Nucleation-enhanced condensation and fast shedding on self-lubricated silicone organogels.

A cross-linked silicone elastomer swollen in silicone oil releases at its surface a thin oil layer, whose thickness slowly increases with time as a consequence of surface energy minimization and residual crosslinking reactions within the polymer matrix. Here, we tune and characterize this oil layer thickness (between 0 and 5 µm) in order to show its quantitative influence on the physical mechanisms at play during water condensation: droplet nucleation and growth, coarsening by menisci-mediated coalescences, and droplet shedding by gravity. We show that continuous nucleation is at the origin of enhanced condensation. Spontaneous replenishment of the oil layer occurs thanks to the storage of oil in the bulk of the swollen elastomer, allowing the same sample to be used for repeated long-lasting condensation experiments.

Memory Re-Condensation.

This paper reveals a phenomenon of memory in dropwise condensation in open air. After a first condensation process and complete evaporation of the condensed droplets, further condensations proceed with droplets nucleating at the very places where former droplets evaporated. The origin of this phenomenon is due to the incorporation of airborne salts during the first droplet condensation and its further concentration during droplet evaporation. Salts act as preferential nucleation sites and humidity sinks. The potential impact of this phenomenon on controlled breath figure patterns and plant metabolism is discussed.

Tailoring silicon for dew water harvesting panels.

Dew water, mostly ignored until now, can provide clean freshwater resources, just by extracting the atmospheric vapor available in surrounding air. Inspired by silicon-based solar panels, the vapor can be harvested by a concept of water condensing panels. Efficient water harvesting requires not only a considerable yield but also a timely water removal from the surface since the very beginning of condensation to avoid the huge evaporation losses. This translates into strict surface properties, which are difficult to simultaneously realize. Herein, we study various functionalized silicon surfaces, including the so-called Black Silicon, which supports two droplet motion modes-out-of-plane jumping and in-plane sweeping, due to its unique surface morphology, synergistically leading to a pioneering combination of above two required characteristics. According to silicon material's scalability, the proposed silicon-based water panels would benefit from existing infrastructures toward dual functions of energy harvesting in daytime and water harvesting in nighttime.

Roughness-enhanced collection of condensed droplets.

Gravity shedding of droplets is limited by droplet pinning, a major limitation for low condensation processes and in particular passive dew harvesting in its use as an alternative source of water. We present experiments showing that, paradoxically, a simple surface treatment increasing roughness (sand-blasting) favors droplet shedding compared to the original substrate, provided that sand-blasting does not increase too much the surface roughness. Sand-blasting ensures the high density of nucleation sites and enhances drops coalescence and growth at a sub-micron scale, thus lowering the lag-time to obtain drop sliding during condensation. Early nucleation indeed overcompensates the delay increase due to roughness. Edges of the substrate, where drops grow faster, also improve water collection, thanks to the early sliding of edge drops that behave as natural wipers. Combining the effects of sand-blasting and edges increases significantly the rate of collection of dew condensation on a substrate at a given time, gains of about 30% can be commonly obtained.

Grooves Accelerate Dew Shedding.

Gravity-driven drainage of small volumes of condensates, such as natural dew, is a challenge because small drops usually remain pinned to inclined surfaces. We report that submillimetric grooves substantially reduce dew retention by modifying the repartition of liquid: Because of a long-range coalescence mechanism mediated by grooves imbibition, the growth and shedding of large drops are accelerated. Such findings can be applied to increase the passive harvesting of dew as well as to accelerate the drainage of other condensates.

Edge effects on water droplet condensation.

In this study we investigate the effect of geometrical or thermal discontinuities on the growth of water droplets condensing on a cooled substrate. Edges, corners, and cooled and noncooled boundaries can have a strong effect on the vapor concentration profile and mass diffusion around the drops. In comparison to growth in a pattern where droplets have to compete to catch vapor, which results in a linear water concentration profile directed perpendicularly to the substrate, droplets near discontinuities can get more vapor (outer edges, corners), resulting in faster growth or less vapor (inner edges), giving lower growth. When the cooling heat flux limits growth instead of mass diffusion (substrate with low thermal conductivity, strong heat exchange with air), edge effects can be canceled. In certain cases, growth enhancement can reach nearly 500% on edges or corners.

Effective hydrodynamic boundary conditions for microtextured surfaces.

Understanding the influence of topographic heterogeneities on liquid flows has become an important issue with the development of microfluidic systems, and more generally for the manipulation of liquids at the small scale. Most studies of the boundary flow past such surfaces have concerned poorly wetting liquids for which the topography acts to generate superhydrophobic slip. Here we focus on topographically patterned but chemically homogeneous surfaces, and measure a drag force on a sphere approaching a plane decorated with lyophilic microscopic grooves. A significant decrease in the force compared with predicted even for a superhydrophobic surface is observed. To quantify the force we use the effective no-slip boundary condition, which is applied at the imaginary smooth homogeneous isotropic surface located at an intermediate position between the top and bottom of grooves. We relate its location to a surface topology by a simple, but accurate analytical formula. Since grooves represent the most anisotropic surface, our conclusions are valid for any texture, and suggest rules for the rational design of topographically patterned surfaces to generate desired drag.