Advances in the fabrication, modification, and performance of biochar, red mud, calcium oxide, and bentonite catalysts in waste-to-fuel conversion.

Various catalysts are being used in fuel production from biomass and polymeric waste for the obtention of an alternative energy source with both environmental friendliness and economic viability. Biochar, red mud bentonite, and calcium oxide have been shown to play a pertinent role as catalysts in waste-to-fuel conversion processes, such as transesterification and pyrolysis. In this line of thought, this paper has provided a compendium of the fabrication and modification technologies of bentonite, red mud calcium oxide, and biochar, together with their various performances in their application in the waste-to-fuel processes. Additionally, an overview of the structural and chemical attributes of these components is discussed regarding their efficiency. Ultimately, research trends and future points of focus are evaluated, and it is observed that techno-economic optimization of catalyst synthetic routes and investigation of new catalytic formulations, such as biochar and red mud-based nanocatalysts, are potential prospects. This report also offers future research directions that are anticipated to contribute to the development of sustainable green fuel generation systems.

EI/IOT of PFCs: Environmental impacts/interactions, occurrences, and toxicities of perfluorochemicals.

Various studies have been conducted on the perfluorochemicals (PFCs) family over the years. These compounds have been sought in various industrial aspects involving the synthesis of everyday utilities due to their broad range of applications. As a result, PFCs have built up in the environment, causing concern. The presence of PFCs in various environmental media, such as terrestrial and marine settings, as well as the mechanisms of transport, bioaccumulation, and physio-chemical interactions of PFCs within plants, aquatic organisms, microplastics, and, ultimately, the human body, are discussed in this review, which draws on a variety of research publications. The interaction of PFCs with proteins, translocation, and adsorption by hydrophobic interactions were observed, and this had an impact on the natural functioning of biological processes, resulting in events such as phylogenic clustering, competitive inhibition, and many others, posing potential hazards to human health and other relevant organisms in the ecosystem. However, further research is needed to have a better knowledge of PFCs and their interactions so that low-cost treatments can be developed to eliminate them. It is therefore, future research should focus on the role of soil matrix as a defensive mechanism for PFCs, as well as the impact of PFC chain length rejection.