Alternating Graft Copolymer Carrying PLA Graft Chains at Every Other Unit: Sequence Impacts on Crystallization Behaviors.

Alternating graft copolymers were precisely synthesized via selective cyclopolymerization of pendant-transformable divinyl monomer (1), post-polymerization modification via aminolysis with alkylamine, and ring-opening polymerization of l-lactide (LLA) from the hydroxy pendant group in alternating sequence. The poly(LLA) (PLLA) graft chain on the alternating copolymer gave a higher crystallization degree on the isothermal treatment than that on the random counterpart likely because of the periodic sequence. The comonomer pendant group from alkylamine in the aminolysis reaction in the alternating sequence affected the crystallization behaviors, and the oligoethylene glycol (OEG) group promoted the crystallization thanks to the larger free volume effect. As for the stereocomplex formation of the racemic mixture of enantiomeric PLLA and poly(d-lactide) (PDLA) chains, the alternating graft copolymer gave a higher degree of stereocomplex crystallization in the mixture with the enantiomer homopolymer than the random analogue.

Coherent Nyquist optical pulse transmission at nearly 1-Tb/s/λ over 1,600 km with a capacity of 21.5 Tb/s using PS-32 QAM signals.

We demonstrate the 1,600-km transmission at nearly 1-Tb/s/λ signals with a capacity of 21.5 Tb/s. Probabilistic shaping was newly applied to high-speed coherent optical Nyquist pulse transmission systems to maximize the transmission capacity. Employing a 160-GBd PS-32 QAM format, WDM signals at nearly 1-Tb/s/λ were successfully transmitted over 1,600 km with a capacity of 21.5 Tb/s.