The increasing demand for biodegradable and environmentally friendly materials is shifting the focus from traditional polymer composites to biocomposites in various applications, especially in electromagnetic shielding. Effective utilization of biopolymers demands improved properties and can be achieved to a certain extent by functionalization. Biopolymers such as cellulose, polylactic acid, and starch are some of the potential candidates for mitigating electromagnetic pollution in next-generation electronic devices because of their high aspect ratio, flexibility, light weight, high mechanical strength, thermal stability, and tunable microwave absorption to the electromagnetic interference (EMI) shielding composites. This Review provides an overview of the current advancements in EMI shielding materials and outlines recent research on EMI shielding composites that utilize various biodegradable polymer structures.
Cellulose, the most abundant polymer on Earth, has been widely utilized in its nanoform due to its excellent properties, finding applications across various scientific fields. As the demand for nanocellulose continues to rise and its ease of use becomes apparent, there has been a significant increase in research publications centered on this biomaterial. Nanocellulose, in its different forms, has shown tremendous promise as a tissue engineered scaffold for regeneration and repair. Particularly, nanocellulose-based composites and scaffolds have emerged as highly demanding materials for both soft and hard tissue engineering. Medical practitioners have traditionally relied on collagen and its analogue, gelatin, for treating tissue damage. However, the limited mechanical strength of these biopolymers restricts their direct use in various applications. This issue can be overcome by making hybrids of these biopolymers with nanocellulose. This review presents a comprehensive analysis of the recent and most relevant publications focusing on hybrid composites of collagen and gelatin with a specific emphasis on their combination with nanocellulose. While bone and skin tissue engineering represents two areas where a majority of researchers are concentrating their efforts, this review highlights the use of nanocellulose-based hybrids in these contexts.
Gelatin , Tissue Engineering , Tissue Scaffolds , Biocompatible Materials , Collagen
Catechol (Cc) molecule adsorption on a pristine and transition metal (TMs = Sc, Pd, and Cu)-functionalized two-dimensional polyaramid (2DPA) monolayer is systematically studied by the first-principles density functional theory method. The weak physisorption (-0.29 eV) and charge transfer of the Cc molecule with p-2DPA result in a very quick recovery time (150 µs), hindering the Cc sensing capability of p-2DPA. Although TM functionalization greatly improved the adsorption ability, the Pd-functionalized 2DPA was shown to be the best choice for Cc adsorption due to the reasonable adsorption energy of -1.39 eV and expedited charge transfer between the Cc and Pd atom. The change of band gap and, hence, the conductivity of the Pd-2DPA system in response to the adsorption of the Cc molecule demonstrate its higher sensitivity than that of p-2DPA. The work function sensitivity of Pd-2DPA upon the Cc adsorption is also investigated. In addition to the change in the electronic properties, the change in the optical properties of Pd-2DPA after Cc adsorption is also analyzed. The structural stability of Pd-2DPA is validated by performing ab initio molecular dynamics simulations at 300 K. The complete desorption of the Cc molecule from Pd-2DPA is attained by annealing the material at 550 K under visible light (τ = 5.4 s) and at 450 K under UV light (τ = 3.7 s). Moreover, the higher diffusion energy barrier of +1.35 eV confirmed that the functionalized Pd atoms did not diffuse through the crystal to form clusters. This study could lay a theoretical foundation for developing possibly new-generation sensors for detecting Cc molecules.
Two-dimensional materials have attracted a great deal of interest in developing nanodevices for gas-sensing applications over the years. The 2D BeN4monolayer, a recently synthesized single-layered Dirac semimetal, has the potential to function as a gas sensor. This study analyzes the NH3sensing capacity of the pristine and vacancy-induced BeN4monolayers using first-principles density functional theory (DFT) calculations. As per the results, the NH3molecule is physisorbed on the pristine BeN4via weak Van der Waals interaction with a poor adsorption energy of -0.41 eV and negligible charge transfer. Introducing Be vacancy in BeN4increased the NH3adsorption energy to -0.83 eV due to the improved charge transfer (0.044 e) from the defective monolayer to the NH3molecule. The structural stability, sufficient recovery time (74 s) at room temperature, and superior work function sensitivity promise the potential application of defective BeN4as an NH3sensor. This research will be a theoretical groundwork for creating innovative BeN4-based NH3gas sensors.
In recent years, carbon-based two-dimensional (2D) materials have gained popularity as the carriers of various anticancer therapy drugs, which could reduce the crucial side effects by directly applying the drugs to the intended tumor cells. In this study, through first-principles density functional theory simulations, we have investigated the adsorption properties of a famous cancer chemotherapy drug called mercaptopurine (MC) on a 2D γ-graphyne (GYN) monolayer. Analyzing the geometric and electronic properties, we can summarize that the MC interaction with the pristine GYN is weak, with a small adsorption energy of -0.15 eV, which is too low for potential applications. Therefore, we have decorated the GYN monolayer with biocompatible metals such as Al, Ag, and Cu to trigger the adsorption capacity. The Al- and Cu-decorated GYN offered improved adsorption towards MC compared to the pristine case. The drug release from these metal-decorated systems was examined by creating an acidic environment. In addition, the desorption temperature of the drug from the system was also evaluated using ab initio molecular dynamics simulations. The calculations demonstrated that the Al-decorated GYN is a potential vehicle for MC drug delivery because of the favourable adsorption energy of -0.63 eV, charge transfer of 0.17e and desorption temperature above 270 K. The current research will stimulate the investigation of other low-dimensional carbon materials for drug-delivery applications.
Excipients , Mercaptopurine , Biological Transport , Adsorption , Carbon , Metals
Recently, polymeric graphitic carbon nitride (g-C3N4) has been explored as a potential catalytic material for the removal of organic pollutants in wastewater. In this work, graphitic carbon nitride (g-C3N4) photocatalysts were synthesized using mixtures of low-cost, environment-friendly urea and thiourea as precursors by varying calcination temperatures ranging from 500 to 650 °C for 3 h in an air medium. Different analytical methods were used to characterize prepared g-C3N4 samples. The effects of different calcination temperatures on the structural, morphological, optical, and physiochemical properties of g-C3N4 photocatalysts were investigated. The results showed that rhodamine B (RhB) dye removal efficiency of g-C3N4 prepared at a calcination temperature of 600 °C exhibited 94.83% within 180 min visible LED light irradiation. Photocatalytic activity of g-C3N4 was enhanced by calcination at higher temperatures, possibly by increasing crystallinity that ameliorated the separation of photoinduced charge carriers. Thus, controlling the type of precursors and calcination temperatures has a great impact on the photocatalytic performance of g-C3N4 towards the photodegradation of RhB dye. This investigation provides useful information about the synthesis of novel polymeric g-C3N4 photocatalysts using a mixture of two different environmentally benign precursors at high calcination temperatures for the photodegradation of organic pollutants.
Supramolecular architectures, which are formed through the combination of inorganic metal cations and organic ligands by self-assembly, are one of the techniques in modern chemical science. This kind of multi-nuclear system in various dimensionalities can be implemented in various applications such as sensing, storage/cargo, display and molecular switching. Iron(II) mediated spin-crossover (SCO) supramolecular architectures with Schiff bases have attracted the attention of many investigators due to their structural novelty as well as their potential application possibilities. In this paper, we review a number of supramolecular SCO architectures of iron(II) with Schiff base ligands exhibiting varying geometrical possibilities. The structural and SCO behavior of these complexes are also discussed in detail.
In contrast to the hot-injection organometallic routes, synthesizing stable and highly luminescent core/shell nanocrystals with encapsulation of biocompatible groups through an aqueous route is a long-standing challenge. In recent years, relatively high quantum efficiency and unique properties of core/shell nanostructured materials (quantum dots) have contributed toward enhancement in sensing capability. The present work reports a facile aqueous synthesis process of core/shell CdSe/ZnS quantum dots (QDs) with encapsulation of glutathione (GSH). The optimal conditions for the synthesis of the most stable particles were ascertained, and the different experimental analyses suggest that the stable core/shell QDs in question have good crystallinity with a size around 4.7 nm with a shell thickness of 0.7 nm and a photoluminescence quantum yield of about 35%. Further, it is demonstrated that the as-synthesized material has great potential in detecting as low as 0.28 nM 3-nitro-l-tyrosine (3-NT), an important marker for oxidative stress, the level of which in our body signals several chronically diseased conditions. The enthalpy-driven interactions of CdSe/ZnS-GSH QDs with 3-NT were characterized through steady-state and time-resolved luminescence spectroscopy and isothermal microcalorimetry. The devised method of probing 3-NT was further validated with human serum samples. Thus, the proposed strategy may provide a protocol for selective determination of 3-NT under different pathological conditions.
Cadmium Compounds , Quantum Dots , Selenium Compounds , Humans , Quantum Dots/chemistry , Cadmium Compounds/chemistry , Luminescence , Selenium Compounds/chemistry , Zinc Compounds/chemistry , Sulfides/chemistry , Water/chemistry , Glutathione/chemistry
Graphene quantum dots (GQDs), the zero dimensional (0D) single nanostructures, have many exciting technological applications in diversified fields such as sensors, light emitting devices, bio imaging probes, solar cells, etc. They are emerging as a functional tool to modulate light by means of molecular engineering due to its merits, including relatively low extend of loss, large outstretch of spatial confinement and control via doping, size and shape. In this article, we present a one pot, facile and ecofriendly synthesis approach for fabricating GQDs via pulsed laser irradiation of an organic solvent (toluene) without any catalyst. It is a promising synthesis choice to prepare GQDs due to its fast production, lack of byproducts and further purification, as well as the control over the product by accurate tuning of laser parameters. In this work, the second (532 nm) and third harmonic (355 nm) wavelengths of a pulsed nanosecond Nd:YAG laser have been employed for the synthesis. It has been found that the obtained GQDs display fluorescence and is expected to have potential applications in optoelectronics and light-harvesting devices. In addition, nonlinear optical absorption of the prepared GQDs was measured using the open aperture z-scan technique (in the nanosecond regime). These GQDs exhibit excellent optical limiting properties, especially those synthesized at 532 nm wavelength.
Graphite , Quantum Dots , Quantum Dots/chemistry , Graphite/chemistry , Fluorescence , Toluene , Lasers
Diabetes is a health disorder that necessitates constant blood glucose monitoring. The industry is always interested in creating novel glucose sensor devices because of the great demand for low-cost, quick, and precise means of monitoring blood glucose levels. Electrochemical glucose sensors, among others, have been developed and are now frequently used in clinical research. Nonetheless, despite the substantial obstacles, these electrochemical glucose sensors face numerous challenges. Because of their excellent stability, vast surface area, and low cost, various types of 2D materials have been employed to produce enzymatic and nonenzymatic glucose sensing applications. This review article looks at both enzymatic and nonenzymatic glucose sensors made from 2D materials. On the other hand, we concentrated on discussing the complexities of many significant papers addressing the construction of sensors and the usage of prepared sensors so that readers might grasp the concepts underlying such devices and related detection strategies. We also discuss several tuning approaches for improving electrochemical glucose sensor performance, as well as current breakthroughs and future plans in wearable and flexible electrochemical glucose sensors based on 2D materials as well as photoelectrochemical sensors.
Biosensing Techniques , Electrochemical Techniques , Blood Glucose , Blood Glucose Self-Monitoring , Glucose , Monitoring, Physiologic
To develop a highly sensitive and selective biosensor for detecting noxious biomolecules from the environment, we examined catechol (Cc) adsorption in pristine and transition metal (TM = Sc, Cu, and Pd) embedded 2D holey graphyne (hGY) monolayers using the first-principles density functional theory method. The interaction between Cc and the pristine hGY is purely weak, and hence the response of the sensing device will be difficult to detect. Therefore, the TM doping strategy is adopted to improve the sensitivity. According to our findings, Sc binds strongly to the hGY monolayer, with a binding energy of -4.09 eV and a charge transfer of 1.89e from the valence orbitals of Sc to the C 2p orbitals. Later on, the Cc adsorption on the TM-embedded hGY was investigated. The interaction of Cc with the transition metal involves charge transfer from Cc to the metal d orbital. A large binding energy of -3.22 eV and a significant charge transfer of about 0.9e from the O 2p orbitals of Cc to the valence orbital of Sc suggest that the Sc embedded hGY monolayer is a good choice for the efficient sensing of Cc molecules. Furthermore, ab initio MD simulations confirmed the structural stability of the Sc + hGY system at room temperature. We strongly believe that this theoretical work will aid the experimentalists in designing and developing 2D semiconducting nanolayer-based biosensors for commercial purposes.
Transition Elements , Adsorption , Catechols , Density Functional Theory , Metals/chemistry , Transition Elements/chemistry
Traditional cotton gauze derived from cellulose has many limitations in the processes of wound healing. To overcome these hassles, we used cellulose nanofibers (CNF) incorporated with curcumin for the fabrication of wound healing 3D porous aerogel. Cellulose nanofibers synthesized from plant waste are promising sustainable nanomaterials due to their biocompatibility and biodegradability. Ionic cross linking with sodium alginate was performed to maintain the mechanical strength. SEM results revealed highly porous architecture that effectively promoted wound healing, as a result of macro- and micro-porous architecture and curcumin. In-vitro drug release studies showed a slow and steady release pattern. The 3D porous nano bio aerogel with curcumin significantly promoted the migration of fibroblast cells and had excellent antimicrobial activity against pathogenic microorganisms. In-vivo studies showed angiogenesis without rejection or inflammation of the scaffold. From the observations, we can conclude that this novel 3D porous aerogel can be used to treat chronic wounds.
Curcumin , Nanofibers , Alginates , Cellulose/pharmacology , Curcumin/pharmacology , Porosity
The demand for metallic nanoparticle ornamented nanohybrid materials of graphene oxide (GO) finds copious recognition by virtue of its advanced high-tech applications. Far apart from the long-established synthesis protocols, a novel laser-induced generation of silver nanoparticles (Ag NPs) that are anchored onto the GO layers by a single-step green method named pulsed laser ablation has been exemplified in this work. The second and third harmonic wavelengths (532 nm and 355 nm) of an Nd:YAG pulsed laser is used for the production of Ag NPs from a bulk solid silver target ablated in an aqueous solution of GO to fabricate colloidal Ag-GO nanohybrid materials. UV-Vis absorption spectroscopy, Raman spectroscopy, and TEM validate the optical, structural, and morphological features of the hybrid nanomaterials. The results revealed that the laser-assisted in-situ deposition of Ag NPs on the few-layered GO surface improved its antibacterial properties, in which the hybrid nanostructure synthesized at a longer wavelength exhibited higher antibacterial action resistance to Escherichia coli (E. coli) than Staphylococcus aureus (S. aureus) bacteria. Moreover, nonlinear optical absorption (NLA) of Ag-GO nanohybrid was measured using the open aperture Z-scan technique. The Z-scan results signify the NLA properties of the Ag-GO hybrid material and have a large decline in transmittance of more than 60%, which can be employed as a promising optical limiting (OL) material.
Nano-heterostructures have attracted immense attention recently due to their remarkable interfacial properties determined by the heterointerface of different nanostructures. Here, using first-principles density functional theory (DFT) calculations, we examine what range the variable electronic properties such as the electronic band gap can be tuned by combining two dissimilar nanostructures consisting of atomically thin nanostructured MoS2 clusters with small silver and gold nanoparticles (Ag/Au NPs). Most interestingly, our calculations show that the electronic band gap of the nanostructured MoS2 cluster can be tuned from 2.48 to 1.58 and 1.61 eV, by the formation of heterostructures with silver and gold metal nanoclusters, respectively. This band gap is ideal for various applications ranging from flexible nanoelectronics to nanophotonics applications. Furthermore, the adsorption of H2 molecules on both nano-heterostructures is investigated, and the computed binding energies are found to be within the desirable range. The reported theoretical results provide inspiration for engineering various optoelectronic applications for nanostructured MoS2-based heterostructures.
The COVID-19 has affected all major aspects of the society in a global perspective. The role of nanotechnology is much sought after in fighting this pandemic. Advanced materials based on nanotechnology are the basis of several technologies starting from masks and personal protection equipment to specific diagnostic tools that could diminish the impact of COVID-19. Development of nanotechnology-based products is therefore an absolute necessity for fight against COVID-19. We examine the fundamental concepts related to virology, histopathologic findings and how nanotechnology can help in fighting the disease. In this review we discuss the state of the art and ongoing nanotechnology-based strategies like antiviral coatings, 3D printing and therapeutics to fight against this deadly disease. The importance of using nanoparticles in point of care tests and biosensors is also highlighted.
An energy efficient move toward the regulation of magnetization vector solely with E-field by developing multiferroic (MF) magnetoelectric (ME) nanostructures' have opened up vast avenues for novel low power consumption memories and magnetoelectric devices. The present study delineates the development of multiferroic nanocomposites (MF NCs) with perovskite BiFeO3 and spinel NiFe2O4. A simple Pechini one-pot method is employed for the preparation of nanocomposites with different molar concentrations and the modified structural, magnetic, dielectric, and magnetoelectric performance of NCs is carried out at room temperature. The purity in the crystalline phase of BiFeO3 and NiFe2O4 in the NCs are corroborated by XRD and FTIR spectroscopy, which is further substantiated, while EDAX analysis pointed out the elemental composition. The SEM images provide an evidence for the closely compacted and agglomerated grains with some voids in the prepared sample. A well saturated magnetic hysteresis (M-H) loop reveals long range ferromagnetic ordering and the remanence value ascertains the multidomain structure. The dielectric performance and impedance analysis imparts greater knowledge of the dependence of grain and grain boundaries on the resistive and conductive behavior of the composites. The frequency dependence of electric modulus and impedance exhibits a non-Debye type of relaxation process. The P-E hysteresis loops clearly show the lossy behavior of the composites with an increase in the NiFe2O4 concentration. The ME coupling coefficient of the composites evaluated using the dynamic magnetic field method demonstrates the effective coupling interaction between ferroelectric (FE) perovskite BiFeO3 and ferromagnetic (FM) spinel NiFe2O4. Thus, the findings disclose a greater potential for innovative applications in spintronics and information technology.
Thin films of BiFeO3-NaNbO3 composites were fabricated in a PMMA matrix. XRD and HRTEM were used for structural investigations. The grain size and surface morphology of samples were analysed through HRTEM images. The self-cleaning property of any material accelerates its industrial applications. Hence, along with the optical limiting performance, the photocatalytic and antibacterial activity of BiFeO3-NaNbO3 composite samples were also studied. BiFeO3-NaNbO3 films fabricated in the PMMA matrix exhibit strong optical nonlinearity when excited by 5 ns laser pulses at 532 nm. The origin and magnitude of the observed optical nonlinearity were explained on the basis of the weak absorption saturation and strong excited state absorption. The photocatalytic performance of samples was analysed by dye degradation method using Methyl Orange dye. The dye degradation rate in the presence of the catalyst is heeded in a particular time interval, which exhibits the photocatalytic performance of the samples. The destruction of microbial organisms that are in contact with the material was contemplated, which could prove its antibacterial activity. The effect of the particle size on the photocatalytic activity was also investigated.
A series of interpenetrating polymer networks (IPNs) and semi-interpenetrating polymer networks (s-IPNs) of styrene butadiene rubber (SBR) and poly(methyl methacrylate) (PMMA) have been synthesized by adopting the sequential interpenetration and in situ polymerization method. The size and the concentration of free volume defects in these systems are monitored and their variations accurately traced using positron annihilation lifetime (PALS) and coincidence Doppler broadening spectroscopic (CDBS) measurements. The morphologies of the IPNs were analyzed with transmission electron microscopy (TEM), scanning electron microscopy (SEM) and atomic force microscopy (AFM). Confocal Raman mapping had been employed to elucidate the mechanism of PMMA interpenetration in the SBR matrix with reference to the blend ratio. The results of free volume analysis lead to the conclusion that the increase of PMMA content in IPN was accompanied by enhancement of interpenetration in the system. Also the morphology changes from dispersed island pattern to a co-continuous one. Besides, the transport parameters and mechanical behavior of IPNs were studied in detail. The results of PALS and CDBS measurements have found to exhibit striking correlations with the sorption, mechanical properties and morphology of the polymer networks. The specific physics involved in the characterization protocol is effectively utilized to explore the chemistry of IPN formation. This new modality of characterization versus composition uplifts and widens the application prospects of elastomer-thermoplastic IPNs.
Nanoscale size-dependent properties give nanomaterials unique specifications that are robust in many applications of human medicine. Gold nanoparticles (AuNPs) have recently gained attention because of their unique optical, physical and electrical properties. AuNPs increase the efficacy of biomedical applications in diagnostic treatments for infectious diseases, by targeting or labeling target cells/bioactive compounds. However, it is imperative to develop the regimens for more accurate diagnostic tools, preventive care and effective therapy. Our critical and comprehensive review presents emerging avenues of molecular diagnostics as well as therapeutics translated into clinical approaches. This manuscript critically reviews the rampant future of AuNPs in the diagnosis and treatment of the most important diseases, such as cancer and viruses of respiratory system.
Gold/chemistry , Metal Nanoparticles/chemistry , Antineoplastic Agents/chemistry , Antineoplastic Agents/therapeutic use , Betacoronavirus/isolation & purification , COVID-19 , Coronavirus Infections/diagnosis , Coronavirus Infections/therapy , Coronavirus Infections/virology , Drug Carriers/chemistry , Humans , Lung Diseases/diagnosis , Lung Diseases/therapy , Neoplasms/diagnosis , Neoplasms/drug therapy , Pandemics , Phototherapy , Pneumonia, Viral/diagnosis , Pneumonia, Viral/therapy , Pneumonia, Viral/virology , SARS-CoV-2
Electromagnetic (EM) pollution is ubiquitous and has soared to a great extent in the past few decades. The use of plant sourced cellulose nanofibers to fabricate sustainable and high performance electromagnetic shielding materials is foreseen as a green solution by the electronics industry to address this unseen pollutant. In this view, we report a facile and environmentally benign strategy to synthesize ultra-light and highly conductive aerogels derived from cellulose nanofibers (CNF) decorated with polyaniline (PANI) via a simple in-situ polymerization and subsequent freeze drying process devoid of any volatile organic solvents. The obtained conductive aerogels exhibited density as low as 0.01925â¯g/cc with a maximum EMI shielding value -32â¯dB in X band region. These porous shields demonstrated strong microwave absorption behavior (95 %) with minimal reflection (5 %) coupled with high specific EMI SE value â¼1667â¯dB.cm3.â¯g-1 which make these aerogels a potential candidate for use in telecommunication, military and defense applications.
