Enhanced green remediation and refinement disposal of electrolytic manganese residue using air-jet milling and horizontal-shaking leaching.

The reclamation and reuse of electrolytic manganese residue (EMR) as a bulk hazard solid waste are limited by its residual ammonia nitrogen (NH4+-N) and manganese (Mn2+). This work adopts a co-processing strategy comprising air-jet milling (AJM) and horizontal-shaking leaching (HSL) for refining and leaching disposal of NH4+-N and Mn2+ in EMR. Results indicate that the co-use of AJM and HSL could significantly enhance the leaching of NH4+-N and Mn2+ in EMR. Under optimal milling conditions (50 Hz frequency, 10 min milling time, 12 h oscillation time, 400 rpm rate, 30 â„ƒ temperature, and solid-to-liquid ratio of 1:30), NH4+-N and Mn2+ leaching efficiencies were optimized to 96.73% and 97.35%, respectively, while the fineness of EMR was refined to 1.78 µm. The leaching efficiencies of NH4+-N and Mn2+ were 58.83% and 46.96% higher than those attained without AJM processing. The AJM used strong airflow to give necessary kinetic energy to EMR particles, which then collided and sifted to become refined particles. The AJM disposal converted kinetic energy into heat energy upon particle collisions, causing EMR phase transformation, and particularly hydrated sulfate dehydration. The work provides a fire-new and high-efficiency method for significantly and simply leaching NH4+-N and Mn2+ from EMR.

Innovative co-treatment technology for effective disposal of electrolytic manganese residue.

Electrolytic manganese residue (EMR) stockpiles contain significant amounts of Mn2+ and NH4+-N which pose a risk of environmental pollution. For EMR safe disposal, an innovative approach is proposed that involves direct sodium silicate-sodium hydroxide (Na2SiO3-NaOH) collaborative technology. This approach utilises Na2SiO3 and NaOH as the solidifying agent and activator, respectively, to treat EMR without hazardous effects. The study also provides insights into the kinetics of Mn2+ leaching under the effect of Na2SiO3-NaOH. Leaching efficiency was determined by varying parameters such as stirring rate, reaction temperature, pH of the initial solution, Na2SiO3 concentration, and reaction time to investigate the efficacy of this method. The study indicates that the co-treatment technology of Na2SiO3-NaOH can achieve maximum solidification efficiencies of 99.7% and 98.2% for Mn2+ and NH4+-N, respectively. The process can successfully solidify Mn2+ by synthesising Mn(OH)2 and MnSiO3 in an alkaline environment under optimal conditions including stirring rate of 450 rpm, initial solution pH of 8, test temperature of 40 °C, test time of 420 min, and Na2SiO3 content of 5%. The findings of this study have confirmed that surface chemistry plays a vital role in regulating the test rate and the proposed equation accurately describes Mn2+ leaching kinetics. Overall, the co-treatment technology involving Na2SiO3-NaOH is a viable solution for EMR resource utilisation without compromising environmental safety. This method has the potential to be implemented for other waste streams with comparable compositions, ultimately promoting the sustainable management of waste.

Deep insight into green remediation and hazard-free disposal of electrolytic manganese residue-based cementitious material.

This work presents an innovative approach to developing a low-carbon and hazard-free cementitious material (EGC) by activating ground granulated blast-furnace slag (GGBS) with electrolytic manganese residue (EMR), which has an excellent heavy metal solidified capacity. Herein, the multi-step leaching was creatively conducted to investigate the solidified morphology of heavy metals in hazardous EMR. CO2 emission per unit strength factor was calculated to quantitatively analyze the low-carbon degree. The results show that the added hazardous EMR rich in sulfate and the dilution effect caused by the decrease in GGBS lessen the final setting time and fluidity. Low-temperature calcination (200 °C) alters the dissolution rate of ettringite and AFm-like phases by changing the sulfate crystal. Excessive acidic EMR consumes more calcium hydroxide and lowers the pH of the EGC system, resulting in weakened GGBS activity. The formation of jouravskite, thaumasite, and henritermierite are AFm-like hydrated lamellated structures, which provides evidence for the immobilization of Mn2+ in EMR. Vast Mn2+ are embedded in the main interlayer of [Ca2Al(OH)6]+ by substituting Al to form AFm-like phase. The lowest 60d unit compressive strength carbon emission of the EGC system containing 20 % calcinated EMR is 0.78 kg∙MPa-1∙m-3, meaning the substitution barrier is better addressed by adding calcined EMR. This work provides an innovative solution for high value-added and hazard-free utilization for EMR and carbon reduction in the cement industry.

Feasibility of low-carbon electrolytic manganese residue-based supplementary cementitious materials.

In this work, the electrolytic manganese residues (EMR) were used as sulfate activators for fly ash and granulated blast-furnace slag to fabricate highly reactive supplementary cementitious materials (SCMs). The findings promote the implementation of a win-win strategy for carbon reduction and waste resource utilisation. The effects of EMR dosing on the mechanical properties, microstructure and CO2 emission of the EMR-doped cementitious materials are investigated. The results show that low dosing EMR (5 %) produced more ettringite, fostering early strength development. The fly ash-doped mortar strength increases and then decreases with the addition of EMR from 0 to 5 % to 5-20 %. It was found that blast furnace slag contributes less to strength than fly ash. Moreover, the sulfate activation and the micro-aggregate effect compensate for the EMR-induced dilution effect. The significant increase in strength contribution factor and direct strength ratio at each age verifies the sulfate activation of EMR. The lowest EIF90 value of 5.4 kg∙MPa-1∙m3 was achieved for the fly ash-doped mortar with 5 % EMR, suggesting the synergistic effect between fly ash and EMR optimised the mechanical properties while maintaining lower CO2 emissions.

The Mechanical Characteristics of High-Strength Self-Compacting Concrete with Toughening Materials Based on Digital Image Correlation Technology.

Brittle fracture is a typical mechanical characteristic of high-strength self-compacting concrete, and the research on its toughening modification remains the highlight in the engineering field. To understand the effect of toughening materials (including polymer latex powders, rubber particles, and polyethylene fibers) on the mechanical behavior of C80 high-strength self-compacting concrete under static loading, the failure mode, mechanical strength, strain field, and crack opening displacement (COD) of prepared high-strength self-compacting concrete under compressive, splitting, and flexural loads were studied based on digital image technology (DIC). The corresponding mechanism is also discussed. The results show that the hybrid of polymer latex powders, rubber particles, and polyethylene fibers can increase the crack path and inhibit the development of macrocracks in concrete, thus turning the fracture behavior of concrete from brittle to ductile. The addition of toughening materials reduced the compressive and flexural strengths of high-strength self-compacting concrete, but it increased the splitting strength. DIC showed that the incorporation of toughening materials promoted the redistribution of strain and reduced the degree of strain concentration in high-strength self-compacting concrete. The evolution of COD in high-strength self-compacting concrete can be divided into two stages, including the linear growth stage and the plastic yield stage. The linear growth stage can be extended by incorporating toughening materials. The COD and energy absorption capacity of concrete were enhanced with the addition of toughening materials, and the best enhancement was observed with the hybrid of polymer latex powders, rubber particles, and polyethylene fibers. Overall, this research provides a reference for exploring effective technical measures to improve the toughness of high-strength self-compacting concrete.

Properties and Microstructural Characteristics of Manganese Tailing Sand Concrete.

In this work, manganese tailing sand concrete (MTSC) was prepared using manganese tailing sand (MTS) in replacement of river sand (RS) to alleviate the shortage of RS resources and achieve clean treatment and high-value resource utilization of manganese tailing stone. The effects of MTS content on the slump, mechanical strength, air void characteristics, hydration products and micromorphology of MTSC were studied experimentally. The leaching risk of harmful substances in MTSC was also explored by testing the concentration of Mn2+. The results show that the utilization of MTS reduces the slump of MTSC to a certain extent. When the MTS content is lower than 40%, the gypsum introduced by MTS and C3A in cement undergoes a hydration reaction to form ettringite, which decreases the number of pores with a diameter less than 0.1 mm and promotes strength development in MTSC. Additionally, when the MTS content exceeds 40%, the large amount of gypsum reacts to form more ettringite. The expansive stress generated by the ettringite severely damages the pore structure, which is not conducive to the mechanical properties of MTSC. In addition, the leaching of hazardous substances in MTSC is insignificant, and the incorporation of cement can effectively reduce the risk of leaching hazardous substances in MTSC. In summary, it is completely feasible to use MTS to replace RS for concrete preparation when the substitution rate of MTS is less than 40%, with no risk of environmental pollution. The results and adaptation in the concrete industry can reduce the carbon footprint, which is in line with the current trend in civil and materials engineering.

Water treatment sludge conversion to biochar as cementitious material in cement composite.

Water treatment sludge was successfully thermally converted to obtain biochar as a stable material with resource potential. This research explored the application of sludge biochar as a supplementary cementitious material. The cement paste samples incorporating different amounts of sludge biochar were prepared, hardened, and analyzed for performance. The results show an improvement in hydration kinetics and mechanical properties of cement paste incorporating biochar, compared to raw sewage sludge. The mineralogical, thermal and microscopic analyses show evidence of pozzolanic activity of the biochar. The samples with 2% and 5% biochar showed higher heat release than the reference material. Specimens with 1%, 2% and 5% biochar showed a slightly higher compressive strength at 28 days compared to the reference material. Sludge conversion to biochar will incur an estimated cost of US$398.23/ton, which is likely to be offset by the substantial benefits from avoiding landfill and saving valuable cementitious materials. Therefore, this research has demonstrated that through conversion to biochar, water treatment sludge can be promoted as a sustainable and alternative cementitious material for cement with minimum environmental impacts, hence contributing to circular economy.

A Comparative Study on the Mechanical Properties and Microstructure of Cement-Based Materials by Direct Electric Curing and Steam Curing.

Direct electric curing (EC) is a new green curing method for cement-based materials that improves the early mechanical properties via the uniform high temperature produced by Joule heating. To understand the effects of EC and steam curing (SC) on the mechanical properties and microstructure of cement-based materials, the mortar was cured at different temperature-controlled curing regimes (40 °C, 60 °C, and 80 °C). Meanwhile, the mechanical properties, hydrates and pore structures of the specimens were investigated. The energy consumption of the curing methods was compared. The results showed that the EC specimens had higher and more stable growth of mechanical strength. The hydration degree and products of EC samples were similar to that of SC samples. However, the pore structure of EC specimens was finer than that of SC specimens at different curing ages. Moreover, the energy consumption of EC was much lower than that of SC. This study provides an important technical support for the EC in the production of energy-saving and high early-strength concrete precast components.

Effects of Temperature on Fluidity and Early Expansion Characteristics of Cement Asphalt Mortar.

In order to solve the problems of the sudden loss of fluidity and low expansion rate of CAM I (cement asphalt mortar type I) in a construction site with high environmental temperature, this paper studies the effect of temperature on the fluidity, expansion ratio and pH value of CAM I. The mechanism of action was analyzed by IR (infrared spectrometry), SEM (scanning electron microscopy) and other test methods. The results showed that a high temperature accelerates aluminate formation in cement paste. Aluminate adsorbs emulsifiers leading to demulsification of emulsified asphalt, and wrapped on the surface of cement particles, this causes CAM I to lose its fluidity rapidly. The aluminum powder gasification reaction is inhibited, resulting in an abnormal change in the expansion ratio. Based on findings, the application of an appropriate amount of superplasticizers can effectively improve the workability and expansion characteristics of CAM I at a high temperature.

A Review on Bubble Stability in Fresh Concrete: Mechanisms and Main Factors.

In order to improve the stability of air bubbles in fresh concrete, it is of great significance to have a better understanding of the mechanisms and main influencing factors of bubble stability. In the present review, the formation and collapse process of air bubbles in fresh concrete are essentially detailed; and the advances of major influencing factors of bubble stability are summarized. The results show that the surface tension of air-liquid interface exerts a huge impact on bubble stability by reducing surface free energy and Plateau drainage, as well as increasing the Gibbs surface elasticity. However, surface tension may not be the only determinant of bubble stability. Both the strength of bubble film and the diffusion rate of air through the membrane may also dominate bubble stability. The application of nano-silica is a current trend and plays a key role in ameliorating bubble stability. The foam stability could be increased by 6 times when the mass fraction of nano-particle reached 1.5%.

Preparation of Green Low Strength Mixture for Foundation Reinforcement Treatment by Using Fly Ash and Waste Coal Gangue.

Effective foundation reinforcement treatment is essential for modern large and complex infrastructure, while it is significant for developing new green high-performance materials for foundation reinforcement. This study investigates a new green concrete by using high volume fly-ash and coal gangue aggregates, which is expected to apply for foundation treatment of modern infrastructure with high loading-bear ability. In this experiment, 12 mix proportions of fly ash coal gangue mixture (the material name, abbreviated FGM) were designed, and its mechanical properties and durability performance were investigated. The mechanical properties of FGM include compressive strength, dynamic elastic modulus, dynamic shear modulus, Poisson's ratio, and the stress-strain behaviors. The durability performance was evaluated by the parameters of acid resistance, which simulated an acid circumstance. After that, the environmental effects about carbon emission of this material were also investigated. Results show that the FGM with 84.6% wastes utilizing rate is a cost-effective material for foundation reinforcing treatment. Its compressive strength at 28 days and 60 days can reach more than 8 MPa and 10 MPa, respectively. After being immersed in the acid environment for 140 days, the mass loss (%) of the material could be under 3.5%. The greenness shows that the e-CO2 indices of FGM are lower than 20 kg/MPa·m3, and the e-energy indices are at below 150 MJ/MPa·m3. FGM has the advantages of acid resistance, waste recycling, and lower carbon emissions than the previous methods for foundation improvement.

Influence of Nano-SiO2, Nano-CaCO3 and Nano-Al2O3 on Rheological Properties of Cement-Fly Ash Paste.

Rheological curves of cement-fly ash (C-FA) paste incorporating nanomaterials including nano-SiO2 (NS), nano-CaCO3 (NC) and nano-Al2O3 (NA) at different resting times (hydration time of 5 min, 60 min, and 120 min) were tested with a rheometer. The rheological behaviors were described by the Herschel-Bulkley (H-B) model, and the influences of these nanomaterials on rheological properties of C-FA paste were compared. Results show that the types, content of nanomaterials and resting time have great influences on the rheological properties of C-FA paste. Incorporating NS and NA increases yield stress and plastic viscosity, and decreases the rheological index of C-FA paste. When the content of NS and NA were 2 wt%, the rheological index of C-FA paste was less than 1, indicating rheological behavior changes from shear thickening to shear thinning. Meanwhile, with rising resting time, yield stress and plastic viscosity increased significantly, but the rheological index decreased evidently, showing paste takes on shear thinning due to the rise of resting time. However, incorporating 3 wt% NC and the rising of resting time did not change the rheological properties of C-FA paste. These differences are mainly that the specific surface area (SSA) of NS (150 m2/g) and NA (120 m2/g) are much larger than that of NC (40 m2/g). The huge SSA of NS and NA consume lots of free water and these tiny particles accelerate the hydration process during resting time.