This study investigates how temperature and forward osmosis (FO) membrane properties, such as water permeability (A), solute permeability (B), and structural parameter (S), affect the specific energy consumption (SEC) of forward osmosis-reverse osmosis system. The results show that further SEC reduction beyond the water permeability of 3 LMH bar-1 is limited owing to high concentration polarization (CP). Increasing S by 10-fold increases FO recovery by 177.6%, causing SEC decreases by 33.6%. However, membrane with smaller S also increases external CP. To reduce SEC, future work should emphasize mixing strategies to reduce external CP. Furthermore, increasing the temperature from 10 to 40 °C can reduce SEC by 14.3%, highlighting the energy-saving potential of temperature-elevated systems. The factorial design indicates that at a lower temperature, increasing A and decreasing S have a more significant impact on reducing SEC. This underlines the importance of developing advanced FO membranes, particularly for lower-temperature processes.
Desalination of hypersaline brine is known as one of the methods to cope with the rising global concern on brine disposal in high-salinity water treatment. However, the main problem of hypersaline brine desalination is the high energy usage resulting from the high operating pressure. In this work, we carried out a parametric analysis on a spiral wound membrane (SWM) module to predict the performance of hypersaline brine desalination, in terms of mass transfer and specific energy consumption (SEC). Our analysis shows that at a low inlet pressure of 65 bar, a significantly higher SEC is observed for high feed concentration of brine water compared with seawater (i.e., 0.08 vs. 0.035) due to the very low process recovery ratio (i.e., 1%). Hence, an inlet pressure of at least 75 bar is recommended to minimise energy consumption. A higher feed velocity is also preferred due to its larger productivity when compared with a slightly higher energy requirement. This study found that the SEC reduction is greatly affected by the pressure recovery and the pump efficiencies for brine desalination using SWM, and employing them with high efficiencies (ηR ≥ 95% and ηpump ≥ 50%) can reduce SEC by at least 33% while showing a comparable SEC with SWRO desalination (<5.5 kWh/m3).
The use of microalgae for wastewater remediation and nutrient recovery answers the call for a circular bioeconomy, which involves waste resource utilization and ecosystem protection. The integration of microalgae cultivation and wastewater treatment has been proposed as a promising strategy to tackle the issues of water and energy source depletions. Specifically, microalgae-enabled wastewater treatment offers an opportunity to simultaneously implement wastewater remediation and valuable biomass production. As a versatile technology, membrane-based processes have been increasingly explored for the integration of microalgae-based wastewater remediation. This review provides a literature survey and discussion of recent progressions and achievements made in the development of membrane photobioreactors (MPBRs) for wastewater treatment and nutrient recovery. The opportunities of using microalgae-based wastewater treatment as an interesting option to manage effluents that contain high levels of nutrients are explored. The innovations made in the design of membrane photobioreactors and their performances are evaluated. The achievements pave a way for the effective and practical implementation of membrane technology in large-scale microalgae-enabled wastewater remediation and nutrient recovery processes.
Introduction: Nanomaterials aggregation within polyamide (PA) layer of thin film nanocomposite (TFN) membrane is found to be a common issue and can negatively affect membrane filtration performance. Thus, post-treatment on the surface of TFN membrane is one of the strategies to address the problem. Objective: In this study, an eco-friendly surface modification technique based on plasma enhanced chemical vapour deposition (PECVD) was used to deposit hydrophilic acrylic acid (AA) onto the PA surface of TFN membrane with the aims of simultaneously minimizing the PA surface defects caused by nanomaterials incorporation and improving the membrane surface hydrophilicity for reverse osmosis (RO) application. Methods: The TFN membrane was first synthesized by incorporating 0.05 wt% of functionalized titania nanotubes (TNTs) into its PA layer. It was then subjected to 15-s plasma deposition of AA monomer to establish extremely thin hydrophilic layer atop PA nanocomposite layer. PECVD is a promising surface modification method as it offers rapid and solvent-free functionalization for the membranes. Results: The findings clearly showed that the sodium chloride rejection of the plasma-modified TFN membrane was improved with salt passage reduced from 2.43% to 1.50% without significantly altering pure water flux. The AA-modified TFN membrane also exhibited a remarkable antifouling property with higher flux recovery rate (>95%, 5-h filtration using 1000 mg/L sodium alginate solution) compared to the unmodified TFN membrane (85.8%), which is mainly attributed to its enhanced hydrophilicity and smoother surface. Furthermore, the AA-modified TFN membrane also showed higher performance stability throughout 12-h filtration period. Conclusion: The deposition of hydrophilic material on the TFN membrane surface via eco-friendly method is potential to develop a defect-free TFN membrane with enhanced fouling resistance for improved desalination process.
Biofouling , Nanocomposites , Biofouling/prevention & control , Filtration/methods , Nanocomposites/chemistry , Nylons/chemistry , Osmosis
Simulation via Computational Fluid Dynamics (CFD) offers a convenient way for visualising hydrodynamics and mass transport in spacer-filled membrane channels, facilitating further developments in spiral wound membrane (SWM) modules for desalination processes. This paper provides a review on the use of CFD modelling for the development of novel spacers used in the SWM modules for three types of osmotic membrane processes: reverse osmosis (RO), forward osmosis (FO) and pressure retarded osmosis (PRO). Currently, the modelling of mass transfer and fouling for complex spacer geometries is still limited. Compared with RO, CFD modelling for PRO is very rare owing to the relative infancy of this osmotically driven membrane process. Despite the rising popularity of multi-scale modelling of osmotic membrane processes, CFD can only be used for predicting process performance in the absence of fouling. This paper also reviews the most common metrics used for evaluating membrane module performance at the small and large scales.
