1.
Chem Pharm Bull (Tokyo)
; 72(3): 303-308, 2024.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38479853
RESUMEN
Amine-free phosphorylation of various alcohols was developed with 4-methylpyridine N-oxide in the presence of 4 Å molecular sieves at room temperature. This mild method gave various phosphorylated products in high yield and could be applied to acid- or base-sensitive substrates. Furthermore, this method was also effective for the chemoselective phosphorylation of diols or polyols.