The effect of biological methods for MSW treatment on the physicochemical, microbiological and phytotoxic properties of used biofilter bed media.

Biofilters are commonly used in municipal solid waste treatment (MSW) facilities to remove odors and pollutants from process gases. However, the effectiveness of biofilter bed media decreases over time, necessitating periodic replacement. The type of the treatment process may affect the lifespan of the bed and the way it should be utilized after replacement. This study aimed to analyze the physical, chemical, calorific, microbiological, and phytotoxic parameters of bed media in biofilters operated at an industrial scale in MSW treatment plants. The experiments included three full cycles of biofiltering gases from biodrying, composting, and aerobic biostabilization in two variations. Physicochemical properties (moisture, organic matter, carbon, nitrogen, sulfur, heavy metal contents), respiration activity (AT4), phytotoxicity, and microorganism abundance were determined for initial materials and samples from two biofilter layers collected after each cycle. Results revealed a substantial reduction in AT4 (by 63%-87% compared to initial material), significant moisture content increase in the bottom layers (by 61% or more, depending on the process), and a considerable decrease in microorganism abundance. Biofilter bed media from biodrying and composting exhibited low environmental risk (low heavy metal concentrations, negligible phytotoxicity, and microbiological stability). However, bed packings from aerobic biostabilization processes showed significant inhibition of indicator plants and incomplete sanitization (presence of pathogens like E. coli and Salmonella spp.). Therefore, these bed packings can be utilized for energy recovery, such as incineration after drying. This research provides significant insights into the effectiveness and safety of biofilter bed media in MSW treatment plants.

Life cycle assessment (LCA) and energy assessment of the production and use of windows in residential buildings.

There is an observable scarcity of comprehensive research results comparing the environmental damage associated with both the production of windows and their subsequent operation. The environmental impact of the operation of windows depends on their thermal insulation parameters, and thus the amount of heat that must be generated to heat the building. The type of heating system and, above all, the type of fuel used to generate heat are also not without significance. Unfortunately, in Poland, a significant proportion of single-family houses operate on the fossil fuel heating system, including on coal and fuel oil. It is therefore important to present an environmental balance sheet of both the production and operation of windows for different variants of building heating. The purpose of the study was to determine: to what extent the manufacturing of windows of different construction and different insulation parameters affects the environment, to what extent does the negative environmental impact of the process of manufacturing with greater insulation compensate by the lower environmental impact related to savings on fuel (gas, coal, fuel oil) used to generate heat during the operation of windows. Three types of windows were selected for a detailed analysis: a triple-glazed aluminum construction, a double-glazed PVC construction and a triple-glazed PVC. The research results show that in the case of all impact categories, the greater environmental losses related to the improvement of the thermal insulation parameters of the windows at the production stage are fully compensated at the stage of their useful life, regardless of the type of fuel used to heat the buildings. Double-glazed PVC windows should be phased out of production due to significant environmental footprint associated with their operation.

Negotiation and honesty in artificial intelligence methods for the board game of Diplomacy.

The success of human civilization is rooted in our ability to cooperate by communicating and making joint plans. We study how artificial agents may use communication to better cooperate in Diplomacy, a long-standing AI challenge. We propose negotiation algorithms allowing agents to agree on contracts regarding joint plans, and show they outperform agents lacking this ability. For humans, misleading others about our intentions forms a barrier to cooperation. Diplomacy requires reasoning about our opponents' future plans, enabling us to study broken commitments between agents and the conditions for honest cooperation. We find that artificial agents face a similar problem as humans: communities of communicating agents are susceptible to peers who deviate from agreements. To defend against this, we show that the inclination to sanction peers who break contracts dramatically reduces the advantage of such deviators. Hence, sanctioning helps foster mostly truthful communication, despite conditions that initially favor deviations from agreements.

The Impact of Kohlrabi Sprouts on Various Thyroid Parameters in Iodine Deficiency- and Sulfadimethoxine-Induced Hypothyroid Rats.

Brassica sprouts, as the rich source of dietary glucosinolates, may have a negative effect on thyroid function. In this study, kohlrabi sprouts diet, combined with two models of rat hypothyroidism, was tested. TSH, thyroid hormones and histopathology analysis were completed with the evaluation of immunological, biochemical, haematological parameters, cytosolic glutathione peroxidase, thioredoxin reductase in the thyroid, and plasma glutathione peroxidase. A thermographic analysis was also adapted to confirm thyroid dysfunction. The levels of TSH, fT3 and fT4, antioxidant enzyme (GPX) as well as histopathology parameters remained unchanged following kohlrabi sprouts ingestion, only TR activity significantly increased in response to the sprouts. In hypothyroid animals, sprouts diet did not prevent thyroid damage. In comparison with the rats with iodine deficiency, kohlrabi sprouts diet decreased TNF-α level. Neither addition of the sprouts to the diet, nor sulfadimethoxine and iodine deficiency, caused negative changes in red blood cell parameters, glucose and uric acid concentrations, or kidney function. However, such a dietary intervention resulted in reduced WBC levels, and adversely interfered with liver function in rats, most likely due to a higher dietary intake of glucosinolates. Moreover, the possible impact of the breed of the rats on the evaluated parameters was indicated.

Impact of Biochar Addition and Air-Flow Rate on Ammonia and Carbon Dioxide Concentration in the Emitted Gases from Aerobic Biostabilization of Waste.

Application of additives to waste may influence the course of the biostabilization process and contribute to its higher effectiveness, as well as to a reduction in greenhouse gas and ammonia (NH3) emission from this process. This paper presents research on the impact of biochar addition on the course of the biostabilization process of an undersized fraction from municipal solid waste (UFMSW) in terms of temperature changes, CO2 concentration in the exhaust gases, NH3 emission from the process, as well as changes in the carbon and nitrogen content in the processed waste. Six different biochar additives and three different air-flow rates were investigated for 21 days. It was found that biochar addition contributes to extending the thermophilic phase duration (observed in the case of the addition of 3% and 5% of biochar). The concentration of CO2 in exhaust gases was closely related to the course of temperature changes. The highest concentration of CO2 in the process gases (approx. 18-19%) was recorded for the addition of 10% and 20% of biochar at the lowest air-flow rate applied. It was found that the addition of 3% or a higher amount of biochar reduces nitrogen losses in the processed UFMSW and reduces NH3 emission by over 90% compared to the control.

Impact of digestate addition on the biostabilization of undersized fraction from municipal solid waste.

Biostabilization is a commonly applied method in mechanical-biological treatment (MBT) plants to process municipal solid waste. In many ways, e.g. by applying additives to waste, MBT plant operators strive to enhance the effectiveness of biostabilization, which leads to reducing the time and energy outlays necessary for the process, as well as to minimizing the amount of final stabilized waste directed to landfills. This paper deals with the impact of digestate waste from agricultural biogas plants used as additive to the biostabilization process of undersized fraction from municipal solid waste (UFMSW) on the intensive phase of the process and properties of stabilized waste. The aim of this study was to assess whether, and if so to what extent, the application of digestate waste affects the process. Five different input compositions were tested (without digestate and with the addition of digestate at: 2.5; 5; 7.5 and 10 wt%). Waste treatment time was 2 weeks. Changes in moisture content, organic matter (OM), respiration activity (AT4), bulk density, air-filled porosity, heavy metal content, pH, carbon to nitrogen ratio, as well as composition of process gases emitted were evaluated. Additionally, microorganisms (including pathogens) inhabiting the processed waste in the aspect of waste sanitation were analyzed. It was found that the addition of digestate at 2.5, 5 and 7.5 wt% extended the duration of the thermophilic phase and decreased the CO2 content in process gases. The addition of digestate at 2.5 wt% and 5 wt%, decreased also OM by approx. 25% of the initial value and AT4 by approx. 30%. It was also proved that the addition of digestate favors the limited sanitation of UFMSW. As a result of the research, it was found that the addition of digestate at 2.5 wt% and 5 wt% is sufficient to accelerate the aerobic biological degradation of UFMSW.

Impact of Calcium Oxide on Hygienization and Self-Heating Prevention of Biologically Contaminated Polymer Materials.

During the storage of spent polymer materials derived from municipal solid waste, which contain biodegradable impurities, an intense growth of microorganisms takes place. The aerobic metabolism of microorganisms may cause these materials to combust spontaneously and to become a real epidemiological risk for humans. The aim of the research is to determine the optimal addition of calcium oxide (CaO), which effectively reduces the number of selected microorganism groups populating the analyzed materials, in which spent polymers represent a significant fraction: refuse-derived fuel (RDF) and an undersize fraction of municipal solid waste (UFMSW). The main novelty of the experiments is to assess the benefits of using the commonly available and cheap filler (CaO), to hygienize the material and to reduce the fire hazard arising from its storage. During the mixing of spent polymer materials with pulverized CaO (mass shares: 1, 2, and 5% CaO), temperature changes were monitored using thermography. Moisture content (MC), pH, respiration activity (AT4) and bacterial count were determined before and after the experiment. During the addition of CaO (especially when the content was at 5%) to the UFMSW, higher maximum temperatures were obtained than in the case of RDF analyses, which may be the result of a high percentage of the biodegradable fraction and higher MC of the UFMSW. In all cases the waste temperature did not increase again after 3 min. CaO used in the experiment effectively limited the number of microorganisms. The addition of 5% of CaO has showed the strongest antimicrobial properties, and it can be recommended for hygienization of the analyzed materials and for the reduction of the risk of self-heating during their storage in windrows.

Animals in Iodine Deficiency or Sulfadimethoxine Models of Thyroid Damage Are Differently Affected by the Consumption of Brassica Sprouts.

The study was primarily aimed at investigating the effect of brassica sprout consumption, namely rutabaga (Brassica napus L. var. napobrassica) sprouts (R) generally recognized as antithyroid agent due to its goitrogenic substance content, on hematological, biochemical, and immunological parameters in rats. Sprouts were tested alone and in a combination with other antithyroid factors, such as iodine deficiency (RDI) and sulfadimethoxine (RS). The expression of the heme oxygenase-1 (HO-1) gene in the thyroid as a stress-inducible protein was determined. The thermographic analysis was also estimated. The intake of rutabaga sprouts by healthy rats did not reveal any significant, harmful effect on the thyroid function. Both body temperature and expression of HO-1 remained unchanged in response to the consumed sprouts. In animals with hypothyroidism, rutabaga sprouts enhanced the negative effect of iodine deficiency or sulfadimethoxine ingestion on the organism by increasing the WBC (RDI), TNF-α (RS), creatinine (RS), and triglyceride (RDI and RS) levels, as well as decreasing PLT (RS) level. Moreover, rutabaga sprout consumption by rats with iodine deficiency and sulfadimethoxine decreased their body temperature. Additionally, the concomitant administration of sprouts and iodine depletion significantly reduced the expression of HO-1 in the thyroid. The results may prove useful in confirming rutabaga sprout consumption to be safe, though the seeds of this vegetable provide a well-known antithyroid agent. Our results have shown that rutabaga sprout consumption may be also a factor that enhances the negative clinical features only when combined with iodine deficiency and sulfadimethoxine ingestion.

The Use of Biodrying to Prevent Self-Heating of Alternative Fuel.

Alternative fuels (refuse-derived fuels-RDF) have been a substitute for fossil fuels in cement production for many years. RDF are produced from various materials characterized by high calorific value. Due to the possibility of self-ignition in the pile of stored alternative fuel, treatments are carried out to help protect entrepreneurs against material losses and employees against loss of health or life. The objective of the research was to assess the impact of alternative fuel biodrying on the ability to self-heat this material. Three variants of materials (alternative fuel produced on the basis of mixed municipal solid waste (MSW) and on the basis of bulky waste (mainly varnished wood and textiles) and residues from selective collection waste (mainly plastics and tires) were adopted for the analysis. The novelty of the proposed solution consists in processing the analyzed materials inside the innovative ecological waste apparatus bioreactor (EWA), which results in increased process efficiency and shortening its duration. The passive thermography technique was used to assess the impact of alternative fuel biodrying on the decrease in the self-heating ability of RDF. As a result of the conducted analyses, it was clear that the biodrying process inhibited the self-heating of alternative fuel. The temperature of the stored fuel reached over 60 °C before the biodrying process. However, after the biodrying process, the maximum temperatures in each of the variants were about 30 °C, which indicates a decrease in the activity of microorganisms and the lack of self-ignition risk. The maximum temperatures obtained (>71 °C), the time to reach them (≈4 h), and the duration of the thermophilic phase (≈65 h) are much shorter than in the studies of other authors, where the duration of the thermophilic phase was over 80 h.

Effect of biochar addition on the OFMSW composting process under real conditions.

The article evaluates the effect of small selected doses of biochar addition (0%, 1.5%, 3% and 5%, wet weight) on the composting process of the organic fraction of municipal solid waste (OFMSW) with a low initial C/N ratio under real conditions. The low C/N composting mixtures with addition of biochar at low rates can have a positive effect on the compost quality and on the reduction of N losses in compost. The novelty of this work consists in studying the impact of small biochar doses on the composting process at full-scale. The research was conducted under real conditions in the Brno Central Composting Plant (Czech Republic) receiving food waste, grass, straw, sawdust, mineral waste, paper, wood and sewage sludge for processing. The experimental processing time was 12 weeks. We evaluated changes in carbon (C), nitrogen (N), moisture content (MC), organic matter (OM), respiration activity (AT4), as well as changes in the microbiocenotic composition of microorganisms colonizing the processed waste. OFMSW with the addition of biochar and compost were assessed for the content of heavy metals (HM). It was found out that biochar reduced the compost toxicity. The resulting compost with the addition of biochar exhibited higher moisture content and lower waste density. Biochar had an impact on N retention during composting but it did not change the course or accelerate the composting process. The highest OM loss (62.6%) was observed in the OFMSW with no biochar addition. The abundance of potentially pathogenic microorganisms clearly decreased during the OFMSW composting process with the addition of biochar.

Effect of broccoli sprouts on thyroid function, haematological, biochemical, and immunological parameters in rats with thyroid imbalance.

Broccoli sprouts may exert a negative influence on thyroid function as they are a rich source of glucosinolates, in particular glucoraphanin. Under the study in a long-term experiment broccoli sprouts were tested as an element of rats diet, combined with deficient iodine, or sulfadimethoxine ingestion - two models of hypothyroidism. Evaluations were performed for serum TSH and thyroid hormones completed with analyzes of selected haematological, biochemical and immunological (IL-6, IL-10) parameters, as well as cytosolic glutathione peroxidase (GPX1), thioredoxin reductase (TR) in the thyroid, and plasma glutathione peroxidase (GPX3). A thermographic analysis was conducted to provide auxiliary indicators for determining a potential thyroid dysfunction under the specific experimental conditions. The levels of TSH, fT3 and fT4 remained unchanged following broccoli sprouts ingestion, which was even found to have a protective effect against sulfadimethoxine induced thyroid damage. Moreover, TR activity significantly increased in response to sprouts ingestion. In animals with hypothyroidism, broccoli sprouts were found to exert a beneficial influence on the antioxidant balance of the thyroid gland. In comparison to the rats with iodine deficiency, broccoli sprouts addition to the diet was observed to decrease IL-6 level. No significant differences in IL-10 concentration were determined. Neither addition of broccoli sprouts to the diet, nor sulfadimethoxine and iodine deficiency, caused negative changes in red blood cell parameters, glucose and uric acid concentrations, or kidney function. However, such a dietary intervention resulted in reduced WBC and PLT levels, and it may adversely interfere with liver function in rats, most likely due to a higher dietary intake of glucosinolates.