Identification of Lithium Compounds on Surfaces of Lithium Metal Anode with Machine-Learning-Assisted Analysis of ToF-SIMS Spectra.

Detailed knowledge about contamination and passivation compounds on the surface of lithium metal anodes (LMAs) is essential to enable their use in all-solid-state batteries (ASSBs). Time-of-flight secondary ion mass spectrometry (ToF-SIMS), a highly surface-sensitive technique, can be used to reliably characterize the surface status of LMAs. However, as ToF-SIMS data are usually highly complex, manual data analysis can be difficult and time-consuming. In this study, machine learning techniques, especially logistic regression (LR), are used to identify the characteristic secondary ions of 5 different pure lithium compounds. Furthermore, these models are applied to the mixture and LMA samples to enable identification of their compositions based on the measured ToF-SIMS spectra. This machine-learning-based analysis approach shows good performance in identifying characteristic ions of the analyzed compounds that fit well with their chemical nature. Moreover, satisfying accuracy in identifying the compositions of unseen new samples is achieved. In addition, the scope and limitations of such a strategy in practical applications are discussed. This work presents a robust analytical method that can assist researchers in simplifying the analysis of the studied lithium compound samples, offering the potential for broader applications in other material systems.

Prediction of ground reaction force and joint moments based on optical motion capture data during gait.

The standard camera- and force plate-based set-up for motion analysis suffers from the disadvantage of being limited to laboratory settings. Since adaptive algorithms are able to learn the connection between known inputs and outputs and generalise this knowledge to unknown data, these algorithms can be used to leverage motion analysis outside the laboratory. In most biomechanical applications, feedforward neural networks are used, although these networks can only work on time normalised data, while recurrent neural networks can be used for real time applications. Therefore, this study compares the performance of these two kinds of neural networks on the prediction of ground reaction force and joint moments of the lower limbs during gait based on joint angles determined by optical motion capture as input data. The accuracy of both networks when generalising to new data was assessed using the normalised root-mean-squared error, the root-mean-squared error and the correlation coefficient as evaluation metrics. Both neural networks demonstrated a high performance and good capabilities to generalise to new data. The mean prediction accuracy over all parameters applying a feedforward network was higher (r = 0.963) than using a recurrent long short-term memory network (r = 0.935).

Artificial Neural Networks in Motion Analysis-Applications of Unsupervised and Heuristic Feature Selection Techniques.

The use of machine learning to estimate joint angles from inertial sensors is a promising approach to in-field motion analysis. In this context, the simplification of the measurements by using a small number of sensors is of great interest. Neural networks have the opportunity to estimate joint angles from a sparse dataset, which enables the reduction of sensors necessary for the determination of all three-dimensional lower limb joint angles. Additionally, the dimensions of the problem can be simplified using principal component analysis. Training a long short-term memory neural network on the prediction of 3D lower limb joint angles based on inertial data showed that three sensors placed on the pelvis and both shanks are sufficient. The application of principal component analysis to the data of five sensors did not reveal improved results. The use of longer motion sequences compared to time-normalised gait cycles seems to be advantageous for the prediction accuracy, which bridges the gap to real-time applications of long short-term memory neural networks in the future.

Estimation of Gait Mechanics Based on Simulated and Measured IMU Data Using an Artificial Neural Network.

Enhancement of activity is one major topic related to the aging society. Therefore, it is necessary to understand people's motion and identify possible risk factors during activity. Technology can be used to monitor motion patterns during daily life. Especially the use of artificial intelligence combined with wearable sensors can simplify measurement systems and might at some point replace the standard motion capturing using optical measurement technologies. Therefore, this study aims to analyze the estimation of 3D joint angles and joint moments of the lower limbs based on IMU data using a feedforward neural network. The dataset summarizes optical motion capture data of former studies and additional newly collected IMU data. Based on the optical data, the acceleration and angular rate of inertial sensors was simulated. The data was augmented by simulating different sensor positions and orientations. In this study, gait analysis was undertaken with 30 participants using a conventional motion capture set-up based on an optoelectronic system and force plates in parallel with a custom IMU system consisting of five sensors. A mean correlation coefficient of 0.85 for the joint angles and 0.95 for the joint moments was achieved. The RMSE for the joint angle prediction was smaller than 4.8° and the nRMSE for the joint moment prediction was below 13.0%. Especially in the sagittal motion plane good results could be achieved. As the measured dataset is rather small, data was synthesized to complement the measured data. The enlargement of the dataset improved the prediction of the joint angles. While size did not affect the joint moment prediction, the addition of noise to the dataset resulted in an improved prediction accuracy. This indicates that research on appropriate augmentation techniques for biomechanical data is useful to further improve machine learning applications.

Prediction of lower limb joint angles and moments during gait using artificial neural networks.

In recent years, gait analysis outside the laboratory attracts more and more attention in clinical applications as well as in life sciences. Wearable sensors such as inertial sensors show high potential in these applications. Unfortunately, they can only measure kinematic motions patterns indirectly and the outcome is currently jeopardized by measurement discrepancies compared with the gold standard of optical motion tracking. The aim of this study was to overcome the limitation of measurement discrepancies and the missing information on kinetic motion parameters using a machine learning application based on artificial neural networks. For this purpose, inertial sensor data-linear acceleration and angular rate-was simulated from a database of optical motion tracking data and used as input for a feedforward and long short-term memory neural network to predict the joint angles and moments of the lower limbs during gait. Both networks achieved mean correlation coefficients higher than 0.80 in the minor motion planes, and correlation coefficients higher than 0.98 in the sagittal plane. These results encourage further applications of artificial intelligence to support gait analysis. Graphical Abstract The graphical abstract displays the processing of the data: IMU data is used as input to a feedforward and a long short-term memory neural network to predict the joint kinematics and kinetics of the lower limbs during gait.

Intelligent prediction of kinetic parameters during cutting manoeuvres.

Due to its capabilities in analysing injury risk, the ability to analyse an athlete's ground reaction force and joint moments is of high interest in sports biomechanics. However, using force plates for the kinetic measurements influences the athlete's performance. Therefore, this study aims to use a feed-forward neural network to predict hip, knee and ankle joint moments as well as the ground reaction force from kinematic data during the execution and depart contact of a maximum effort 90° cutting manoeuvre. A total number of 525 cutting manoeuvres performed by 55 athletes were used to train and test neural networks. Either marker trajectories or joint angles were used as input data. The correlation coefficient between the measured and predicted data indicated strong correlations. By using joint angles as the input parameters, slightly but not significantly higher accuracy was found in joint moments predictions. The prediction of the ground reaction force showed significantly higher accuracy when using marker trajectories. Hence, the proposed feed-forward neural network method can be used to predict motion kinetics during a fast change of direction. This may allow for the simplification of cutting manoeuvres experimental set-ups for and through the use of inertial sensors. Graphical abstract The left part of the graphical abstract displays the angle progression of the hip, knee and ankle joint as an example of the kinematic input data and is supported by a stick figure of the motion task, a 90° cutting manoeuvre. This data is used to train a feed-forward neural network, which is displayed in the middle. The neural network's output is displayed on the right. As an example of the kinetic data, the joint moments of hip, knee and ankle joint are displayed and supported by a stick figure.