Continuous batch synthesis with atmospheric-pressure microwave plasmas.

Plasmas under atmospheric pressure offer a high-temperature environment for material synthesis, but electrode ablation compromises purity. Here, we introduce an atmospheric-pressure microwave plasma (AMP) operated without electrodes to overcome the existing limitations in pure material synthesis. The distribution of the electrostatic field intensity inside a waveguide during AMP excitation was examined via electrostatic field simulations. The lateral and radial gas temperature distributions were also studied using optical emission spectroscopy. The AMP exhibited a uniform ultrahigh temperature (9,000 K), a large volume (102-104 cm3), and a response time on the millisecond level. AMP efficiently synthesized silicon nanoparticles, graphene, and graphene@Si-Fe core-shell nanoparticles within tens of milliseconds, ensuring purity and size control. We propose the "heat impulse" metric for evaluating the plasma characteristics (n a, T g, and t) in material synthesis, extended to other high-temperature plasmas. AMP is compact, cost-effective, and easy to assemble, promising for eco-friendly mass production of pure materials.

Polymer Dielectrics with Outstanding Dielectric Characteristics via Passivation with Oxygen Atoms through C-F Vacancy Carbonylation.

The development of advanced electrical equipment necessitates polymer dielectrics with a higher electric strength. Unfortunately, this bottleneck problem has yet to be solved because current material modification methods do not allow direct control of deep traps. Here, we propose a method for directly passivating deep traps. Measurements of nanoscale microregion charge characteristics and trap parameters reveal a significant reduction in the number of deep traps. The resulting polymer dielectric has an impressively high electrical strength, less surface charge accumulation, and a significantly increased flashover voltage and breakdown strength. In addition, the energy storage density is increased without sacrificing the charge-discharge efficiency. This reveals a new approach to increasing the energy storage density by reducing the trap energy levels at the electrode-dielectric interface. We further calculated and analyzed the microscopic physical mechanism of deep trap passivation based on density functional theory and characterized the contributions of orbital composition and orbital hybridization.

An atmospheric microwave plasma-based distributed system for medical waste treatment.

Inadequate handling of infectious medical waste may promote the spread of the virus through secondary transmission during the transfer process. Microwave plasma, an ease-of-use, device-compact, and pollution-free technology, enables the on-site disposal of medical waste, thereby preventing secondary transmission. We developed atmospheric-pressure air-based microwave plasma torches with lengths exceeding 30 cm to rapidly treat various medical wastes in situ with nonhazardous exhaust gas. The gas compositions and temperatures throughout the medical waste treatment process were monitored by gas analyzers and thermocouples in real time. The main organic elements in medical waste and their residues were analyzed by an organic elemental analyzer. The results showed that (i) the weight reduction ratio of medical waste achieved a maximum value of 94%; (ii) a water-waste ratio of 30% was beneficial for enhancing the microwave plasma treatment effect for medical wastes; and (iii) substantial treatment effectiveness was achievable under a high feeding temperature (≥ 600 °C) and a high gas flow rate (≥ 40 L/min). Based on these results, we built a miniaturized and distributed pilot prototype for microwave plasma torch-based on-site medical waste treatment. This innovation could fill the gap in the field of small-scale medical waste treatment facilities and alleviate the existing issue of handling medical waste on-site.

Microwave plasma torches for solid waste treatment and vitrification.

Conventional thermal plasma technology used in the treatment of solid waste has a high demand for power and a high rate of heat loss during solid waste treatment. We developed a novel approach for treating and vitrifying solid waste with a low-power microwave plasma torch (MPT). Based on theoretical thermodynamic equilibrium calculations, we studied the melting temperature of the residual ash and achieved vitrification of the residual ash with an MPT by adding specified ratios of discarded glass scraps. Thermocouples and a gas analyzer were used to characterize the temperature variations and gas concentrations in the plasma treatment chambers, respectively. An organic elemental analyzer and X-ray fluorescence (XRF) analyses were used to determine the chemical proportions of the solid waste residues. The morphologies of the residues and vitreous material were analyzed using scanning electron microscopy (SEM). The results showed that the microwave plasma treatment process converted 96 wt.% of the solid wastes into nonpolluting gases, leaving a residue of pure carbon and inorganic powder. Through theoretical calculations and experiments, atmospheric MPTs with power levels less than 10 kW were identified as realistic means for treating and vitrifying solid wastes.