Formation of nanostructured MnO/Co/solid-electrolyte interphase ternary composites as a durable anode material for lithium-ion batteries.

Nanoporous MnO frameworks with highly dispersed Co nanoparticles were produced from MnCO3 precursors prepared in a gel matrix. The MnO frameworks that contain 20 mol% Co exhibited excellent cycle performance as an anode material for Li-ion batteries. The solid-electrolyte interphase (SEI) formed in the frameworks through the electrochemical reaction mediates the active materials, such as MnO, Mn, and Li2O, during the conversion reaction in the charge-discharge cycle. The Co nanoparticles and SEI provide the electron and Li-ion conductive networks, respectively. The ternary nanocomposites of the MnO framework, metallic Co nanoparticles, and embedded SEI are categorized as durable anode materials for Li-ion batteries.

Biomimetic synthesis of metal ion-doped hierarchical crystals using a gel matrix: formation of cobalt-doped LiMn(2)O(4) with improved electrochemical properties through a cobalt-doped MnCO(3) precursor.

We have synthesized spinel type cobalt-doped LiMn(2)O(4) (LiMn(2-y)Co(y)O(4), 0