Plasmon Enhanced Second Harmonic Generation from ZnO Nanofilms on Vertical Au Nanorod Arrays.

Vertically aligned gold nanorod arrays have attracted much attention for their fascinating optical properties. Different from longitudinal surface plasmon wavelength (LSPW) and edge-to-edge spacing of gold nanorods, the role of gold nanorod diameter in plasmonic enhancement ability of vertical gold nanorod arrays has rarely been explored. In this work, we selected gold nanorods with similar LSPW but two different diameters (22 and 41 nm), the optical properties of which are dominated by absorption and scattering cross sections, respectively. The vertically aligned arrays of these gold nanorods formed by evaporation self-assembly are coupled with nonlinear ZnO nanocrystal films spin-coated on their surfaces. It was found that the gold nanorod array with a larger diameter can enhance the second harmonic generation (SHG) of ZnO nanofilm by a factor of 27.0, while it is about 7.3 for the smaller gold nanorod array. Theoretical simulations indicate that such stronger enhancement of the larger vertical gold nanorod array compared with the smaller one is due to its stronger scattering ability and greater extent of near-field enhancement at SHG fundamental wavelength. Our work shows that the diameter of gold nanorods is also an important factor to be considered in realizing strong plasmon enhancement of vertically aligned gold nanorod arrays.

Polarization control of plasmon-induced transparency in metamaterials with reversibly convertible bright and dark modes.

We numerically demonstrate a Z-shaped metal-based metamaterial to realize an active polarization-controlled plasmon-induced transparency (PIT). The metamaterial unit cell contains two horizontal Au bars and a vertical Au bar. Simply by varying the incident light polarization, a tunable PIT can be achieved due to the reversible conversion of bright and dark modes between the horizontal and vertical Au bars. Moreover, a switchable PIT window modulation can be accomplished via changing the geometrical parameters, and the theoretical fittings according to the coupled Lorentz oscillator model display consistency with the simulated results. Our proposed metamaterials provide a promising strategy for fabricating compact PIT devices such as optical switching, sensing, and selective filters.

Bright near-surface silicon vacancy centers in diamond fabricated by femtosecond laser ablation.

We report the generation of single negatively charged silicon vacancy (SiV-) color centers by focusing a femtosecond (fs) laser on top of a high-purity diamond coated with a layer of Si nanoball. Under the interaction of a high-intensity fs laser, Si atoms were ionized and implanted into the diamond, accompanied with the creation of vacancies. After annealing at 850°C in vacuum for 1 h, the photoluminescence spectra of bright spots around the created crater presented a typical strong zero-phonon line at around 737 nm of SiV- centers. Bright single SiV- color centers could be observed with a maximum saturating counting rate of 300×103 counts/s. We explain the formation mechanism of SiV- centers in diamond via a Coulomb explosion model. The results demonstrate that fs laser ablation can be utilized as a very promising tool to conveniently fabricate single bright SiV- centers in diamond.

Plasmon-enhanced fluorescence of submonolayer porphyrins by silver-polymer core-shell nanoparticles.

We investigate the fluorescence from submonolayer porphyrin molecules near silver-polymer core-shell nanoparticles (NPs) at a well-controlled separation distance of about 1 nm - 5 nm. When porphyrin molecules are deposited on silver NPs with the plasmonic resonance peak at about 410 nm, which matches very closely with the 405-nm excitation laser and the absorption band of porphyrin molecules, their emission intensity is found to be enhanced due to the plasmonic resonant excitation enhancement, and shows a decline as the increasing polymer shell thickness. Meanwhile, the lifetime results demonstrate that there exists the fluorescence quenching due to the charge transfer and nonradiative energy transfer losses, which is also the main reason that the maximum enhancement factor obtained in experiment is only about 2.3, although the theoretical one is above 60 according to the electric field distribution near silver NPs calculated by finite-difference time-domain method.

Tuning Plasmonic Enhancement of Single Nanocrystal Upconversion Luminescence by Varying Gold Nanorod Diameter.

Plasmonic enhancement induced by metallic nanostructures is an effective strategy to improve the upconversion efficiency of lanthanide-doped nanocrystals. It is demonstrated that plasmonic enhancement of the upconversion luminescence (UCL) of single NaYF4 :Yb3+ /Er3+ /Mn2+ nanocrystal can be tuned by tailoring scattering and absorption cross sections of gold nanorods, which is synthesized wet chemically. The assembly of the single gold nanorod and single upconversion nanocrystal is achieved by the atomic force microscope probe manipulation. By selecting two kinds of gold nanorods with similar longitudinal surface plasmon resonance wavelength but different diameters (27.3 and 46.7 nm), which extinction spectra are separately dominant by the absorption and scattering, the maximum UCL enhancement by a factor of 110 is achieved with the 46.7 nm-diameter gold nanorod, while it is 19 for the nanorod with the diameter of 27.3 nm. Such strong enhancement with the larger gold nanorod is due to stronger scattering ability and greater extent of the near-field enhancement. The enhanced UCL shows a strong dependence on the excitation polarization relative to the nanorod long axis. Time-resolved measurements and finite-difference time-domain simulations unveil that both excitation and emission processes of UCL are accelerated by the nanorod plasmonic effect.