a significant medium for the transportation and diffusion of volatile and semi-volatile pollutants. Furthermore, the atmosphere is the primary exposure route for pollutants to enter the human body. Therefore, the study of the environmental fate of pollutants in the atmosphere is essential. In this study, 16 polycyclic aromatic hydrocarbons (PAHs) were analyzed in snow samples and air samples within 24 hours after a snowfall, and the temporal trend of PAHs in the atmosphere was comprehensively studied. The results indicated that the detection rate of the 16 PAHs in snow was 100%, and the concentration of phenanthrene (538.3 ng·L-1) was the highest, followed by naphthalene (509.1 ng·L-1) and fluoranthene (429.9 ng·L-1), indicating that snowfall can remove PAHs from the atmosphere. After the snowfall, a falling-rising-falling temporal trend of the concentrations of PAHs in the atmosphere was observed. Higher concentrations appeared during rush hour, with the largest automobile exhaust emissions, while lower concentrations appeared during periods with the lowest human activity. The results indicated that the atmospheric concentrations of PAHs were predominantly influenced by human activities. Within 24 hours after snowfall, the ratio of PAHs between the gas phase and particle phase, which depends primarily on the physical and chemical properties of PAHs, had not changed substantially. The diagnostic ratios indicated that within 24 hours after snowfall, the PAHs in the atmosphere originated mostly from the emissions of solid fuel and liquid fuel combustion.
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In this paper, two level III fugacity models are developed and applied using an environmental system containing six compartments, including air, aerosols, soil, water, suspended particulate matters (SPMs), and sediments, as a "unit world". The first model, assumes equilibrium between air and aerosols and between water and SPMs. These assumptions lead to a four-fugacity model. The second model removes these two assumptions leading to a six-fugacity model. The two models, compared using four PBDE congeners, BDE-28, -99, -153, and -209, with a steady flux of gaseous congeners entering the air, lead to the following conclusions. 1. When the octanol-air partition coefficient (KOA) is less than 1011.4, the two models produce similar results; when KOA > 1011.4, and especially when KOA > 1012.5, the model results diverge significantly. 2. Chemicals are in an imposed equilibrium in the four-fugacity model, but in a steady state and not necessary an equilibrium in the six-fugacity model, between air and aerosols. 3. The results from the six-fugacity model indicate an internally consistent system with chemicals in steady state in all six compartments, whereas the four-fugacity model presents an internally inconsistent system where chemicals are in equilibrium but not a steady state between air and aerosols. 4. Chemicals are mass balanced in air and aerosols predicted by the six-fugacity model but not by the four-fugacity model. If the mass balance in air and aerosols is achieved in the four-fugacity model, the condition of equilibrium between air and aerosols will be no longer valid.
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Contaminantes Atmosféricos , Aerosoles , Contaminantes Atmosféricos/análisis , Gases , SueloRESUMEN
Gas/particle (G/P) partition quotients of semi-volatile organic compounds (SVOCs) for bulk air have been widely discussed in experimental and theoretical contexts, but research on size-resolved G/P partition quotients (KPi) are scarce and limited in scope. To investigate G/P partition behavior of polybrominated diphenyl ethers (PBDEs) for size-segregated particles in the atmosphere, 396 individual size-segregated particulate samples (36 batches × 11 size-ranges), and 108 pairs of concurrent gaseous and bulk particulate samples were collected in Harbin, China. A steady-state equation based on bulk particles is derived to determine G/P partition quotients of PBDEs for size-segregated particles, which depends on the organic matter contents of size-segregated particles (fOMi). This equation can well predict KPi with knowledge of bulk partition quotient (KPS), ambient temperature, and fOMi, the results of which match well with monitoring data in Harbin and other published data collected in Shanghai and Guangzhou of China and Thessaloniki of Greece, and remedies a defect of over-estimate KPi for high-brominated PBDEs by the previous equation. In particular, the new equation contributes to obtaining the PBDEs concentrations in all atmospheric phase from partial phase, then provides a credible path to evaluate healthy exposure dose from the airborne PBDEs, by co-utilization with exposure models.
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Gas/particle (G/P) partitioning of semi-volatile organic compounds (SVOCs) such as polybrominated diphenyl ethers (PBDEs), is an important atmospheric process due to its significance in governing atmospheric fate, wet/dry deposition, and long-range atmospheric transport. In this article, eight models published to predict the G/P partitioning of PBDEs are reviewed. These eight models are used to calculate the G/P partitioning quotient and particulate phase fraction of selected PBDE congeners. A comparison of the predicted results from the eight models with monitoring data published by several research groups worldwide leads to the following conclusions: 1) when the values of the logarithm of the octanol-air partition coefficient (logKOA) fall below 11.4 (the first threshold value, logKOA1), all 8 models perform well in predicting the G/P partitioning of PBDEs in the atmosphere, and 2) when logKOA is >11.4, and especially above 12.5 (the second threshold value, logKOA2), the Li-Ma-Yang model, a steady-state model developed based on wet and dry deposition of the particles (Li et al., Atmos. Chem. Phys. 2015; 15:1669-1681), shows the best performance with highest conformity to the measurements for selected PBDEs (94.4 ± 1.6% data points within ±1 log unit). Overall, the Li-Ma-Yang model appears to capture the most important factors that affect the partitioning of PBDEs between gaseous and particular phases in the atmosphere.
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The gas/particle (G/P) partitioning (KP) behavior is an important factor for the environmental fate of PAHs in atmosphere. Based on large database of log KP, equilibrium-state and steady-state models were applied for the comprehensive study with the G/P partitioning of PAHs, including the Harner-Bidleman (H-B) model, the Dachs-Eisenreich (D-E) model, and the Li-Ma-Yang (L-M-Y) model. For different sites, the trend of regression between log KP and log KOA was same, however, the slopes and intercepts were different. No obvious difference was observed between northern Chinese cities and southern Chinese cities. For congeners and aromatic rings of PAHs, the difference was much more obvious for the regressions, slopes and intercepts. The prediction of the D-E model and the H-B model matched well for the regression of the 4-rings and 5-rings PAHs, with >80% of monitoring data points in the range of ±1 log unit. The L-M-Y model only predicted well with the measurement for 4-rings PAHs with special values of log KOA. For different ranges of log KOA, the difference with the regression between log KP and log KOA was also obvious. Compared with our measurement, if 1 order of magnitude difference with log KP values between prediction and measurement was considered, the H-B model, the D-E model and the L-M-Y model can be only used when the log KOA in the ranges from 7.65 to 13.7, 6.88 to 13.5, and 7.65 to 11.7, respectively. Therefore, further studies with prediction models should be conducted for the G/P partitioning of PAHs. The results of this study provided new insights into the research field of the G/P partitioning of SVOCs.
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To investigate the distributions, degree, and possible sources of polycyclic aromatic hydrocarbons (PAHs) in bed sediments from four rivers of Xinxiang, 18 sediment samples were analyzed. The concentrations ranged from 4.45 × 10(3) to 29.0 × 10(3) ng/g for ∑15PAHs (sum of US Environmental Protection Agency (EPA) priority PAHs apart from naphthalene (Nap)) and 3.37 × 10(3) to 23.5 × 10(3) ng/g for ∑7carPAHs (including benzo[a]anthracene (BaA), chrysene (Chr), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), dibenzo[a,h]anthracene (DBA), and indeno[1,2,3-cd]pyrene (InP)) with average concentrations of 10.7 × 10(3) and 7.99 × 10(3) ng/g, respectively. Compared with those from other rivers in China, sediments from four rivers of Xinxiang were severely polluted with PAHs. Pearson correlation analysis showed that ∑15PAHs concentrations had a significant positive correlation with black carbon content. Four- to six-ring PAHs accounted for 83.4 % of total PAHs, which indicated that the main source of PAHs in the studied area could be pyrogenic contamination. Source apportionment using PCA/MLR and UNMIX revealed that coal and biomass combustion contributed 64.4-67.1 %, gasoline vehicle 23.2-27.2 %, and diesel vehicle 5.70-12.4 % of the total PAHs, respectively. The effects range low/effects range median (ERL/ERM) values showed that there was a high level of toxicity risk for BaA. The ecological risk assessment by mean effects range median quotients (mERMQ) revealed a medium ecological risk of ∑15PAHs in sediments from four rivers of Xinxiang, manifesting that a close attention should be paid to pollution of PAHs in the studied area.
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Monitoreo del Ambiente , Sedimentos Geológicos/química , Hidrocarburos Policíclicos Aromáticos/análisis , Contaminantes Químicos del Agua/análisis , China , Carbón Mineral/análisis , Residuos Industriales , Hidrocarburos Policíclicos Aromáticos/química , Medición de Riesgo , Ríos/química , Contaminantes Químicos del Agua/químicaRESUMEN
The levels, potential sources and ecological risks of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) in Yellow River of Henan section, a typical agricultural area in China, were investigated. Surface water samples and suspended particulate matters (SPMs) were collected from 23 sites during two seasons. In wet season, the residues of ∑HCHs (α-HCH, ß-HCH, γ-HCH and δ-HCH) and ∑DDTs (p,p'-DDT, o,p'-DDT, p,p'-DDE, p,p'-DDD) ranged from 41.7 to 290 and 4.42 to 269 ng/L in surface water, while those varied from 0.86 to 157 and 1.79 to 96.1 ng/g dw in SPM, respectively. Moreover, in surface water, the levels of HCHs and DDTs in wet season were much higher than those in dry season. The reverse was true for residues of HCHs and DDTs in SPM. Compared with the large rivers in other regions, the levels of HCHs and DDTs in the studied area ranked at high levels and the residual concentrations might cause adverse biological risk, especially for ∑HCHs during wet season. Distributions of HCHs and DDTs delineated that the input of tributaries made a significant effect on the residue of HCHs and DDTs in the mainstream. ∑HCHs in surface water were consist of 26.7 % α-HCH, 30.0 % ß-HCH, 37.9 % γ-HCH and 5.45 % δ-HCH and those in SPM contained 5.16 % α-HCH, 22.1 % ß-HCH, 60.5 % γ-HCH and 12.2 % δ-HCH on average. Combined with ratios of α-HCH/γ-HCH in surface water (0.70) and in SPM (0.09), the results strongly indicated that lindane was recently used or discharged in the studied area. The mean percentage of DDTs' isomers were 28.7 % p,p'-DDT, 29.8 % o,p'-DDT, 28.1 % p,p'-DDE and 13.4 % p,p'-DDD in surface water, while those were 12.5 % p,p'-DDT, 31.8 % o,p'-DDT, 30.5 % p,p'-DDE and 25.1 % p,p'-DDD in SPM. The ratios of (DDE + DDD)/∑DDTs and o,p'-DDT/p,p'-DDT revealed that the DDTs in the studied area mainly derived from long-term weathering of technical DDTs residue and the input of dicofol.