1.
Chem Commun (Camb)
; 54(6): 631-634, 2018 Jan 16.
Artículo
en Inglés
| MEDLINE
| ID: mdl-29299562
RESUMEN
The first metal-organic framework exhibiting thermally activated delayed fluorescence (TADF) was developed. The zirconium-based framework (UiO-68-dpa) uses a newly designed linker composed of a terphenyl backbone, an electron-accepting carboxyl group, and an electron-donating diphenylamine and exhibits green TADF emission with a photoluminescence quantum yield of 30% and high thermal stability.