Ecotoxicological risk of asphalt pavements to aquatic animals associated with pollutant leaching.

Contaminants such as heavy metals and polycyclic aromatic hydrocarbons (PAHs) can be released from asphalt pavement and transported through stormwater runoff to nearby water bodies, leading to water pollution and potential harm to living aquatic animals. This study characterizes the heavy metal and PAH leaching from various asphalt paving materials and their potential ecotoxicological effects on zebrafish Danio rerio. Artificial runoffs were prepared in the laboratory concerning the effects of water, temperature, and traffic. The concentrations of heavy metals and PAHs in the leachates were quantified, while the toxicity assessment encompassed mortality, metal stress, PAH toxicity, inflammation, carcinogenicity, and oxidative damage. Gene expressions of related proteins or transcription factors were assessed, including metallothionines, aryl hydrocarbon receptors, interleukin-1ß, interleukin-10, nuclear factor-κB, tumor necrosis factor-α, tumor suppressor p53, heat shock protein 70, and reactive oxygen species (ROS). The findings demonstrate that leachates from asphalt pavements containing waste bottom ash, crumb rubber, or specific chemicals could induce notable stress and inflammation responses in zebrafish. In addition, potential carcinogenic effects and the elevation of ROS were identified within certain treatment groups. This study represents the first attempt to assess the ecotoxicity of pavement leachates employing a live fish model, thereby improving the current understanding of the environmental impact of asphalt pavements.

Leaching characteristics of metals and Polycyclic Aromatic Hydrocarbons (PAHs) from asphalt paving materials.

Asphalt pavement, a major type of road surface, may contain hazardous elements depending on its specific composition. A growing concern has developed regarding the potential leaching of these hazardous constituents from asphalt pavements, particularly when incorporating waste materials and additives. This study investigates the presence of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in leachates from six commonly employed asphalt paving materials. A comprehensive laboratory leaching experiment was conducted on three key sample scales: asphalt binder, asphalt mortar, and asphalt mixture. The impact of the leachates was assessed by the heavy metal pollution index and the toxic equivalency factor based on the benzo[a]pyrene equivalent concentration. The results reveal that leaching tests at the binder and mortar scales provided fundamental insights into leaching characteristics within a relatively short timeframe, while the mixture-scale test was more capable of representing pollutant leaching in near-true scenarios. In addition, the results indicate potential adverse health implications associated with the incorporation of hazardous waste, such as bottom ash, into asphalt pavement. These findings hold significant implications for promoting environmentally responsible practices of asphalt pavement.

Kinetics and toxicological potential of heavy metal leaching from asphalt pavements.

The leaching of heavy metals from asphalt pavement has attracted increasing attention due to its associated environmental risks. Comprehending the leaching process is crucial for ensuring the safe utilization of asphalt pavement. This study investigates heavy metal leaching kinetics from asphalt pavements using tank-leaching tests and dynamic simulations employing both first and second-order kinetic models. Furthermore, this study reveals the toxicological potential of heavy metal leaching from asphalt pavement by assessing its temporal metal accessibility based on the obtained kinetic attributes. Six distinct asphalt mixtures were prepared and tested, each exhibiting two different gradations. The findings demonstrated that both kinetic models effectively elucidated the leaching process. Notably, the relatively stable final leaching stages primarily adhered to first-order kinetics, while the second-order kinetics provided a superior description of the more intricate initial leaching stages. In terms of toxicological potential, the results indicated that recycled waste-incorporated asphalt pavements, specifically bottom ash-incorporated asphalt and asphalt rubber, exhibited excessive heavy metal leaching for varying durations, ranging from several days to months under specific conditions. This study has provided valuable insights into the metal leaching kinetics of asphalt pavements and their associated toxicological impact, significantly advancing the current understanding of the consequences of heavy metal leaching from asphalt pavements.

[Characteristics of climate change and its impacts on water resources in Qilian Mountains, China]. / ç¥è¿žå±±æ°”å€™å˜åŒ–ç‰¹å¾åŠå ¶å¯¹æ°´èµ„æºçš„å½±å“.

Qilian Mountains, is an important ecological function area, an important ecological security barrier, the river runoff region in Northwest China, as well as a sensitive area to global climate change and fragile area of ecological environment. The ecological environment in this area played an important role in the economic development of Northwest China. Based on the observation data of temperature and precipitation in Qilian Mountains, MOD10A2 snow products and the flow data of Shiyang River, Heihe River and Shule River, we systematically analyzed the characteristics of climate change from 1961 to 2020, and the impacts of climate change on water resources under the scenario of climate warming. The results showed that, from 1961 to 2020, the annual average temperature increased significantly, with the rate reaching 0.39 ℃·(10 a)-1. The warming rate was the highest in the western part of Qilian Mountains, followed by the middle and eastern regions. The warming trend was the strongest in winter and the lowest in spring. The average temperature changed abruptly in 1997. The annual average precipitation increased with flucturation, with a rate of 10 mm·(10 a)-1, which increased most obviously in the middle of Qilian Mountains. After 2004, it entered a rainy period, with a warm and humid trend. The precipitation in the four seasons showed an increasing trend and the increase of precipitation in summer contributed the most to the annual precipitation. Annual precipitation was dominated by interannual scale change, and the contribution rate of 2.8-year was approximately 64.3%. The snow cover of Qilian Mountains was obviously affected by temperature and snowfall, which was negatively correlated with summer temperature and positively correlated with snowfall. From 2016 to 2020, the temperature increase had slowed down in Qilian Mountains, the snowfall had increased, and the snow cover tended to increase. After 2000, the temperature and precipitation increased more obviously, the meltwater from glacier and snow increased, the mountainous runoff of Shiyang River, Heihe River and Shule River had an increasing trend. Our findings are of great significance to the construction of ecological civilization and coping with climate change in Qilian Mountains.

Comparison of Mechanical Responses of Asphalt Mixtures under Uniform and Non-Uniform Loads Using Microscale Finite Element Simulation.

Continuously increasing traffic volumes necessitate accurate design methods to ensure the optimal service life and efficient use of raw materials. Numerical simulations commonly pursue a simplified approach with homogeneous pavement materials and homogeneous loading. Neither the pavement geometry nor the loading is homogeneous in reality. In this study, the mechanical response of the asphalt mixtures due to homogeneous loads is compared with their mechanical response to inhomogeneous loads. A 3D finite element model was reconstructed with the aid of X-ray computed tomography. Sections of a real tire's pressure distribution were used for the inhomogeneous loads. The evaluation of the material response analyzes the stress distribution within the samples. An inhomogeneous load evokes an increased proportion of high stresses within the sample in every case, particularly at low temperatures. When comparing the two types of loads, the average stresses on the interior (tension and compression) exhibit significant differences. The magnitude of the discrepancies shows that this approach yields results that differ significantly from the common practice of using homogeneous models and can be used to improve pavement design.

Sustainable Green Pavement Using Bio-Based Polyurethane Binder in Tunnel.

As a closed space, the functional requirements of the tunnel pavement are very different from ordinary pavements. In recent years, with the increase of requirements for tunnel pavement safety, comfort and environmental friendliness, asphalt pavement has become more and more widely used in long tunnels, due to its low noise, low dust, easy maintenance, and good comfort. However, conventional tunnel asphalt pavements cause significant safety and environmental concerns. The innovative polyurethane thin overlay (PTO) has been developed for the maintenance of existing roads and constructing new roads. Based on the previous study, the concept of PTO may be a feasible and effective way to enrich the innovative functions of tunnel pavement. In this paper, the research aims to evaluate the functional properties of PTO, such as noise reduction, solar reflection and especially combustion properties. Conventional asphalt (Open-graded Friction Course (OGFC) and Stone Mastic Asphalt (SMA)) and concrete pavement materials were used as control materials. Compared with conventional tunnel pavement materials, significant improvements were observed in functional properties and environmental performance. Therefore, this innovative wearing layer can potentially provide pavements with new eco-friendly functions. This study provides a comprehensive analysis of these environmentally friendly materials, paving the way for the possible application in tunnels, as well as some other fields, such as race tracks in stadiums.

Numerical Simulation of Crack Propagation in Flexible Asphalt Pavements Based on Cohesive Zone Model Developed from Asphalt Mixtures.

To give engineers involved in planning and designing of asphalt pavements a more accurate prediction of crack initiation and propagation, theory-based models need to be developed to connect the loading conditions and fracture mechanisms present in laboratory tests and under traffic loading. The aim of this study is to develop a technical basis for the simulation of fracture behavior of asphalt pavements. The cohesive zone model (CZM) approach was applied in the commercial FE software ABAQUS to analyze crack propagation in asphalt layers. The CZM developed from the asphalt mixtures in this study can be used to simulate the fracture behavior of pavements and further optimize both the structure and the materials. The investigations demonstrated that the remaining service life of asphalt pavements under cyclic load after the initial onset of macro-cracks can be predicted. The developed CZM can, therefore, usefully supplement conventional design methods by improving the accuracy of the predicted stress states and by increasing the quality, efficiency, and safety of mechanical design methods by using this more realistic modeling approach.

Laboratory and Numerical Investigation of Microwave Heating Properties of Asphalt Mixture.

Microwave heating is an encouraging heating technology for the maintenance, recycling, and deicing of asphalt pavement. To investigate the microwave heating properties of asphalt mixture, laboratory tests and numerical simulations were done and compared. Two types of Stone Mastic Asphalt (SMA) mixture samples (with basalt aggregates and steel slag aggregates) were heated using a microwave oven for different times. Numerical simulation models of microwave heating of asphalt mixture were developed with finite element software COMSOL Multiphysics. The main thermal and electromagnetic properties of asphalt mixture, served as the model input parameters, were measured through a series of laboratory tests. Both laboratory-measured and numerical simulated surface temperatures were recorded and analyzed. Results show that the replacement of basalt aggregates with steel slag aggregates can significantly increase the microwave heating efficiency of asphalt mixture. Numerical simulation results have a good correlation with laboratory test results. It is feasible to use the developed model coupling electromagnetic waves with heat transfer to simulate the microwave heating process of asphalt mixture.

Effect of Aging on Chemical and Rheological Properties of Bitumen.

Engineering performance of asphalt pavement highly depends on the properties of bitumen, the bonding material to glue aggregates and fillers together. During the service period, bitumen is exposed to sunlight, oxygen and vehicle loading which in turn leads to aging and degradation. A comprehensive understanding of the aging mechanism of bitumen is of critical importance to enhance the durability of asphalt pavement. This study aims to determine the relations between micro-mechanics, chemical composition, and macro-mechanical behavior of aged bitumen. To this end, the effect of aging on micro-mechanics, chemical functional groups, and rheological properties of bitumen were evaluated by atomic force microscope, Fourier transform infrared spectroscopy and dynamic shear rheometer tests, respectively. Results indicated that aging obviously increased the micro-surface roughness of bitumen. A more discrete distribution of micromechanics on bitumen micro-surface was noticed and its elastic behavior became more significant. Aging also resulted in raised content of carbonyl, sulfoxide, and aromatic ring functional groups. In terms of rheological behavior, the storage modulus of bitumen apparently increased after aging due to the transformation of viscous fractions to elastic fractions, making it stiffer and less viscous. By correlation analysis, it is noted that the bitumen rheological behavior was closely related to its micro-mechanics.