RESUMEN
We investigated the adsorption mechanisms for removing fluoride based on experimental and modeling studies. Lanthanum-aluminum perovskite was designed for treating wastewater contaminated by fluoride. A fluorine-species model was developed to calculate the concentrations of different species of fluorine: F-, HF, HF2-. Multiple kinetic models were examined and the pseudo-second order model was found the best to fit the experimental data, implying fast-chemisorption. The thermodynamic data were fitted by the Langmuir model and Freundlich model at different temperatures, indicating heterogeneous adsorption at low temperature and homogeneous adsorption at high temperature. The La2Al4O9 material had less influence from negative ions when adsorbing fluoride. The adsorption mechanisms were further studied using experiments and Density Functional Theory calculations. The adsorption experiments could be attributed to the lattice plane (1 2 1) and La, O, Al sites. More Al sites were required than La sites for the increase of fluoride concentration. By contrast, more La sites than Al sites were needed for increased pH.
Asunto(s)
Contaminantes Químicos del Agua , Purificación del Agua , Adsorción , Aluminio , Compuestos de Calcio , Fluoruros , Concentración de Iones de Hidrógeno , Cinética , Lantano , Óxidos , Termodinámica , TitanioRESUMEN
Stabilization of arsenic sulfur slag (AsâS slag) is of high importance to prevent the release of deadly As pollutants into environment. However, the molecular understanding on the stability of AsâS slag is missing, which in turn restricts the development of robust approach to solve the challenge. In this work, we investigated the structure-stability relationship of AsâS slag with adopting various AsâS clusters as prototypes by density functional theory (DFT). Results showed that the configuration of S multimers-covering-(As2S3)n is the most stable structure amongst the candidates by the analysis of energies and bonding characteristics. The high stability is explained by orbital composition that the 4p-orbital (As) binding with 3p-orbital (S) decreases energy level of highest occupied molecular orbital (HOMO). Inspired from the calculations, an excess-S-based hydrothermal method was successfully proposed and achieved to promote the stabilization of AsâS slag. Typically, the As concentration from the leaching test of stabilized AsâS slag is only 0.8 mg/L, which is much lower than the value from other stabilized slag.
RESUMEN
The interactions between Fe2SiO4 and ZnO play an essential role in the recovery of zinc from copper slag. The dissolution and substitution mechanism of ZnO in fayalite were investigated by using TG-DSC, XRD, PPMS DynaCool, XPS, Mossbauer and SEM-EDS analyses and compared with MS calculation results. The results indicate that the dissolution and substitution are actually processes of the penetrating dissolution of Zn(II) ions that can be divided into three steps: 1) ZnO dissociates into Zn1-yO and Zn(II) ions; 2) Zn(II) penetrates the gap of the octahedron outer layer to substitute Fe(II) sites in the internal structure of SiOFe(II) (M2) to form (Fe2-x, Znx)SiO4; 3) Fe(II) is forced to migrate to the surface of (Fe2-x, Znx)SiO4 to form (Zn1-y, Fe(II)y)O. These findings can be derived the occurrence state and distribution of zinc in copper slag theoretically.