RESUMEN
Cellulosic ethanol could play a major role in the upcoming circular-economy once the process complexity, low carbohydrate extraction yields and high costs are resolved. To this purpose, different steam-treatment severity factors were employed on whole sweet sorghum biomass, followed by the delignification and hydrolysis of resulted lignocellulose fibers. A modified ASTM International (American Society for Testing and Material) standard cellulose hydrolysis approach as well as a newly developed SACH (Sulfuric Acid Cellulose Hydrolysis) process were used, recovering up to 24.3â¯wt% of cellulosic carbohydrates. This amounted to a total extractable and constitutive carbohydrate recovery of 51.7â¯wt% (dry basis) when a mild steam-treatment of whole sorghum biomass and the SACH cellulose hydrolysis were employed. An ethanol potential of 6378 L/ha/year was determined, comparable to values obtained from biomass such as sugarcane in warmer climates, supporting thus the opportunity of implementing this novel approach on a wider scale.
Asunto(s)
Sorghum , Vapor , Biomasa , Etanol , Fermentación , Hidrólisis , LigninaRESUMEN
Sweet sorghum was subjected to an impregnation step, which recovered most of the 1st generation sugars, prior to a steam-treatment extraction of the 2nd generation sugars, at three different severity factors (SF). A medium severity (3.56â¯SF) treatment proved to be an optimal compromise between the amount of sugars extracted and the fermentation inhibitors generated following the subsequent depolymerization approaches applied on the broth. Next, a series of detoxification approaches (ozonation, overliming and a combination of both) were investigated following a concentration and depolymerization step. Results show that higher steam-treatment severity required more intense detoxification steps. However, when combining the 1st and 2nd generation streams at a 2:1 ratio, the inhibitors did not affect the fermentation process and ethanol yields above 90% of the theoretical maximum were achieved.