Development and characterization of a biodegradable film based on guar gum-gelatin@sodium alginate for a sustainable environment.

A significant amount of plastic trash has been dumped into the environment across the world, contributing to the present white pollution crisis. Therefore, plastic manufacturing and disposal must be examined. Biodegradable plastics (BPs) have recently become the subject of study due to their beneficial biodegradability and harmlessness, and they have been the most efficient method for addressing the issue of plastic pollution. This study aims to enhance the synthesis of biodegradable polymers from sodium alginate (Na-Alg) with the addition of guar gum, corn starch, and gelatin using the solution-casting method, followed by mixing in suitable proportions and drying at a certain temperature, resulting in thin film formation. To enhance qualities of the already produced polymer, additional substances such as glycerol, PVA, and latex were added as plasticizers. Characterization techniques such as scanning electron microscopy (SEM), tensile strength, thermogravimetric analysis (TGA), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), UV-vis spectroscopy, and Fourier transform infrared (FTIR) spectroscopy were used to study structural characteristics, surface morphology, polymeric linkages, water absorption capabilities, chemical conductivity, and light transmittance of the newly formed films. These characterization results depict a remarkable achievement in the sense of the high degradability and impressive tensile strength of the newly formed films. In addition, SEM images indicated a porous structure with interconnected pores. FT-IR confirms the occurrence of molecular interactions between separate components. Consequently, different films showed different behavior of degradability, and it is suggested from interpreting the results that the polymeric films may be a viable biodegradable option.

Development of Plumeria alba extract supplemented biodegradable films containing chitosan and cellulose derived from bagasse and corn cob waste for antimicrobial food packaging.

With the increase in global plastic pollution due to conventional plastic packaging (petroleum-derived), bioplastics have emerged as an alternative green source for practising a circular economy. This research aimed to extract cellulose from bagasse and corn cob waste and utilized in mixed form to prepare bioplastic film. The mixed cellulose was further reinforced with natural substances such as chitosan, bentonite, and P. alba extract. These newly developed bioplastics films were characterized by various physical tests like film thickness, moisture content, water solubility and spectroscopic techniques such as Fourier transform infrared (FTIR), scanning electron microscopy-energy dispersive spectroscopic (SEM-EDX), thermal gravimetric analysis (TGA), and ultraviolet-visible (UV-Vis) spectroscopy for opacity testing. The results revealed the enhanced bioplastic thermal and mechanical characteristics through robust interactions between cellulose and bentonite molecules. Moreover, incorporating chitosan solution as reinforcements in bio-composite films resulted in improved water barrier properties. The results indicated lower absorption in the UV range of 250-400 nm, attributed to the absence of UV-absorbing groups. Finally, their biodegradability was tested in soil, and 85.3 % weight loss of bioplastic films was observed after 50 days of the experiment which is the main task of this research. The antimicrobial properties of bioplastic films have been evaluated, and showed an inhibition zone of 16 mm against E. coli. After 12 days of incubation of sherbet berries, complete spoilage is identified in the control group compared to those covered with the bioplastic film. This outcome is attributed to the antioxidant and antimicrobial activities provided by chitosan and P. alba extract in the bioplastic film. The comprehensive outcomes of this study suggest the potential future adoption of these entirely bio-derived, environmentally sustainable and biodegradable bioplastic films as a viable substitute for the plastic packaging currently present in the market.

Sb-Doped Cerium Molybdate: An Emerging Material as Dielectric and Photocatalyst for the Removal of Diclofenac Potassium from Aqueous Media.

This work reports the influence of antimony substitution in a cerium molybdate lattice for improved dielectric and photocatalytic properties. For this purpose, a series of Ce2-xSbx(MoO4)3 (x = 0.00, 0.01, 0.03, 0.05, 0.07, and 0.09) were synthesized through a co-precipitation route. The as-synthesized materials were characterized for their optical properties, functional groups, chemical oxidation states, structural phases, surface properties, and dielectric characteristics using UV-Vis spectroscopy (UV-Vis), Fourier transform infrared (FTIR) and Raman spectroscopies, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, and impedance spectroscopy, respectively. UV-Vis study showed a prominent red shift of absorption maxima and a continuous decrease in band gap (3.35 eV to 2.79 eV) by increasing the dopant concentration. The presence of Ce-O and Mo-O-Mo bonds, detected via FTIR and Raman spectroscopies, are confirmed, indicating the successful synthesis of the desired material. The monoclinic phase was dominant in all materials, and the crystallite size was decreased from 40.29 nm to 29.09 nm by increasing the Sb content. A significant increase in the dielectric constant (ε' = 2.856 × 108, 20 Hz) and a decrease in the loss tan (tanδ = 1.647, 20 Hz) were exhibited as functions of the increasing Sb concentration. Furthermore, the photocatalytic efficiency of pristine cerium molybdate was also increased by 1.24 times against diclofenac potassium by incorporating Sb (x = 0.09) in the cerium molybdate. The photocatalytic efficiency of 85.8% was achieved within 180 min of UV light exposure at optimized conditions. The photocatalytic reaction followed pseudo-first-order kinetics with an apparent rate constant of 0.0105 min-1, and the photocatalyst was recyclable with good photocatalytic activity even after five successive runs. Overall, the as-synthesized Sb-doped cerium molybdate material has proven to be a promising candidate for charge storage devices and a sustainable photocatalyst for wastewater treatment.

Degradation of cefadroxil drug by newly designed solar light responsive alcoholic template-based lanthanum ferrite nanoparticles.

In this work, lanthanum ferrite nanoparticles were synthesized via a simple co-precipitation method. Two different templates, namely sorbitol and mannitol, were used in this synthesis to tune the optical, structural, morphological, and photocatalytic properties of lanthanum ferrite. The synthesized lanthanum ferrite-sorbitol (LFOCo-So) and lanthanum ferrite-mannitol (LFOCo-Mo) were investigated through Ultraviolet-Visible (UV-Vis), X-ray diffraction (XRD), Fourier Transform Infra-Red (FTIR), Raman, Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX), and photoluminescence (PL) techniques to study the effects of the templates on the tunable properties of lanthanum ferrite nanoparticles. The UV-Vis study revealed a remarkably small bandgap (2.09 eV) of LFOCo-So compared to the LFOCo-Mo having a band gap of 2.46 eV. XRD analysis revealed a single-phased structure of LFOCo-So, whereas LFOCo-Mo showed different phases. The calculated crystallite sizes of LFOCo-So and LFOCo-Mo were 22 nm and 39 nm, respectively. FTIR spectroscopy indicated the characteristics of metal-oxygen vibrations of perovskites in both lanthanum ferrite (LFO) nanoparticles, whereas a slight shifting of Raman scattering modes in LFOCo-Mo in contrast to LFOCo-So showed the octahedral distortion of the perovskite by changing the template. SEM micrographs indicated porous particles of lanthanum ferrite with LFOCo-So being more uniformly distributed, and EDX confirmed the stoichiometric ratios of the lanthanum, iron, and oxygen in the fabricated lanthanum ferrite. The high-intensity green emission in the photoluminescence spectrum of LFOCo-So indicated more prominent oxygen vacancies than LFOCo-Mo. The photocatalytic efficiency of synthesized LFOCo-So and LFOCo-Mo was investigated against cefadroxil drug under solar light irradiation. At optimized photocatalytic conditions, LFOCo-So showed higher degradation efficiency of 87% in only 20 min than LFOCo-Mo having photocatalytic activity of 81%. The excellent recyclability of the LFOCo-So reflected that it could be reused without affecting photocatalytic efficiency. These findings showed that sorbitol is a useful template for the lanthanum ferrite particles imparting outstanding features, enabling it to be used as an efficient photocatalyst for environmental remediation.

Multifunctional catalyst-assisted sustainable reformation of lignocellulosic biomass into environmentally friendly biofuel and value-added chemicals.

Rapid urbanization is increasing the world's energy demand, making it necessary to develop alternative energy sources. These growing energy needs can be met by the efficient energy conversion of biomass, which can be done by various means. The use of effective catalysts to transform different types of biomasses will be a paradigm change on the road to the worldwide goal of economic sustainability and environmental protection. The development of alternative energy from biomass is not easy, due to the uneven and complex components present in lignocellulose; accordingly, the majority of biomass is currently processed as waste. The problems may be overcome by the design of multifunctional catalysts, offering adequate control over product selectivity and substrate activation. Hence, this review describes recent developments involving various catalysts such as metallic oxides, supported metal or composite metal oxides, char-based and carbon-based substances, metal carbides and zeolites, with reference to the catalytic conversion of biomass including cellulose, hemicellulose, biomass tar, lignin and their derivative compounds into useful products, including bio-oil, gases, hydrocarbons, and fuels. The main aim is to provide an overview of the latest work on the use of catalysts for successful conversion of biomass. The review ends with conclusions and suggestions for future research, which will assist researchers in utilizing these catalysts for the safe conversion of biomass into valuable chemicals and other products.

Bio-fabricated bismuth-based materials for removal of emerging environmental contaminants from wastewater.

Although rapid industrialization has made life easier for humans, several associated issues are emerging and harming the environment. Wastewater is regarded as one of the key problems of the 21st century due to its massive production every year and requires immediate attention from all stakeholders to protect the environment. Since the introduction of nanotechnology, bismuth-based nanomaterials have been used in variety of applications. Various techniques, such as hydrothermal, solvo-thermal and biosynthesis, have been reported for synthesizing these materials, etc. Among these, biosynthesis is eco-friendly, cost-effective, and less toxic than conventional chemical methods. The prime focuses of this review are to elaborate biosynthesis of bismuth-based nanomaterials via bio-synthetic agents such as plant, bacteria and fungi and their application in wastewater treatment as anti-pathogen/photocatalyst for pollutant degradation. Besides this, future perspectives have been presented for the upcoming research in this field, along with concluding remarks.

Assessment of potentially toxic metal(loid)s contamination in soil near the industrial landfill and impact on human health: an evaluation of risk.

The generation of solid waste is increasing with each passing day due to rapid urbanization and industrialization and has become a matter of concern for the international community. Leachate leakages from landfills pollute the soil and can potentially harm the human health. In this paper, inductively coupled plasma-optical emission spectrometric studies were employed to assess and analyze the composition of metals (Ba, Cd, Pb, Hg, Cu, Cr and Mn) and metalloid (As) in soil samples. Results of Cr, Mn, Cu, As, Ba, Cd, Pb and Hg from CRM (certified reference material, SRM 2709a) of San Joaquin soil were evaluated and reported in terms of percent recoveries which were in the range of 97.6-102.9% and show outstanding extraction efficiency. Other than copper, where the permitted limit set by the EU is specified as 50-140 mg/kg in soil, the average amount of all the metals in soil was found within the permissible limits provided by WHO, the European Community (EU) and US EPA. Soil contaminated with Hg (PERI = 100) and Cd (PERI = 145.50) posed an ecological risk significantly. Pollution load index (PLI) value is greater than 1, while degree of contamination (Cdeg) value is less than 32 which indicated that the soil is polluted and considerably contaminated with metals and metalloid, respectively. In terms of the average daily dosage (ADD) of soil, children received the highest doses of all metals (ADDing = 1.315 × 10-7 - 2.470 × 10-3 and ADDderm = 9.939 × 10-7 - 5.292 × 10-11), whereas ADDing (1.409 × 10-8 - 2.646 × 10-4) was found greater in adults. For all metals except for Ba, the hazard quotient (HQ) trend in both children and adults was observed to be HQing > HQderm > HQinh of soil. Children who are at the lower edge of cancer risk had a lifetime cancer risk (LCR) of 2.039 × 10-4 for Cr from various paths of soil exposure.

Development of zinc ferrite nanoparticles with enhanced photocatalytic performance for remediation of environmentally toxic pharmaceutical waste diclofenac sodium from wastewater.

Diclofenac sodium is an anti-inflammatory drug commonly used to cure pain in various treatments. The remarkable potential of this pain-killer leads to its excessive use and, therefore, a persistent water contaminant. Its presence in aqueous bodies is hazardous for both humans and the environment because it causes the growth of harmful drug-resistant bacteria in water. Herein, we present a comparative study of the ZnO and ZnFe2O4 as photocatalysts for the degradation of diclofenac sodium, along with their structural and morphological studies. A simple co-precipitation method was used for the synthesis of ZnO and ZnFe2O4 and characterized by various analytical techniques. For instance, the UV-Vis study revealed the absorption maxima of ZnO at 320 nm, which was shifted to a longer wavelength region at 365 nm for zinc ferrite. The optical band gaps obtained from the Tauc plot indicated that the incorporation of iron has led to a decreased band gap of zinc ferrite (2.89 eV) than pure ZnO (3.14 eV). The metal-oxygen linkages shown by FTIR indicated the formation of desired ZnO and ZnFe2O4, which was further confirmed by XRD. It elucidated the typical hexagonal structure for ZnO and spinel cubic structure for ZnFe2O4 with an average crystallite of 31 nm and 44 nm for ZnO and ZnFe2O4, respectively. The micrographs obtained by SEM showed rough spherical particles of ZnO, whereas for ZnFe2O4 flower-like clustered particles were observed. The photocatalytic investigation against diclofenac sodium revealed the higher degradation efficiency of ZnFe2O4 (61.4%) in only 120 min, whereas ZnO degraded only 48.9% of the drug. Moreover, zinc ferrite has shown good recyclability and was stable up to five runs of photodegradation with a small loss (3.9%) of photocatalytic activity. The comparison of two catalysts has suggested the promising role of zinc ferrite in wastewater remediation to eliminate hazardous pharmaceuticals.

Estimation of some trace metals, bioactive compounds, curative antimicrobial and antioxidant agents from Russula foetens and Russula cf. foetentoides.

The current study is an attempt to estimate minerals, antioxidant and antimicrobial activities of two medicinal mushrooms (Russula foetens and Russula cf. foetentoides) along with their mycochemicals. Among the metal analysis, iron was most abundantly (7.428mg/g) present in R. cf. foetentoides. The mycochemical screening revealed the presence of active secondary metabolites and phenolic composition by HPLC showed five stable compounds with maximum concentration of gallic acid (22.31%). The highest antibacterial activity (27.8±0.152mm) was displayed in ethanol macerate of R. foetens in contradiction of Staphylococcus aureus. Similarly, highest antifungal potential was exhibited by R. foetens (ethanolic macerate) against Fusarium equiseti with zone of inhibition 23±0.572mm. The antioxidant potential was assessed by five assays and the R. foetens exhibited maximum % inhibition (43.045±0.037%) by DPPH radical protocol. Maximum % inhibition by ABTS protocol was exhibited by R. cf. foetentoides i.e., 88.057±0.021. The highest reducing potential was revealed in R. foetens (0.684±0.001mmol/L of FeSO4). The highest flavonoids and total phenolic contents (TPC) were shown by R. cf. foetentoides i.e., 0.115±0.002mg/100g of Catechin and 0.064±0.001mg/100g of GAE (gallic acid equivalents), respectively. All the obtained results were analyzed statistically by applying the ANOVA to determine the significant and non-significant ranges.

Modified matrix solid phase dispersion-HPLC method for determination of pesticide residue in vegetables and their impact on human health: A risk assessment.

The use of pesticides is unavoidable in agricultural practices. This class of chemicals is highly toxic for the environment as well as for humans. The present work was carried out to assess the presence of some pesticides (diafenthiuron, lufenuron, azoxystrobin, difenoconazole, and chlorothalonil) residues in five of the very commonly used vegetables (eggplant, capsicum, apple gourd, cauliflower, and sponge gourd). Matrix solid phase dispersion (MSPD) technique was used to extract the pesticides and subsequently their quantification was performed through high performance liquid chromatography (HPLC) coupled to ultraviolet-visible (UV-Vis) detector. The elution was accomplished at wavelength of 254 nm by injecting 20 µL of standards or samples into chromatographic system. The mobile phase consisted of acetonitrile and water (80:20 v/v), where the flow rate was adjusted at 1.0 ml/min. The linearity was good (R 2 ≥ 0.994) over a concentration range from 20 to 100 µg/ml for the investigated pesticides. The low detection limits showed a quite appreciable potential of the method to detect (1.12-1.61 µg/L) and quantify (3.73-5.36 µg/ml) the pesticides under study. The accuracy was demonstrated in terms of percent recovery which ranged between 88.5% and 116.9% for all the pesticides under investigation. These results justify the suitability of the technique for the intended purpose. The concentration of difenoconazole in apple gourd (20.97 mg/kg), cauliflower (10.28 mg/kg), and sponge gourd (40.32 mg/kg) whereas diafenthiuron in cauliflower (0.66 mg/kg) exceeded the maximum residue level (MRLs) as defined by Food and Agriculture Organization of the United Nations and the World Health Organization (FAO/WHO). Target hazard quotient (THQ) values of difenoconazole and diafenthiuron (except for adults) were more than one which indicates the significant effect on human health on consumption of apple gourd, cauliflower, and sponge gourd.

Recent advances in metal-based nanoporous materials for sensing environmentally-related biomolecules.

Highly sensitive, stable, selective, efficient, and short reaction time sensors play a substantial role in daily life/industry and are the need of the day. Due to the rising environmental issues, nanoporous carbon and metal-based materials have attracted significant attention in environmental analysis owing to their intriguing and multifunctional properties and cost-effective and rapid detection of different analytes by sensing applications. Environmental-related issues such as pollution have been a significant threat to the world. Therefore, it is necessary to fabricate highly promising performance-based sensor materials with excellent reliability, selectivity and good sensitivity for monitoring various analytes. In this regard, different methods have been employed to fabricate these sensors comprising metal, metal oxides, metal oxide carbon composites and MOFs leading to the formation of nanoporous metal and carbon composites. These composites have exceptional properties such as large surface area, distinctive porosity, and high conductivity, making them promising candidates for several versatile sensing applications. This review covers recent advances and significant studies in the sensing field of various nanoporous metal and carbon composites. Key challenges and future opportunities in this exciting field are also part of this review.

Functionalized magnetic nanostructured composites and hybrids for photocatalytic elimination of pharmaceuticals and personal care products.

Due to rapid urbanization and globalization, an enormous use of pharmaceuticals and personal care products (PPCPs) has resulted their excessive release in water bodies leading to several environmental issues. This release into the environment takes place via household sewage, hospital effluents, manufacturing units and landfill sites etc. The pharmaceuticals and personal care products (PPCPs) are recently listed as emerging contaminants having many adverse effects towards aquatic life, human beings, and the whole ecosystem. The alarming threats of PPCPs demand efficient methods to cope up their hazardous impacts. The conventional wastewater remediations are not specifically designed for the removal of PPCPs and hence, they require advanced technologies and materials for their elimination to ensure water safety. Among various methods employed so far, photocatalysis is considered to be one of the most cost effective and eco-friendly method but it requires a suitable candidate as a photocatalyst. Thanks to the magnetic nanocomposites which have improved the limitations (poor stability, agglomeration, and difficult separation, etc.) of classically used nanomaterials. Magnetic nanocomposites contain at least one component having magnetic properties making their separation easy from the aqueous media after the photodegradation phenomenon. These can be further functionalized with other materials to obtain maximum advantage as photocatalyst. Few examples of such functionalized nanocomposites are inorganic material based magnetic nanocomposites, carbon based magnetic nanocomposites, biomaterial based magnetic nanocomposites, metal-organic framework based magnetic nanocomposites and polymer based magnetic nanocomposites etc. This review covers the global environmental issue of water pollution especially with respect to the PPCPs, their occurrence in aqueous environment and toxic effects on living beings. A comprehensive discussion of the recently reported functionalized magnetic nanocomposites for the photocatalytic removal of PPCPs from water is the main aim of this review. The synthetic/morphological approaches of various functionalized magnetic composites and their mechanism of action are also elaborated. The possible research challenges in the field of magnetic nanocomposites and future research directions are discussed to apply magnetic nanocomposites for wastewater treatment in near future.

Multifunctional nanomaterials and nanocomposites for sensing and monitoring of environmentally hazardous heavy metal contaminants.

The applications of conventional sensors are limited by the long response time, high cost, large detection limit, low sensitivity, complicated usage and low selectivity. These sensors are nowadays replaced by Nanocomposite-based modalities and nanomaterials which are known for their high selectivity and physical and chemical properties. These nanosensors effectively detect heavy metal contaminants in the environment as the discharge of heavy metals into natural water as a result of human activity has become a global epidemic. Exposure to these toxic metals might induce many health-related complications, including kidney failure, brain injury, immune disorders, muscle paleness, cardiac damage, nervous system impairment and limb paralysis. Therefore, designing and developing novel sensing systems for the detection and recognition of these harmful metals in various environmental matrices, particularly water, is of extremely important. Emerging nanotechnological approaches in the past two decades have played a key role in overcoming environmentally-related problems. Nanomaterial-based fabrication of chemical nanosensors has widely been applied as a powerful analytical tool for sensing heavy metals. Portability, high sensitivity, on-site detection capability, better device performance and selectivity are all advantages of these nanosensors. The detection and selectivity have been improved using molecular recognition probes for selective binding on different nanostructures. This study aims to evaluate the sensing properties of various nanomaterials such as metal-organic frameworks, fluorescent materials, metal-based nanoparticles, carbon-based nanomaterials and quantum dots and graphene-based nanomaterials and quantum dots for heavy metal ions recognition. All these nano-architectures are frequently served as effective fluorescence probes to directly (or by modification with some large or small biomolecules) sense heavy metal ions for improved selectivity. However, efforts are still needed for the simultaneous designing of multiple metal ion-based detection systems, exclusively in colorimetric or optical fluorescence nanosensors for heavy metal cations.

Nanoengineered metal-organic framework for adsorptive and photocatalytic mitigation of pharmaceuticals and pesticide from wastewater.

Rapidly expanding water pollution has transformed into significant dangers around the world. In recent years, the pharmaceutical and agriculture field attained enormous progress to meet the necessities of health and life; however, discharge of trace amounts of pharmaceuticals and pesticides into water significantly have a negative influence on human health and the environment. Contamination with these pollutants also constitutes a great threat to the aquatic ecosystem. To deal with the harmful impacts of such pollutants, their expulsion has attracted researchers' interest a lot, and it became essential to figure out techniques suitable for the removal of these pollutants. Thus, many researchers have devoted their efforts to improving the existing technology or providing an alternative strategy to solve this environmental problem. One of the attractive materials for this purpose is metal-organic frameworks (MOFs) due to their superior high surface area, high porosity, and the tunable features of their structures and function. Among various techniques of wastewater treatment, such as biological treatment, advanced oxidation process and membrane technologies, etc., metal-organic frameworks (MOFs) materials are tailorable porous architectures and are viably used as adsorbents or photocatalysts for wastewater treatment due to their porosity, tunable internal structure, and large surface area. MOFs are synthesized by various methods such as solvo/hydrothermal, sonochemical, microwave and mechanochemical methods. Most common method used for the synthesis of MOFs is solvothermal/hydrothermal methods. Herein, this review aims at providing a comprehensive overview of the latest advances in MOFs and their derivatives, focusing on the following aspects: synthesis and applications. This review comprehensively highlights the application of MOFs and nano-MOFs to remove pharmaceuticals and pesticides from wastewater. For the past years, transition metal-based MOFs have been concentrated as photocatalyst/adsorbents in treating contaminated water. However, work on main group metal-based MOFs is not so abundant. Hence, the foremost objective of this review is to present the latest material and references concerning main group element-based MOFs and nanoscale materials derived from them towards wastewater treatment. It summarizes the possible research challenges and directions for MOFs and their derivatives as catalysts applied to wastewater treatment in the future. With the context of recent pioneering studies on main group elements-based MOFs and their derivatives; we hope to stimulate some possibilities for further development, challenges and future perspectives in this field have been highlighted.

Citric acid-capped NiWO4/Bi2S3 and rGO-doped NiWO4/Bi2S3 nanoarchitectures for photocatalytic decontamination of emerging pollutants from the aqueous environment.

Herein, we describe the successful synthesis of NiWO4/Bi2S3 and reduced graphene oxide (rGO-NiWO4/Bi2S3) nanocomposites through a simple green sol-gel approach. The fabricated composites were subsequently characterized by Fourier transform infrared (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDX) and ultraviolet-visible spectroscopy (UV-VIS) spectroscopic analyses. Dielectric properties were done by a precision impedance analyzer. Tanδ and dielectric constant for NiWO4/Bi2S3 and rGO-NiWO4/Bi2S3 were 1.811, 292818, and 0.2970, 344574, respectively, at 20 Hz. The photocatalytic performance of NiWO4/Bi2S3 and rGO-NiWO4/Bi2S3 was investigated against methylene blue and methyl orange dyes in an aqueous medium. NiWO4-Bi2S3 showed degradation of methylene blue 15.52% after 20 min, 21.8% after 30 min and 46.8% after 40 min. Similarly, for methyl orange dye it was 18.1% after 20 min, 54% after 30 min and 59.36% after 40 min. Compared to NiWO4/Bi2S3, rGO-NiWO4/Bi2S3 exhibited superior degradation efficiency of 7.5% (20 min), 25.24% (30 min) and 57.71% (40 min) for methylene blue, and 35.7% (20 min), 56.98% (30 min) and 72.42% (40 min) for methyl orange under sunlight. This enhancement in photocatalytic and dielectric properties might be attributed to the presence of graphene in rGO-NiWO4/Bi2S3 nanococomposite. Different factors such as effect of time, pH, dose of catalyst, concentration of dye were optimized and the reusability of superior catalyst rGO-NiWO4/Bi2S3 was also checked for four cycles. In conclusion, promising photocatalytic and dielectric properties of rGO-NiWO4/Bi2S3 suggest its potential applications in the photocatalytic degradation of organic pollutants and energy storage materials. This study provides a well-developed route to exploit metal sulphide/oxide nanocomposites in environmental remediation and energy storage devices.

Improved High-Temperature Thermoelectric Properties of Dual-Doped Ca3Co4O9.

Layered structured Ca3Co4O9 has displayed great potential for thermoelectric (TE) renewable energy applications, as it is nontoxic and contains abundantly available constituent elements. In this work, we study the crystal structure and high-temperature TE properties of Ca3-2y Na2y Co4-y Mo y O9 (0 ≤ y ≤ 0.10) polycrystalline materials. Powder X-ray diffraction (XRD) analysis shows that all samples are single-phase samples and without any noticeable amount of the secondary phase. X-ray photoelectron spectroscopic (XPS) measurements depict the presence of a mixture of Co3+ and Co4+ valence states in these materials. The Seebeck coefficient (S) of dual-doped materials is significantly enhanced, and electrical resistivities (ρ) and thermal conductivities (κ) are decreased compared to the pristine compound. The maximum thermoelectric power factor (PF = S 2/ρ) and dimensionless figure of merit (zT) obtained for the y = 0.025 sample at 1000 K temperature are ∼3.2 × 10-4 W m-1 K-2 and 0.27, respectively. The zT value for Ca2.95Na0.05Co3.975Mo0.025O9 is about 2.5 times higher than that of the parent Ca3Co4O9 compound. These results demonstrate that dual doping of Na and Mo cations is a promising strategy for improving the high-temperature thermoelectric properties of Ca3Co4O9.

MXene-based hybrid composites as photocatalyst for the mitigation of pharmaceuticals.

Environmental contamination is a burning issue and has gained global attention in the present era. Pharmaceuticals are emerging contaminants affecting the natural environment worldwide owing to their extensive consumption particularly in developing countries where self-medication is a common practice. These pharmaceuticals or their degraded active metabolites enter water bodies via different channels and are continuous threat to the whole ecological system. There is a dire need to find efficient approaches for their removal from all environmental matrices. Photocatalysis is one of the most effective and simple approach, however, finding a suitable photocatalyst is a challenging task. Recently, MXenes (two-dimensional transition metal carbides/nitrides), a relatively new material has attracted increasing interest as photocatalysts due to their exceptional properties, such as large surface area, appreciable safety, huge interlayer spacing, thermal conductivity, and environmental flexibility. This review describes the recent advancements of MXene-based composites and their photocatalytic potential for the elimination of pharmaceuticals. Furthermore, present limitations and future research requirements are recommended to attain more benefits of MXene-based composites for the purification of wastewater.

Nanohybrids-assisted photocatalytic removal of pharmaceutical pollutants to abate their toxicological effects - A review.

Advancement in medication by health care sector has undoubtedly improved our life but at the same time increased the chemical burden on our natural ecosystem. The residuals of pharmaceutical products become part of wastewater streams by different sources such as excretion after their usage, inappropriate way of their disposal during production etc. Hence, they are serious health hazards for human, animal, and aquatic lives. Due to rapid urbanization, the increased demand for clean drinking water is a burning global issue. In this regard it is need of the present era to explore efficient materials which could act as photocatalyst for mitigation of pharmaceuticals in wastewater. Nanohybrid as photocatalyst is one of the widely explored class of materials in photocatalytic degradation of such harmful pollutants. Among these nanohybrids; metal based nanohybrids (metals/metal oxides) and carbon based nanohybrids (carbon nanotubes, graphene, fullerenes etc.) have been explored to remove pharmaceutical drugs. Keeping in view the increasing harmful impacts of pharmaceuticals; the sources of pharmaceuticals in wastewater, their health risk factors and their mitigation using efficient nanohybrids as photocatalysts have been discussed in this review.

Photocatalytic Degradation of Cefixime Trihydrate by Bismuth Ferrite Nanoparticles.

The present work was carried out to synthesize bismuth ferrite (BFO) nanoparticles by combustion synthesis, and to evaluate the photocatalytic activity of synthesized bismuth ferrite nanoparticles against cefixime trihydrate. BFO nanoparticles were successfully synthesized using bismuth (III) nitrate and iron (III) nitrate by a combustion synthesis method employing different types of fuels such as maltose, succinic acid, cinnamic acid, and lactose. The effects of the different types of fuels on the morphology and size of the bismuth ferrite nanoparticles were investigated. Characterization of the as-obtained bismuth ferrite nanoparticles was carried out by different techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy-Dispersive Spectroscopy (EDS), N2-sorption analysis, Fourier-transform infrared spectroscopy (FT-IR), and ultraviolet-visible (UV-vis) spectroscopy. Photoluminescence studies were also carried out for the various bismuth ferrite nanoparticles obtained. Degradation of cefixime trihydrate was investigated under sunlight to evaluate the photocatalytic properties of the bismuth ferrite nanoparticles, and it was found that the bismuth ferrite nanoparticles followed first-order degradation kinetics in solar irradiation in the degradation of antibiotic, cefixime trihydrate.