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The discharge of toxic dye effluents from industry is a major concern for environmental pollution and toxicity. These toxic dyes can be efficiently removed from waste streams using a photocatalysis process involving visible light. Due to its simple synthesis procedure, inexpensive precursor, and robust stability, graphitic carbon nitride (g-C3N4, or CN) has been used as a visible light responsive catalyst for the degradation of dyes with mediocre performance because it is limited by its low visible light harvesting capability due to its wide bandgap and fast carrier recombination rate. To overcome these limitations and enhance the performance of g-C3N4, it was coupled with a narrow bandgap copper tin sulfide (CTS) semiconductor to form a p-n heterojunction. CTS and g-C3N4 were selected due to their good stability, low toxicity, ease of synthesis, layered sheet/plate-like morphology, and relatively abundant precursors. Accordingly, a series of copper tin sulfide/graphitic carbon nitride nanocomposites (CTS/g-C3N4) with varying CTS contents were successfully synthesized via a simple two-step process involving thermal pyrolysis and coprecipitation for visible-light-induced photocatalytic degradation of methyl orange (MO) dye. The photocatalytic activity results showed that the 50%(wt/wt) CTS/g-C3N4 composite displayed a remarkable degradation efficiency of 95.6% for MO dye under visible light illumination for 120 min, which is higher than that of either pristine CTS or g-C3N4. The improved performance is attributed to the extended light absorption range (due to the optimized bandgap), effective suppression of photoinduced electron-hole recombination, and improved charge transfer that arose from the formation of a p-n heterojunction, as evidenced by electrochemical impedance spectroscopy (EIS), photocurrent, and photoluminescence results. Moreover, the results of the reusability study showed that the composite has excellent stability, indicating its potential for the degradation of MO and other toxic organic dyes from waste streams.
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A gold nanogap substrate was used to measure the thiram and carbaryl residues in various fruit juices using surface-enhanced Raman scattering (SERS). The gold nanogap substrates can detect carbaryl and thiram with limits of detection of 0.13 ppb (0.13 µgkg-1) and 0.22 ppb (0.22 µgkg-1). Raw SERS data were first preprocessed to reduce noise and undesirable effects and, were later used for model creation, implementing classification, and regression analysis techniques. The partial least-squares regression models achieved the highest prediction correlation coefficient (R2) of 0.99 and the lowest root mean square of prediction value below 0.62 ppb for both pesticide-infected juice samples. Furthermore, to differentiate between juice samples contaminated by both pesticides and control (pesticide-free), logistic-regression classification models were produced and achieved the highest classification accuracies of 100% and 99% for contaminated juice containing thiram and 100% accurate results for contaminated juice containing carbaryl. This indicates that the gold nanogap surface has significant potential for achieving high sensitivity in detecting trace contaminants in food samples.
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Carbaril , Contaminación de Alimentos , Jugos de Frutas y Vegetales , Oro , Residuos de Plaguicidas , Espectrometría Raman , Tiram , Residuos de Plaguicidas/análisis , Espectrometría Raman/métodos , Carbaril/análisis , Jugos de Frutas y Vegetales/análisis , Tiram/análisis , Contaminación de Alimentos/análisis , Oro/química , Quimiometría , Nanopartículas del Metal/química , Límite de Detección , Frutas/químicaRESUMEN
The slow photon effect in inverse opal photonic crystals represents a promising approach to manipulate the interactions between light and matter through the design of material structures. This study introduces a novel ordered inverse opal photonic crystal (IOPC) sensitized with perovskite quantum dots (PQDs), demonstrating its efficacy for efficient visible-light-driven H2 generation via water splitting. The rational structural design contributes to enhanced light harvesting. The sensitization of the IOPC with PQDs improves optical response performance and enhances photocatalytic H2 generation under visible light irradiation compared to the IOPC alone. The designed photoanode exhibits a photocurrent density of 3.42â mA cm-2 at 1.23â V vs RHE. This work advances the rational design of visible light-responsive photocatalytic heterostructure materials based on wide band gap metal oxides for photoelectrochemical applications.
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Solid-state batteries are commonly acknowledged as the forthcoming evolution in energy storage technologies. Recent development progress for these rechargeable batteries has notably accelerated their trajectory toward achieving commercial feasibility. In particular, all-solid-state lithium-sulfur batteries (ASSLSBs) that rely on lithium-sulfur reversible redox processes exhibit immense potential as an energy storage system, surpassing conventional lithium-ion batteries. This can be attributed predominantly to their exceptional energy density, extended operational lifespan, and heightened safety attributes. Despite these advantages, the adoption of ASSLSBs in the commercial sector has been sluggish. To expedite research and development in this particular area, this article provides a thorough review of the current state of ASSLSBs. We delve into an in-depth analysis of the rationale behind transitioning to ASSLSBs, explore the fundamental scientific principles involved, and provide a comprehensive evaluation of the main challenges faced by ASSLSBs. We suggest that future research in this field should prioritize plummeting the presence of inactive substances, adopting electrodes with optimum performance, minimizing interfacial resistance, and designing a scalable fabrication approach to facilitate the commercialization of ASSLSBs.
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Copper tin sulfide, Cu4SnS4 (CTS), a ternary transition-metal chalcogenide with unique properties, including superior electrical conductivity, distinct crystal structure, and high theoretical capacity, is a potential candidate for supercapacitor (SC) electrode materials. However, there are few studies reporting the application of Cu4SnS4 or its composites as electrode materials for SCs. The reported performance of the Cu4SnS4 electrode is insufficient regarding cycle stability, rate capability, and specific capacity; probably resulting from poor electrical conductivity, restacking, and agglomeration of the active material during continued charge-discharge cycles. Such limitations can be overcome by incorporating graphene as a support material and employing a binder-free, facile, electrodeposition technique. This work reports the fabrication of a copper tin sulfide-reduced graphene oxide/nickel foam composite electrode (CTS-rGO/NF) through stepwise, facile electrodeposition of rGO and CTS on a NF substrate. Electrochemical evaluations confirmed the enhanced supercapacitive performance of the CTS-rGO/NF electrode compared to that of CTS/NF. A remarkably improved specific capacitance of 820.83 F g-1 was achieved for the CTS-rGO/NF composite electrode at a current density of 5 mA cm-2, which is higher than that of CTS/NF (516.67 F g-1). The CTS-rGO/NF composite electrode also exhibited a high-rate capability of 73.1% for galvanostatic charge-discharge (GCD) current densities, ranging from 5 to 12 mA cm-2, and improved cycling stability with over a 92% capacitance retention after 1000 continuous GCD cycles; demonstrating its excellent performance as an electrode material for energy storage applications, encompassing SCs. The enhanced performance of the CTS-rGO/NF electrode could be attributed to the synergetic effect of the enhanced conductivity and surface area introduced by the inclusion of rGO in the composite.
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The need for the development of soft materials capable of stably adhering to nerve tissues without any suturing followed by additional damages is at the fore at a time when success in postoperative recovery depends largely on the surgical experience and/or specialized microsuturing skills of the surgeon. Despite fully recognizing such prerequisite conditions, designing the materials with robust adhesion to wet nerves as well as acute/chronic anti-inflammation remains to be resolved. Herein, a sticky and strain-gradient artificial epineurium (SSGAE) that overcomes the most critically challenging aspect for realizing sutureless repair of severely injured nerves is presented. In this regard, the SSGAE with a skin-inspired hierarchical structure entailing strain-gradient layers, anisotropic Janus layers including hydrophobic top and hydrophilic bottom surfaces, and synergistic self-healing capabilities enables immediate and stable neurorrhaphy in both rodent and nonhuman primate models, indicating that the bioinspired materials strategy significantly contributes to translational medicine for effective peripheral nerve repair.
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Nervios Periféricos , Roedores , Animales , Nervios Periféricos/fisiología , Nervios Periféricos/cirugía , Primates , Regeneración NerviosaRESUMEN
The photodegradation of organic pollutants using metal oxide-based catalysts has drawn great attention as an effective method for wastewater treatment. In this study, zinc oxide nanoparticles (ZnO NPs) and zinc oxide/copper oxide nanocomposites (ZnO/CuO NCs) were fabricated using the leaf extract of Croton macrostachyus as a nontoxic, natural reducing and stabilizing agent. The synthesized samples were characterized by employing X-ray diffraction, microscopic, spectroscopic, and electrochemical methods. The results confirmed the successful synthesis of ZnO NPs and ZnO/CuO NCs with well-defined crystalline structures and morphologies. The prepared samples were tested for the photodegradation of methylene blue (MB) dye under visible light irradiation. Compared to ZnO NPs, ZnO/CuO NCs showed greatly improved photocatalytic performances, particularly with the sample prepared with the 20 mol % Cu precursor (97.02%). The enhancement could be related to the formed p-n heterojunction, which can suppress the recombination of charge carriers and extend the photoresponsive range. A theoretical study of the photocatalytic activity of ZnO/CuO NCs against MB dye degradation was also conducted by using COMSOL Multiphysics software. The results of the simulation are in reasonable agreement with those of the experiment. This study contributes to the development of sustainable and effective photocatalytic materials that are suitable for application in environmental remediation, particularly in the treatment of wastewater.
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Fe-based nanostructures have possessed promising properties that make it suitable for chiral sensing and imaging applications owing to their ultra-small size, non-toxicity, biocompatibility, excellent photostability, tunable fluorescence, and water solubility. This review summarizes the recent research progress in the field of Fe-based nanostructures and places special emphases on their applications in chiral sensing and imaging. The synthetic strategies to prepare the targeted Fe-based structures were also introduced. The chiral sensing and imaging applications of the nanostructures are discussed in details.
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Nanoestructuras , Puntos Cuánticos , Humanos , Puntos Cuánticos/química , Nanoestructuras/química , Diagnóstico por Imagen , Fluorescencia , SolubilidadRESUMEN
The introduction of noble metal nanoparticles with good LSPR characteristics can greatly improve the sensitivity of SPR through resonance coupling effect. The plasma resonance response and optical properties of film coupling nanoparticle systems largely depends on the ingenious design of gap structures. Nucleic acid nanostructures have good stability, flexibility, and high biocompatibility, making them ideal materials for gap construction. 2D MOF (Cu-Tcpp) has a large conjugated surface similar to graphene, which can provide a stable substrate for the directional fixation of nucleic acid nanostructures. However, research on gap coupling plasmon based on nucleic acid nanostructures and 2D MOF is still rarely reported. By integrating the advantages of Cu-Tcpp assembled film and DNA tetrahedron immobilization, a nano gap with porous scaffold structure between the gold film and gold nanorod was build. The rigidity of DNA tetrahedron can precisely control the gap size, and its unique programmability allows us to give the coupling structure greater flexibility through the design of nucleic acid chain. The experimental results and FDTD simulation show that the film coupling nanoparticle systems constructed with DNA tetrahedrons greatly enhance the electric field strength near the chip surface and effectively improve the sensitivity of SPR. This research shows the huge potential of nucleic acid nanomaterials in the construction of SPR chip surface microstructures.
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Técnicas Biosensibles , Nanopartículas del Metal , Ácidos Nucleicos , Resonancia por Plasmón de Superficie/métodos , Técnicas Biosensibles/métodos , Antígeno B7-H1 , ADN/química , Nanopartículas del Metal/química , Oro/químicaRESUMEN
MXene is widely used in the construction of optoelectronic interfaces due to its excellent properties. However, the hydrophilicity and metastable surface of MXene lead to its oxidation behavior, resulting in the degradation of its various properties, which seriously limits its practical application. In this work, a 2D metal-organic framework (2D MOF) with matching 2D morphology, excellent stability performance, and outstanding optoelectronic performance is grown in situ on the MXene surface through heterojunction engineering to suppress the direct contact between reactive molecules and the inner layer material without affecting the original advantages of MXene. The photoelectric dual gain MXene@MOF heterojunction is confirmed. As a photoelectric material, its properties are highly suitable for the demand of interface sensitization layer materials of surface plasmon resonance (SPR). Therefore, using SPR as a platform for the application of this interface material, the performance of MXene@MOF and its potential mechanism to enhance SPR are analyzed in depth using experiments combined with simulation calculations (FDTD/DFT). Finally, the MXene@MOF/peptides-SPR sensor is constructed for rapid and sensitive detection of the cancer marker exosomes to explore its potential in practical applications. This work offers a forward-looking strategy for the design of interface materials with excellent photoelectric performance.
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The measurement of biosignals in the clinical and healthcare fields is fundamental; however, conventional electrodes pose challenges such as incomplete skin contact and skin-related issues, hindering accurate biosignal measurement. To address these challenges, conductive hydrogels, which are valuable owing to their biocompatibility and flexibility, have been widely developed and explored for electrode applications. In this study, we fabricated a conductive hydrogel by mixing polyethylene glycol diacrylate (PEGDA) with poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) polymers dissolved in deionized water, followed by light-triggered crosslinking. Notably, this study pioneered the use of a PEGDA-PEDOT:PSS hydrogel for electrocardiogram (ECG) monitoring- a type of biosignal. The resulting PEGDA-PEDOT:PSS hydrogel demonstrated remarkable conductivity while closely approximating the modulus of skin elasticity. Additionally, it demonstrated biocompatibility and a high signal-to-noise ratio in the waveforms. This study confirmed the exceptional suitability of the PEGDA-PEDOT:PSS hydrogel for accurate biosignal measurements with potential applications in various wearable devices designed for biosignal monitoring.
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The rapid and efficient detection of chloride (Cl-) ions is crucial in a variety of fields, making the development of advanced sensing methods such as colorimetric sensors an imperative advancement in analytical chemistry. Herein, a novel, selective, and straightforward paper-based colorimetric sensing platform has been developed utilizing an amorphous photonic array (APA) of magnetoplasmonic Ag@Fe3O4 nanoparticles (MagPlas NPs) for the detection of Cl- in water. Taking advantage of the highly responsive APA, the key principle of this sensing method is based on the chemical reaction between Ag+ and Cl-, which results in the precipitation of high-refractive index (RI) AgCl. This assay, distinct from typical plasmonic sensors that rely heavily on nanoparticle aggregation/anti-aggregation, is premised on the precipitation reaction of Ag+ and Cl-. In the presence of Cl-, a rapid, distinctive color alteration from royal purple to a dark sky blue is visually observable within a short time of a few minutes, eliminating the necessity for any surface modification procedures. Comprehensive assessments substantiated that these sensors display commendable sensitivity, selectivity, and stability, thereby establishing their effective applicability for Cl- analysis in various technological fields.
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In wearable bioelectronics, various studies have focused on enhancing prosthetic control accuracy by improving the quality of physiological signals. The fabrication of conductive composites through the addition of metal fillers is one way to achieve stretchability, conductivity, and biocompatibility. However, it is difficult to measure stable biological signals using these soft electronics during physical activities because of the slipping issues of the devices, which results in the inaccurate placement of the device at the target part of the body. To address these limitations, it is necessary to reduce the stiffness of the conductive materials and enhance the adhesion between the device and the skin. In this study, we measured the electromyography (EMG) signals by applying a three-layered hydrogel structure composed of chitosan-alginate-chitosan (CAC) to a stretchable electrode fabricated using a composite of styrene-ethylene-butylene-styrene and eutectic gallium-indium. We observed stable adhesion of the CAC hydrogel to the skin, which aided in keeping the electrode attached to the skin during the subject movement. Finally, we fabricated a multichannel array of CAC-coated composite electrodes (CACCE) to demonstrate the accurate classification of the EMG signals based on hand movements and channel placement, which was followed by the movement of the robot arm.
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Skin has a dynamic surface and offers essential information through biological signals originating from internal organs, blood vessels, and muscles. Soft and stretchable bioelectronics can be used in wearable machines for long-term stability and to continuously obtain distinct bio-signals in conjunction with repeated expansion and contraction with physical activities. While monitoring bio-signals, the electrode and skin must be firmly attached for high signal quality. Furthermore, the signal-to-noise ratio (SNR) should be high enough, and accordingly, the ionic conductivity of an adhesive hydrogel needs to be improved. Here, we used a chitosan-alginate-chitosan (CAC) triple hydrogel layer as an interface between the electrodes and the skin to enhance ionic conductivity and skin adhesiveness and to minimize the mechanical mismatch. For development, thermoplastic elastomer Styrene-Ethylene-Butylene-Styrene (SEBS) dissolved in toluene was used as a substrate, and gold nanomembranes were thermally evaporated on SEBS. Subsequently, CAC triple layers were drop-casted onto the gold surface one by one and dried successively. Lastly, to demonstrate the performance of our electrodes, a human electrocardiogram signal was monitored. The electrodes coupled with our CAC triple hydrogel layer showed high SNR with clear PQRST peaks.
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Background: Heterocyclic analogs of curcumin have a wide range of therapeutic potential and the ability to control the activity of a variety of metabolic enzymes. Methods: 1H-NMR and 13C-NMR spectroscopic techniques were used to determine the structures of synthesized compounds. The agar disc diffusion method and α-amylase inhibition assay were used to examine the antibacterial and anti-diabetic potential of the compounds against α-amylase enzyme inhibitory activity, respectively. DPPH-free radical scavenging and lipid peroxidation inhibition assays were used to assess the in vitro antioxidant potential. Results and Discussion: In this work, nine heterocyclic analogs derived from curcumin precursors under ultrasonic irradiation were synthesized in excellent yields (81.4-93.7%) with improved reaction time. Results of antibacterial activities revealed that compounds 8, and 11 displayed mean inhibition zone of 13.00±0.57, and 19.66±00 mm, respectively, compared to amoxicillin (12.87±1.41 mm) at 500 µg/mL against E. coli, while compounds 8, 11 and 16 displayed mean inhibition zone of 17.67±0.57, 14.33±0.57 and 23.33±00 mm, respectively, compared to amoxicillin (13.75±1.83 mm) at 500 µg/mL against P. aeruginosa. Compound 11 displayed a mean inhibition zone of 11.33±0.57 mm compared to amoxicillin (10.75±1.83 mm) at 500 µg/mL against S. aureus. Compound 11 displayed higher binding affinities of -7.5 and -8.3 Kcal/mol with penicillin-binding proteins (PBPs) and ß-lactamases producing bacterial strains, compared to amoxicillin (-7.2 and -7.9 Kcal/mol, respectively), these results are in good agreement with the in vitro antibacterial activities. In vitro antidiabetic potential on α-amylase enzyme revealed that compounds 11 (IC50=7.59 µg/mL) and 16 (IC50=4.08 µg/mL) have higher inhibitory activities than acarbose (IC50=8.0 µg/mL). Compound 8 showed promising antioxidant inhibition efficacy of DPPH (IC50 = 2.44 g/mL) compared to ascorbic acid (IC50=1.24 g/mL), while compound 16 revealed 89.9±20.42% inhibition of peroxide generation showing its potential in reducing the development of lipid peroxides. In silico molecular docking analysis, results are in good agreement with in vitro biological activity. In silico ADMET profiles suggested the adequate oral drug-likeness potential of the compounds without adverse effects. Conclusion: According to our findings, both biological activities and in silico computational studies results demonstrated that compounds 8, 11, and 16 are promising α-amylase inhibitors and antibacterial agents against E. coli, P. aeruginosa, and S. aureus, whereas compound 8 was found to be a promising antioxidant agent.
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The rational synthesis and tailoring of metal-organic frameworks (MOFs) with multifunctional micro/nanoarchitectures have emerged as a subject of significant academic interest owing to their promising potential for utilization in advanced energy storage devices. Herein, we explored a category of three-dimensional (3D) NiCo2S4 nanospikes that have been integrated into a 1D Fe3C microarchitecture using a chemical surface transformation process. The resulting electrode materials, i.e., Fe3C@NiCo2S4 nanospikes, exhibit immense potential for utilization in high-performance hybrid supercapacitors. The nanospikes exhibit an elevated specific capacity (1894.2 F g-1 at 1 A g-1), enhanced rate capability (59%), and exceptional cycling stability (92.5% with 98.7% Coulombic efficiency) via a charge storage mechanism reminiscent of a battery. The augmented charge storage characteristics are attributed to the collaborative features of the active constituents, amplified availability of active sites inherent in the nanospikes, and the proficient redox chemical reactions of multi-metallic guest species. When using nitrogen-doped carbon nanofibers as the anode to fabricate hybrid supercapacitors, the device exhibits high energy and power densities of 62.98 Wh kg-1 and 6834 W kg-1, respectively, and shows excellent long-term cycling stability (95.4% after 5000 cycles), which affirms the significant potential of the proposed design for applications in hybrid supercapacitors. The DFT study showed the strong coupling of the oxygen from the electrolyte OH- with the metal atom of the nanostructures, resulting in high adsorption properties that facilitate the redox reaction kinetics.
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In this study, a Ag/WO3/InGaN hybrid heterostructure was successfully developed by sputtering and molecular beam epitaxy techniques, to obtain unique Ag nanospheres adorned with cauliflower-like WO3 nanostructure over the InGaN nanorods (NRs). Exploiting the localized surface plasmon resonance of Ag, the Ag/WO3/InGaN heterostructure exhibited superior photoabsorption ability in the visible region (400-700 nm) of the solar spectrum, with a surface plasmon resonance band centered around 440 nm. Comprehensive analysis through photoluminescence spectroscopy, photocurrent measurements, and electrochemical impedance spectroscopy revealed that the Ag/WO3/InGaN hybrid heterostructure significantly enhances the charge carrier separation and transfer kinetics leading to improved overall photoelectrochemical (PEC) performance. The photocurrent density of the Ag/WO3/InGaN photoanode is 1.17 mA/cm2, which is about 2.72 times higher than that of pure InGaN NRs under visible light irradiation. The photoanode exhibited excellent stability for about 12 h. From the study, it has been found that the maximum applied bias photon-to-current efficiency (ABPE) is â¼1.67% at the applied bias of 0.6 V. The improved PEC water splitting efficiency of the Ag/WO3/InGaN photoanode is attributed to the synergistic effects of localized surface plasmon resonance (LSPR), efficient charge carrier separation and transport, and the presence of a Schottky junction. Consequently, the plasmonic metal-assisted heterojunction-based semiconductor Ag/WO3/InGaN demonstrates immense potential for practical applications in photoelectrochemical water splitting.
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A feasible nanoscale framework of heterogeneous plasmonic materials and proper surface engineering can enhance photoelectrochemical (PEC) water-splitting performance owing to increased light absorbance, efficient bulk carrier transport, and interfacial charge transfer. This article introduces a new magnetoplasmonic (MagPlas) Ni-doped Au@Fex Oy nanorods (NRs) based material as a novel photoanode for PEC water-splitting. A two stage procedure produces core-shell Ni/Au@Fex Oy MagPlas NRs. The first-step is a one-pot solvothermal synthesis of Au@Fex Oy . The hollow Fex Oy nanotubes (NTs) are a hybrid of Fe2 O3 and Fe3 O4 , and the second-step is a sequential hydrothermal treatment for Ni doping. Then, a transverse magnetic field-induced assembly is adopted to decorate Ni/Au@Fex Oy on FTO glass to be an artificially roughened morphologic surface called a rugged forest, allowing more light absorption and active electrochemical sites. Then, to characterize its optical and surface properties, COMSOL Multiphysics simulations are carried out. The core-shell Ni/Au@Fex Oy MagPlas NRs increase photoanode interface charge transfer to 2.73 mAcm-2 at 1.23 V RHE. This improvement is made possible by the rugged morphology of the NRs, which provide more active sites and oxygen vacancies as the hole transfer medium. The recent finding may provide light on plasmonic photocatalytic hybrids and surface morphology for effective PEC photoanodes.
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Here, the structural, optical, and adsorptive behaviors of Ni0.075-xMnxAl0.025(OH)2(CO3)0.0125·yH2O (Ni-Mn/Al) layered double hydroxides (LDHs) are investigated to capture fluoride from aqueous media. The 2D mesoporous plate-like Ni-Mn/Al LDHs are successfully prepared via a co-precipitation method. The molar ratio of divalent to trivalent cations is maintained at 3:1 and the pH at 10. The X-ray diffraction (XRD) results confirm that the samples consist of pure LDH phases with a basal spacing of 7.66 to 7.72 Å, corresponding to the (003) planes at 2θ of 11.47o and the average crystallite sizes of 4.13 to 8.67 nm. The plate-like Mn-doped Ni-Al LDH consists of many superimposed nanosheets with a size of 9.99 nm. Energy-dispersive X-ray and X-ray photoelectron spectroscopies confirm the incorporation of Mn2+ into the Ni-Al LDH. UV-vis diffuse reflectance spectroscopy results indicate that incorporating Mn2+ into LDH enhances its interaction with light. The experimental data from the batch fluoride adsorption studies are subjected to kinetic models such as pseudo-first order and pseudo-second order. The kinetics of fluoride retention on Ni-Mn/Al LDH obey the pseudo-second-order model. The Temkin equation well describes the equilibrium adsorption of fluoride. The results from the thermodynamic studies also indicate that fluoride adsorption is exothermic and spontaneous.
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Trace-level ammonia gas in air was analyzed using a fiber-based compact cavity ring-down spectrometer (CRDS). For the compact spectrometer, a 20 cm linear cavity with two high reflectivity (>99.999%) mirrors was employed. The laser frequency was locked to the cavity resonance by using frequency shifted (160 MHz) optical feedback. For N H 3 detection, a strong absorption band at 1513.98 nm with an absorption cross section of 3.3â 10-21 c m/m o l e c u l e was used. As a result, a detection sensitivity of â¼0.1p p b (3-σ) was achieved for N H 3 within 10 s.