Hybridization of Layered Titanium Oxides and Covalent Organic Nanosheets into Hollow Spheres for High-Performance Sodium-Ion Batteries with Boosted Electrical/Ionic Conductivity and Ultralong Cycle Life.

While development of a sodium-ion battery (SIB) cathode has been approached by various routes, research on compatible anodes for advanced SIB systems has not been sufficiently addressed. The anode materials based on titanium oxide typically show low electrical performances in SIB systems primarily due to their low electrical/ionic conductivity. Thus, in this work, layered titanium oxides were hybridized with covalent organic nanosheets (CONs), which exhibited excellent electrical conductivity, to be used as anodes in SIBs. Moreover, to enlarge the accessible areas for sodium ions, the morphology of the hybrid was formulated in the form of a hollow sphere (HS), leading to the highly enhanced ionic conductivity. This synthesis method was based on the expectation of synergetic effects since titanium oxide provides direct electrostatic sodiation sites that shield organic components and CON supports high electrical and ionic conductivity with polarizable sodiation sites. Therefore, the hybrid shows enhanced and stable electrochemical performances as an anode for up to 2600 charge/discharge cycles compared to the HS without CONs. Furthermore, the best reversible capacities obtained from the hybrid were 426.2 and 108.5 mAh/g at current densities of 100 and 6000 mA/g, which are noteworthy results for the TiO2-based material.

Exfoliation and Reassembly Routes to a Ge/RuO2 Nanocomposite as an Anode for Advanced Lithium-Ion Batteries.

Ge/RuO2 nanocomposites were successfully fabricated as anode materials for lithium-ion batteries using RuO2 nanosheets and Ge/GeO2 nanoparticles (NPs). X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) analyses showed that elemental Ge nanoparticles were distributed onto the rutile-type RuO2. Transmission electron microscopy images showed well-dispersed Ge nanoparticles embedded in rutile-type RuO2. The Ge/RuO2 nanocomposite maintained higher discharge capacities (471 mA h g-1) after the 90th cycle at 0.1 A g-1 than that (211 mA h g-1) of Ge/GeO2 nanoparticles. The Ge/RuO2 nanocomposite exhibited a higher capacity retention than Ge/GeO2 NPs. These results suggest that the well-dispersed Ge nanoparticles within RuO2 matrices enhance the cycle stability and capacity retention of the anode material.

Microwave-Assisted Synthesis of Reduced Graphene Oxide with Hollow Nanostructure for Application to Lithium-Ion Batteries.

In this study, reduced graphene oxide (RGO) with a hollow nanostructure was successfully synthesized by layer-by-layer self-assembly using electrostatic interactions and van der Waals forces between building blocks, and its lithium storage characteristics were investigated. After 800 cycles at a current density of 1 A/g, the microwave-irradiated RGO hollow spheres (MRGO-HS) maintained a capacity of 626 mA h/g. In addition, when the charge/discharge capacity was measured stepwise in the current density range of 0.1-2 A/g, the discharge capacity of the RGO rapidly decreased to 156 mA h/g even at the current density of 2 A/g, whereas MRGO-HS provided a capacity of 252 mA h/g. Even after the current density was restored at a current density of 0.1 A/g, the MRGO-HS capacity was maintained to be 827 mA h/g at the 100th cycle, which is close to the original reversible capacity. Thus, MRGO-HS provides a higher capacity and better rate capability than those of traditionally synthesized RGO.

Two-Dimensional Organic/Inorganic Hybrid Nanosheet Electrodes for Enhanced Electrical Conductivity toward Stable and High-Performance Sodium-Ion Batteries.

Invited for this month's cover are the groups of Jae-Min Oh, Jin Kuen Park, and Seung-Min Paek at three different universities in South Korea. The image shows how the supramolecular interaction between two different two-dimensional materials can control the electrical storage properties for a sodium-ion battery. The Full Paper itself is available at 10.1002/cssc.202100545.

Two-Dimensional Organic/Inorganic Hybrid Nanosheet Electrodes for Enhanced Electrical Conductivity toward Stable and High-Performance Sodium-Ion Batteries.

To investigate the effect of electrical conductivity on the energy-storage characteristics of anode materials in sodium-ion batteries, covalent organic nanosheets (CONs) are hybridized with highly conductive graphene nanosheets (GNs) via two different optimized synthesis routes, that is, reflux and solvothermal methods. The reflux-synthesized hybrid shows a well-overlapped 2D structure, whereas the solvothermally prepared hybrid forms a segregated phase in which the contact area between the CONs and GNs is reduced. These two hybrids synthesized by facile methods are fully characterized, and the results reveal that their energy-storage properties can be significantly improved by enhancing the electrical conductivity via the formation of a well-overlapped structure between CONs and GNs. The discharge capacity and rate capability of the reflux-synthesized hybrid was considerably larger than that of the bare CONs, highlighting that the improvement in the charge-carrier transport properties can improve the accessibility of Na ions to the surface of the hybrids. This synthetic methodology can be extended to the fabrication of high-performance anodes for Na-ion batteries.

Controlled Growth of Silver Oxide Nanoparticles on the Surface of Citrate Anion Intercalated Layered Double Hydroxide.

Silver oxide nanoparticles with controlled particle size were successfully obtained utilizing citrate-intercalated layered double hydroxide (LDH) as a substrate and Ag+ as a precursor. The lattice of LDH was partially dissolved during the reaction by Ag+. The released hydroxyl and citrate acted as a reactant in crystal growth and a size controlling capping agent, respectively. X-ray diffraction, X-ray photoelectron spectroscopy, and microscopic measurements clearly showed the development of nano-sized silver oxide particles on the LDH surface. The particle size, homogeneity and purity of silver oxide were influenced by the stoichiometric ratio of Ag/Al. At the lowest silver ratio, the particle size was the smallest, while the chemical purity was the highest. X-ray photoelectron spectroscopy and UV-vis spectroscopy results suggested that the high Ag/Al ratio tended to produce silver oxide with a complex silver environment. The small particle size and homogeneous distribution of silver oxide showed advantages in antibacterial efficacy compared with bulk silver oxide. LDH with an appropriate ratio could be utilized as a substrate to grow silver oxide nanoparticles with controlled size with effective antibacterial performance.