Visible light driven (VLD) reduced TiO2-x nanocatalysts designed by inorganic and organic reducing agent-mediated solvothermal methods for electrocatalytic and photocatalytic applications.

This work presents a comparative study on the structural, optical and electrochemical characteristics of visible light driven (VLD) reduced titanium dioxide (TiO2-x ) nanocatalysts synthesized via inorganic and organic synthetic routes. X-ray diffraction (XRD) patterns, Raman spectra and X-ray absorption fine structure (XAFS) analyses reflected anatase phase titania. Whereas, the quantitative EXAFS fit and XANES analysis revealed structural distortion due to the presence of oxygen and titanium vacancies with low valent Ti states in anatase lattices of certain nanocatalysts, which subsequently leads to better electrochemical and photocatalytic activities. Moreover, owing to the large surface area and mesoporous structures, the Mg-TiO2-x nanocatalysts exhibited enhanced water adsorption and ultimately increased overall water splitting with an OER overpotential equal to 420 mV vs. RHE at a current density of 10 mA cm-2 (Tafel slope = 62 mV dec-1), extended visible light absorbance, decreased photoluminescence (PL) intensity and increased carrier lifetime in comparison with commercial titania.

Hydrothermal synthesis and characterization of transition metal (Mn/Fe/Cu) co-doped cerium oxide-based nano-additives for potential use in the reduction of exhaust emission from spark ignition engines.

The goal of this work was to synthesize new cerium oxide-based nano-additives to minimise emissions from spark ignition (SI) engines fueled with gasoline blends, such as carbon monoxide (CO), unburned hydrocarbons (HC) and oxides of nitrogen (NO x ). To investigate the effect of transition metal dopants on their respective catalytic oxidation activity, nano-sized CeO2 catalysts co-doped with Mn, Fe, Cu and Ag ions were successfully produced by a simple hydrothermal technique. The synthesis of nano-catalysts with cubic fluorite geometry was confirmed by XRD data. The addition of transition metal ions to the CeO2 lattice increased the concentration of structural defects like oxygen vacancies and Ce3+ ions, which are advantageous for the catalytic oxidation reaction, as also supported by XAFS and RAMAN analysis. Further, nano-gasoline fuel emission parameters are measured and compared to straight gasoline fuel. The results demonstrated that harmful exhaust pollutants such as CO, HC and NO x were significantly reduced. The high surface area, better redox characteristics and presence of additional oxygen vacancy sites or Ce3+ ions have been linked to the improved catalytic performance of the synthesized catalyst.