Development of tungsten trioxide nano-flakes intercalated on tannic acid-functionalized reduced graphene oxide for flexible acebutolol sensors.

Acebutolol (ACE) is commonly used to treat hypertension and high blood pressure. Large doses of ACE can have adverse effects with potentially life-threatening consequences. It is, therefore, essential to develop a simple, low-cost, reliable, and reproducible device for detecting ACE in biofluids. This study explores the potential of unique two-dimensional nano-flakes, such as tungsten trioxide (WO3). Graphene oxide (GO) typically exhibits lower electrical conductivity than pristine graphene due to the presence of oxygen-containing functional groups that interfere with the π-conjugated structure. Functionalizing GO with tannic acid (TA) can partially reinstate the π-conjugation and limit the amount of oxygen, resulting in enhanced electrical conductivity. Ultrasonic techniques were utilized to create WO3 NFs@TA-rGO, and a range of spectroscopic and microscopic methods were applied to examine the formation of the resulting WO3 NFs@TA-rGO nanocomposites. Under optimal conditions, modified sensors resulted in lower limits of detection (0.0055 µM) and good sensitivity (0.40 µA µM-1 cm-2). They also exhibited a broad linear range spanning from 0.009 to 568.6 µM. Fabricated sensors have significant anti-interference properties with high specificity and excellent storage stability (RSD = 4.3 %), reproducibility (RSD = 3.9 %), and repeatability (RSD = 3.3 %). Ultimately, the sensor's efficacy was confirmed through the successful detection of ACE in biological samples (with recoveries ranging from 99.1 to 99.6 %). Lastly, this study highlights the substantial potential of ACE detection and extends its applications in biomedical diagnostics and pharmaceutical research.

Production of gluconic acid from the washed rice waste water using Au/MgO catalyst - A sustainable route.

The majority of the waste produced by the food and agriculture industries is abundant in proteins, carbohydrates, and fats, which can be utilized effectively in other food products or industrial products. Especially, washed rice water (WRW) contains a significant quantity of starch that has been discarded without being utilized properly. In the present investigation, we have successfully upgraded washed rice water into the industrially important intermediate, i.e., gluconic acid, using an Au/MgO catalyst in a single pot reaction. The upgrading strategy was developed in three consecutive phases using two different model reactions: (1) glucose to gluconic acid, (2) hydrolysis of starch into glucose, followed by the oxidation reaction. The results showed that almost 60% gluconic acid was achieved at room temperature with atmospheric pressure. The present investigation highlighted that hydrolysis, followed by oxidation reaction is the most promising route for upgrading WRW to gluconic acid.

Green composites for sustainable food packaging: Exploring the influence of lignin-TiO2 nanoparticles on poly(butylene adipate-co-terephthalate).

Titanium dioxide (TiO2) is a common pigment used in food packaging to provide a transparent appearance to plastic packaging materials. In the present study, poly(butylene adipate-co-terephthalate) (PBAT) incorporated with lignin-TiO2 nanoparticles (L-TiO2) eco-friendly composite films was prepared by employing an inexpensive melting and hot-pressing technique. The P-L-TiO2 composite films have been studied using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), Thermogravimetric analysis (TGA), and Differential scanning calorimetry (DSC) analysis. The FTIR results and homogeneous, dense SEM images confirm the interaction of L-TiO2 with the PBAT matrix. It has also been found that the addition of L-TiO2 nanoparticles can increase the crystallinity, tensile strength, and thermal stability of PBAT. The addition of L-TiO2 increased the tensile strength and decreased the elongation at break of films. The maximum tensile strength of the film, achieved with 5 wt% L-TiO2, was 47.0 MPa, compared with 24.3 MPa for pure PBAT film. The composite film with 5 wt% L-TiO2 has outstanding oxygen and water vapor barrier properties. As the content of lignin-TiO2 increases, the antimicrobial activity of the composite films also increases; the percentage of growth of all the tested bacteria Staphylococcus aureus (S. aureus), and Escherichia coli (E. coli) is significantly reduced. Strawberries were packed to evaluate the suitability of produced composite films as packaging materials, as they effectively preserved pigments from accumulation and extended the shelf-life as compared to commercial polyethylene packaging film.

Synthesis of bis(2-aminoethyl)amine functionalized mesoporous silica (SBA-15) adsorbent for selective adsorption of Pb2+ ions from wastewater.

Rapid growth in the industry has released large quantities of contaminants, particularly metal discharges into the environment. Heavy metal poisoning in water bodies has become a major problem due to its toxicity to living organisms. In this study, we developed a 3-chloropropyl triethoxysilane incorporated mesoporous silica nanoparticle (SBA-15) based adsorbent utilizing the sol-gel process and Pluronic 123 (P123) as a structure-directing surfactant. Furthermore, the produced SBA-15 NPs were functionalized with bis(2-aminoethyl)amine (BDA) using the surface grafting approach. The physical and chemical properties of the prepared SBA-15@BDA NPs were determined using a variety of instruments, including small-angle X-ray diffraction (SAXS), Fourier-transform infrared (FTIR), scanning electron microscope (SEM), N2 adsorption-desorption, thermogravimetric, particle size distribution, and zeta potential analysis. The MSN has a large surface area of up to 574 m2/g, a pore volume of 0.57 cm3/g, and a well-ordered mesoporous nanostructure with an average pore size of 3.6 nm. The produced SBA-15@BDA NPs were used to adsorb selectively to lead (Pd2+) ions from an aqueous solution. The adsorption study was performed under various conditions, including the influence of solution pH, adsorbent dose, adsorption kinetics, adsorption selectivity in the presence of competing metal ions, and reusability. The results of the kinetic study demonstrated that SBA-15@BDA NPs absorb selectively Pb2+ ions via chemisorption. The SBA-15@BDA NPs show Pb2+ ions with a maximum adsorption capacity of ~ 88% and an adsorbed quantity of approximately ~ 112 mg/g from the studied aqueous solution. The adsorption mechanism relies on coordination bonding between Pb2+ ions and surface-functionalized amine groups on SBA-15@BDA NPs. Furthermore, the proposed SBA-15@BDA NPs adsorbent demonstrated excellent reusability over five cycles without significantly reducing adsorption performance. As a consequence, SBA-15@BDA NPs might serve as an effective adsorbent for the selective removal of Pb2+ ions from aqueous effluent.

Fabrication of Sandwiched NiCo-Layered Double Hydroxides/Carbon Nanoballs for Sustainable Energy Storage.

This study presents a promising method for creating high-performance supercapacitor electrodes. The approach involves crafting a unique composite material-nickel-cobalt-layered double hydroxides (NiCo-LDH) grown on carbon nanoballs (CNBs). This is achieved by first creating a special carbon material rich in oxygen and nitrogen from a polybenzoxazine source. At first, eugenol, ethylene diamine and paraformaldehyde undergo Mannich condensation to form the benzoxazine monomer, which undergoes self-polymerization in the presence of heat to produce polybenzoxazine. This was then carbonized and activated to produce CNBs containing heteroatoms. Then, through a hydrothermal technique, NiCo-LDH nanocages are directly deposited onto the CNBs, eliminating the need for complicated templates. The amount of CNBs used plays a crucial role in performance. By optimizing the CNB content to 50%, a remarkable specific capacitance of 1220 F g-1 was achieved, along with excellent rate capability and impressive cycling stability, retaining 86% of its capacitance after 5000 cycles. Furthermore, this NiCo-LDH/CNB composite, when combined with active carbon in a supercapacitor configuration, delivered outstanding overall performance. The exceptional properties of this composite, combined with its simple and scalable synthesis process, position it as a strong contender for next-generation sustainable energy storage devices. The ease of fabrication also opens doors for its practical application in advancing energy storage technologies.

Adolescent Female Users' Avatar Creation in Social Virtual Worlds: Opportunities and Challenges.

Many adolescent females are active online, finding creative ways to express themselves through evolving social media technologies. Social virtual worlds (SVWs), distinguished by extensive avatar customization features, provide them with unique opportunities to craft virtual identities and explore diverse facets of self-presentation. This study investigates adolescent females' construction of avatars in Zepeto, a South Korea-based global SVW platform. Employing social representation theory (SRT) as a theoretical framework, this study conducted in-depth interviews with adolescent female Zepeto users to uncover their perceptions of and motivations behind avatar creation in SVWs, as well as to explore how the interplay of virtual and real worlds presents them with various opportunities and challenges. While the prospects of SVWs remain uncertain, examining how these young users interpret and experience SVWs contributes to identifying potential strategies to enhance the sustainability of these platforms.

Enhanced Wettability and Adhesive Property of PTFE through Surface Modification with Fluorinated Compounds.

Polytetrafluoroethylene (PTFE) is prized for its unique properties in electrical applications, but its natural hydrophobicity poses challenges as it repels water and can cause electrical short circuits, shortening equipment lifespan. In this work, the mentioned issue has been tackled by using two different fluorinated compounds, such as perfluorooctanoic acid (PFOA)/perfluorooctanol (PFOL), along with plasma processing to enhance the surface hydrophilicity (water attraction) of PTFE. This method, demonstrated on Teflon membrane, quickly transformed their surfaces from hydrophobic to hydrophilic in less than 30 s. The treated films achieved a water contact angle saturation of around 80°, indicating a significant increase in water affinity. High-resolution C 1s X-ray photoelectron spectroscopy (XPS) confirmed the formation of new bonds, such as -COOH and -OH, on the surface, responsible for enhanced hydrophilicity. Extended plasma treatment led to further structural changes, evidenced by increased intensity in infrared (IR) and Raman spectra, particularly sensitive to vibrations associated with the C-F bond. Moreover, Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR) showed the formation of surface-linked functional groups, which contributed to the improved water attraction. These findings decisively show that treatment with fluoro-compound along with plasma processing can be considered as a highly effective and rapid method for converting PTFE surfaces from hydrophobic to hydrophilic, facilitating its broader use in various electrical applications.

State-of-the-art progress on locust bean gum polysaccharide for sustainable food packaging and drug delivery applications: A review with prospectives.

Locust bean gum (LBG), a polysaccharide-based natural polymer, is being widely researched as an appropriate additive for various products, including food, gluten-free formulations, medicines, paper, textiles, oil well drilling, cosmetics, and medical uses. Drug delivery vehicles, packaging, batteries, and catalytic supports are all popular applications for biopolymer-based materials. This review discusses sustainable food packaging and drug delivery applications for LBG. Given the benefits of LBG polysaccharide as a source of dietary fiber, it is also being investigated as a potential treatment for many health disorders, including colorectal cancer, diabetes, and gastrointestinal difficulties. The flexibility of LBG polysaccharide allows it to form hydrogen bonds with water molecules, a crucial characteristic of biomaterials, and the film-forming properties of LBG are critical for food packaging applications. The extraction process of LBG plays an important role in properties such as viscosity and gel-forming properties. Moreover, there are multiple factors such as temperature, pressure, pH, etc. The LBG-based functional composite film is effective in improving the shelf life as well as monitoring the freshness of fruits, meat and other processed food. The LBG-based hydrogel is excellent carrier of drugs and can be used for slow and sustainable release of active components present in drugs. Thus, the primary goal of this review was to conduct a comprehensive evaluation of the literature with a focus on the composition, properties, processing, food packaging, and medicine delivery applications of LBG polysaccharides. Thus, we investigated the chemical composition, extraction, and characteristics of LBG polysaccharides that underlie their applications in the food packaging and medicine delivery fields.

Conductive Polymer-Based Hydrogels for Wearable Electrochemical Biosensors.

Hydrogels are gaining popularity for use in wearable electronics owing to their inherent biomimetic characteristics, flexible physicochemical properties, and excellent biocompatibility. Among various hydrogels, conductive polymer-based hydrogels (CP HGs) have emerged as excellent candidates for future wearable sensor designs. These hydrogels can attain desired properties through various tuning strategies extending from molecular design to microstructural configuration. However, significant challenges remain, such as the limited strain-sensing range, significant hysteresis of sensing signals, dehydration-induced functional failure, and surface/interfacial malfunction during manufacturing/processing. This review summarizes the recent developments in polymer-hydrogel-based wearable electrochemical biosensors over the past five years. Initially serving as carriers for biomolecules, polymer-hydrogel-based sensors have advanced to encompass a wider range of applications, including the development of non-enzymatic sensors facilitated by the integration of nanomaterials such as metals, metal oxides, and carbon-based materials. Beyond the numerous existing reports that primarily focus on biomolecule detection, we extend the scope to include the fabrication of nanocomposite conductive polymer hydrogels and explore their varied conductivity mechanisms in electrochemical sensing applications. This comprehensive evaluation is instrumental in determining the readiness of these polymer hydrogels for point-of-care translation and state-of-the-art applications in wearable electrochemical sensing technology.

Examining spatiotemporal crowdsensing and caching for population-dynamic OTT content delivery.

This study proposes a novel spatiotemporal crowdsensing and caching (SCAC) framework to address the surging demands of urban wireless network traffic. In the context of rampant urbanization and ubiquitous digitization in cities, effective data traffic management is crucial for maintaining a dynamic urban ecosystem. Leveraging user mobility patterns and content preferences, this study formulates an offloading policy to alleviate congestion across urban areas. Our approach uses an AI-based method at the cell level, providing a practical and scalable solution that can be readily adapted to bustling metropolitan areas. The implementation of our model demonstrated its effectiveness in reflecting real-world urban dynamics, resulting in significant reductions in peak-hour traffic and robust performance across diverse urban settings. The deployment strategy initiates from densely populated transportation hubs, gradually expanding to broader urban areas. This systematic expansion adheres to a policy framework that emphasizes data privacy and sustainable urban development, ensuring alignment with societal needs and regulatory frameworks. By addressing technological efficacy and societal impact, this study enhances the understanding of urban wireless traffic management. It offers mobile network operators, policymakers, and urban planners a comprehensive strategy to harness the potential of spatiotemporal technology, thereby ensuring that cities remain dynamic, efficient, and well-prepared for the future of digital connectivity.

Factors Influencing Users' Perceptions of Digital Platform Indispensability: A Comparative Study of Korea and Finland.

The pervasive integration of digital platforms into daily life has amplified their perceived indispensability. This study investigates the factors influencing this perception across countries with contrasting platform landscapes, focusing on platform quality and usage patterns. We conducted surveys in Finland and Korea, countries representing distinct platform ecosystems. The results revealed higher perceived indispensability in Korea than in Finland, with usefulness and habitual platform use emerging as significant predictors of indispensability in both countries. However, the specific aspects of platform quality influencing this perception diverged. In Finland, the platform's comprehensiveness and security risk significantly impacted indispensability, while social interaction features played a negligible role. Conversely, in Korea, social interaction features significantly influenced indispensability, while platform comprehensiveness and security risk were non-significant. These findings underscore the multifaceted nature of digital platform indispensability, shaped by the interaction of platform quality and usage patterns. The contextual variations highlighted by our cross-country comparison suggest that a one-size-fits-all approach to platform regulation or user education may be ineffective. Future research should explore these cultural and platform-specific nuances to devise tailored policies.

Electron Beam-Supported Fabrication of Biocompatible Silver/iota-Carrageenan for Wound Healing Application.

Silver nanoparticles (AgNPs) are a potent antibacterial agent, especially when used to treat bacteria that are multidrug resistant. However, it is challenging to eliminate the hazardous reducing agents that remain in AgNPs produced by the conventional chemical reduction process. To overcome these challenges, the presented research demonstrates the fabrication of AgNPs using iota-carrageenan (ι-carra) as a carbohydrate polymer using electron beam (EB) irradiation. Well-characterized ι-carra@AgNPs have a face-centered cubic (FCC) structure with spherical morphology and an average size of 26 nm. Herein we explored the approach for fabricating ι-carra@AgNPs that is suitable for scaling up the production of nanoparticles that exhibit excellent water stability. Further, the optimized ι-carra@AgNPs exhibited considerable antibacterial activity of 40% and 30% inhibition when tested with Gram-negative Escherichia coli ATCC 43895 and Gram-positive Staphylococcus aureus (S. aureus) (ATCC 6538), respectively, and low cytotoxicity at 10-50 µg/mL. To establish the potential biomedical application, as proof of the concept, the ι-carra@AgNPs showed significant antibiofilm activity at 20 µg/mL and also showed 95% wound healing abilities at 50 µg/mL compared to the nontreated control groups. Electron beam assisted ι-carra@AgNPs showed significant beneficial effects against specific bacterial strains and may provide a guide for the development of new antibacterial materials for wound dressing for large-scale production for biomedical applications.

Eco-Friendly Poly (Butylene Adipate-co-Terephthalate) Coated Bi-Layered Films: An Approach to Enhance Mechanical and Barrier Properties.

In this research work, a coated paper was prepared with poly (butylene adipate-co-terephthalate) (PBAT) film to explore its use in eco-friendly food packaging. The paper was coated with PBAT film for packaging using hot pressing, a production method currently employed in the packaging industry. The coated papers were evaluated for their structural, mechanical, thermal, and barrier properties. The structural morphology and chemical analysis of the coated paper confirmed the consistent formation of PBAT bi-layered on paper surfaces. Surface coating with PBAT film increased the water resistance of the paper samples, as demonstrated by tests of barrier characteristics, including the water vapor transmission rate (WVTR), oxygen transmission rate (OTR), and water contact angle (WCA) of water drops. The transmission rate of the clean paper was 2010.40 cc m-2 per 24 h for OTR and 110.24 g m-2 per 24 h for WVTR. If the PBAT-film was coated, the value decreased to 91.79 g m-2 per 24 h and 992.86 cc m-2 per 24 h. The hydrophobic nature of PBAT, confirmed by WCA measurements, contributed to the enhanced water resistance of PBAT-coated paper. This result presents an improved PBAT-coated paper material, eliminating the need for adhesives and allowing for the fabrication of bi-layered packaging.

Synergistic Blends of Sodium Alginate and Pectin Biopolymer Hosts as Conducting Electrolytes for Electrochemical Applications.

The world needs sustainable energy resources with affordable, economic, and accountable sources. Consequently, energy innovation technologies are evolving toward electrochemical applications like batteries, supercapacitors, etc. The current study involves the solid blend biopolymer electrolyte (SBBE) with different compositions of sodium alginate blended with pectin via the casting technique. The characterization of the sample was tested by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, AC impedance, linear sweep voltammetry (LSV), and cyclic voltammetry (CV) analyses. Evidently, the sample NP4 (NaAlg/pectin = 60:40 wt %) has a higher conductivity of 1.26 × 10-7 and 3.25 × 10-6 S cm-1 at 303 and 353 K, respectively. The performances of the samples were analyzed with variations in temperature, frequency, and time responses to signify the blended nature of the electrolyte. Hence, the studied biopolymers can be constructed for electrochemical device applications.

Chitosan-Based Films Blended with Tannic Acid and Moringa Oleifera for Application in Food Packaging: The Preservation of Strawberries (Fragaria ananassa).

Biobased plastics provide a sustainable alternative to conventional food packaging materials, thereby reducing the environmental impact. The present study investigated the effectiveness of chitosan with varying levels of Moringa oleifera seed powder (MOSP) and tannic acid (TA). Chitosan (CS) biocomposite films with tannic acid acted as a cross-linker, and Moringa oleifera seed powder served as reinforcement. To enhance food packaging and film performance, Moringa oleifera seed powder was introduced at various loadings of 1.0, 3.0, 5.0, and 10.0 wt.%. Fourier-transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy analyses were performed to study the structure and morphology of the CS/TA/MOSP films. The scanning electron microscopy results confirmed that chitosan/TA with 10.0 wt.% of MOSP produced a lightly miscible droplet/matrix structure. Furthermore, mechanical properties, swelling, water solubility, optical barrier, and water contact angle properties of the film were also calculated. With increasing Moringa oleifera seed powder contents, the biocomposite films' antimicrobial and antifungal activity increased at the 10.0 wt.% MOSP level; all of the observed bacteria [Staphylococcus aureus (S. aureus), Escherichia coli (E. coli), Aspergillus niger (A. niger), and Candida albicans (C. albicans)] had a notably increased percentage of growth. The film, with 10.0 wt.% MOSP content, effectively preserves strawberries' freshness, making it an ideal food packaging material.

A Study on the Antibacterial, Antispasmodic, Antipyretic, and Anti-Inflammatory Activity of ZnO Nanoparticles Using Leaf Extract from Jasminum sambac (L. Aiton).

The green synthesis of zinc oxide nanoparticles (ZnO NPs) using plants has grown in significance in recent years. ZnO NPs were synthesized in this work via a chemical precipitation method with Jasminum sambac (JS) leaf extract serving as a capping agent. These NPs were characterized using UV-vis spectroscopy, FT-IR, XRD, SEM, TEM, TGA, and DTA. The results from UV-vis and FT-IR confirmed the band gap energies (3.37 eV and 3.50 eV) and the presence of the following functional groups: CN, OH, C=O, and NH. A spherical structure and an average grain size of 26 nm were confirmed via XRD. The size and surface morphology of the ZnO NPs were confirmed through the use of SEM analysis. According to the TEM images, the ZnO NPs had an average mean size of 26 nm and were spherical in shape. The TGA curve indicated that the weight loss starts at 100 °C, rising to 900 °C, as a result of the evaporation of water molecules. An exothermic peak was seen during the DTA analysis at 480 °C. Effective antibacterial activity was found at 7.32 ± 0.44 mm in Gram-positive bacteria (S. aureus) and at 15.54 ± 0.031 mm in Gram-negative (E. coli) bacteria against the ZnO NPs. Antispasmodic activity: the 0.3 mL/mL sample solution demonstrated significant reductions in stimulant effects induced by histamine (at a concentration of 1 µg/mL) by (78.19%), acetylcholine (at a concentration of 1 µM) by (67.57%), and nicotine (at a concentration of 2 µg/mL) by (84.35%). The antipyretic activity was identified using the specific Shodhan vidhi method, and their anti-inflammatory properties were effectively evaluated with a denaturation test. A 0.3 mL/mL sample solution demonstrated significant reductions in stimulant effects induced by histamine (at a concentration of 1 µg/mL) by 78.19%, acetylcholine (at a concentration of 1 µM) by 67.57%, and nicotine (at a concentration of 2 µg/mL) by 84.35%. These results underscore the sample solution's potential as an effective therapeutic agent, showcasing its notable antispasmodic activity. Among the administered doses, the 150 mg/kg sample dose exhibited the most potent antipyretic effects. The anti-inflammatory activity of the synthesized NPs showed a remarkable inhibition percentage of (97.14 ± 0.005) at higher concentrations (250 µg/mL). Furthermore, a cytotoxic effect was noted when the biologically synthesized ZnO NPs were introduced to treated cells.

pNIPAm-Based pH and Thermoresponsive Copolymer Hydrogel for Hydrophobic and Hydrophilic Drug Delivery.

The regulated and targeted administration of hydrophobic and hydrophilic drugs is both promising and challenging in the field of drug delivery. Developing a hydrogel which is responsive to dual stimuli is considered a promising and exciting research area of study. In this work, melamine functionalized poly-N-isopropyl acrylamide-co-glycidyl methacrylate copolymer has been developed by copolymerizing glycidyl methacrylate (GMA) monomer with N-isopropyl acrylamide (NIPAm) and further functionalized with melamine units (pNIPAm-co-pGMA-Mela). The prepared pNIPAm-co-pGMA-Mela copolymer hydrogel was characterized using various characterization techniques, including 1H NMR, FTIR, SEM, zeta potential, and particle size analysis. A hydrophobic drug (ibuprofen, Ibu) and hydrophilic drug (5-fluorouracil, 5-Fu) were selected as model drugs. Dual pH and temperature stimuli-responsive drug release behavior of the pNIPAm-co-pGMA-Mela hydrogel was evaluated under different pH (pH 7.4 and 4.0) and temperature (25 °C, 37 °C, and 45 °C) conditions. Furthermore, the in vitro biocompatibility of the developed pNIPAm-co-pGMA-Mela copolymer hydrogel was determined on MDA-MB-231 cells. The pH and temperature-responsive drug delivery study results reveal that the pNIPAm-co-pGMA-Mela hydrogel system is responsive to both pH and temperature stimuli and exhibits about ~100% of Ibu and 5-Fu, respectively, released at pH 4.0/45 °C. Moreover, the MTT assay and hemocompatibility analysis results proved that the pNIPAm-co-pGMA-Mela hydrogel system is biocompatible and hemocompatible, suggesting that that it could be used for drug delivery applications. The experimental results suggest that the proposed pNIPAm-co-pGMA-Mela hydrogel system is responsive to dual pH and temperature stimuli, and could be a promising drug carrier system for both hydrophilic and hydrophobic drug delivery applications.

Flexible Composite Hydrogels Based on Polybenzoxazine for Supercapacitor Applications.

Polybenzoxazines (Pbzs) are advanced forms of phenolic resins that possess many attractive properties, including thermal-induced self-curing polymerization, void-free polymeric products and absence of by-product formation. They also possess high Tg (glass transition temperature) and thermal stability. But the produced materials are brittle in nature. In this paper, we present our attempt to decrease the brittleness of Pbz by blending it with polyvinylalcohol (PVA). Benzoxazine monomer (Eu-Ed-Bzo) was synthesized by following a simple Mannich condensation reaction. The formation of a benzoxazine ring was confirmed by FT-IR and NMR spectroscopic analyses. The synthesized benzoxazine monomer was blended with PVA in order to produce composite films, PVA/Pbz, by varying the amount of benzoxazine monomer (1, 3 and 5 wt. % of PVA). The property of the composite films was studied using various characterization techniques, including DSC, TGA, water contact angle analysis (WCA) and SEM. WCA analysis proved that the hydrophobic nature of Pbz (value) was transformed to hydrophilic (WCA of PVA/Pbz5 is 35.5°). These composite films could play the same role as flexible electrolytes in supercapacitor applications. For this purpose, the composite films were immersed in a 1 M KOH solution for 12 h in order to analyze their swelling properties. Moreover, by using this swelled gel, a symmetric supercapacitor, AC//PVA/Pbz5//AC, was constructed, exhibiting a specific capacitance of 170 F g-1.

Understanding Mobile OTT Service Users' Resistance to Participation in Wireless D2D Caching Networks.

With the explosive pace of mobile over-the-top (OTT) video content streaming services, mobile network traffic has seen unprecedented growth in recent years. However, the limitation of antenna performance, the burden of investment cost, and restricted resources hinder improving the current mobile networks' functionality. Accordingly, wireless device-to-device (D2D) caching networks came to the fore as one of the competitive alternatives for alleviating the overloads of mobile network traffic. Wireless D2D caching networks can be a desirable alternative for OTT service providers and telecommunication operators, but the problem is user resistance. User participation is imperative to deliver wireless D2D caching network functionality successfully. Thus, to gain a deeper understanding of user resistance toward wireless D2D caching networks and their underlying sources, this study introduces two perceived cost factors contributing to this resistance and one perceived benefit that mitigates such resistance. Based on an online survey, this study found new theoretical links among perceived costs and benefits, resistance, and participation intention. The findings reveal that user resistance is predicted by perceived costs, encompassing resource sacrifices and privacy concerns, whereas perceived benefits-specifically, perceived usefulness-did not significantly influence resistance. This implies that telecommunication operators should prioritize market requirements over technological advantages, emphasizing the potential for successful commercialization of wireless D2D caching networks.