Electrode materials must be rationally designed with morphologies and electroactive sites manipulated through cations' synergy in bimetal compounds in order to maximize the performance of energy storage devices. Therefore, the present study emphasizes binder-free scalable preparation of cobalt nickel vanadate (CNV) thin films by a facile successive ionic layer adsorption and reaction (SILAR) approach with specific cations (Co:Ni) alternation. Increasing the Ni cation content in the CNV notably transforms its microflower structure comprising nanoflakes (252 nm) into nanoparticles (74 nm). An optimized S-CNV5 thin film cathode with Co:Ni molar ratio of â¼ 0.4:0.6 and a high specific surface area of 340 m2 g-1, provided the excellent specific capacitance (Csp) and capacity (Csc) of 1382 F g-1 and 691 C g-1, respectively at 1 A g-1 current density. A hybrid aqueous supercapacitor (HASc) device with positive and negative electrodes comprising optimized CNV and reduced graphene oxide (rGO), respectively, in a 1 M KOH electrolyte delivered a Csp of 133 F g-1 and a specific energy (SE) of 53 Wh kg-1 at a specific power (SP) of 2261 kW kg-1. Additionally, a fabricated hybrid solid-state supercapacitor (HSSc) device with the same electrodes applying PVA-KOH gel electrolyte displayed a Csp of 119 F g-1, and SE of 46 Wh kg-1 at SP of 1184 W kg-1. This boosted electrochemical activity is due to the synergetic effects of Ni and Co species in the CNV thin film electrodes, emphasizing the potential of CNV electrodes as cathodes in hybrid energy storage devices.
2D-2D lattice engineering route is used to synthesize intimately coupled nanohybrids of layered double hydroxide (LDH) and potassium hexaniobate. The 2D-2D lattice engineering route is based on the electrostatically derived self-assembly of delaminated zinc-chromium-layered double hydroxide (ZC-LDH) nanosheets and potassium hexaniobate (HNb) nanosheets (ZCNb nanohybrids). The 2D-2D lattice-engineered ZCNb nanohybrids display expanded surface area, mesoporous anchored nanosheets network morphology, and intimate coupling between nanosheets. The 2D-2D lattice engineered ZCNb nanohybrids are used for the low temperature operated gas sensor. The ZCNb nanohybrids display outstanding selectivity for the SO2, with the high response of 61.5% compared to pristine ZC-LDH (28.08%) and potassium niobate (8%) at 150 °C. Moreover, ZCNb sensors demonstrate superior response and recovery periods of 6 and 167 s at 150 °C, respectively. This result underscores the exceptional functionality of the ZCNb nanohybrids as efficient SO2 sensors. Moreover, these findings vividly demonstrate that the 2D-2D lattice-engineered ZCNb nanohybrids are quite effective not only in improving the gas sensor activity but also in developing of new type of intimately coupled mesoporous LDH-metal-oxide based hybrid materials.
The layer-by-layer mesoporous nanohybrids of Ni-Cr-layered double hydroxide (Ni-Cr-LDH) and polyoxotungstate nanoclusters (Ni-Cr-LDH-POW) are prepared via exfoliation reassembling strategy. The intercalative hybridization of Ni-Cr-LDH with POW nanoclusters leads to forming a layer-by-layer stacking framework with significant expansion of the interplanar spacing and surface area. The aqueous hybrid supercapacitor (AHSC) and all-solid-state hybrid supercapacitor (SSHSC) devices are fabricated using Ni-Cr-LDH-POW nanohybrid as a cathode and reduced graphene oxide (rGO) as an anode material. Notably, the NCW-2//rGO AHSC device delivers an ED of 43 Wh kg-1 at PD of 1.33 kW kg-1 and excellent electrochemical stability over 10,000 charge-discharge cycles. Moreover, NCW-2//rGO SSHSC exhibits an ED of 34 Wh kg-1 at PD of 1.32 kW kg-1 with capacitance retention of 86% after 10,000 cycles. These results highlight the excellent electrochemical functionality and advantages of the Ni-Cr-LDH-POW nanohybrids as a cathode for hybrid supercapacitors.
Designing nanostructure based robust catalyst for the electrochemical water splitting is the great task in the energy conversion field to accomplish high electrical conductivity, low overpotential and long lasting activity. Herein, the electrochemical overall water splitting is reported by using the hydrothermally synthesized binder free cobalt iron phosphate thin films on low cost stainless steel substrates as a conducting backbone for the first time. The effect of composition ratio variation of cobalt and iron was studied on the structural, compositional, morphological, and surface electronic properties by conducting various characterizations which results in amorphous hydrous cobalt iron phosphate having mesoporosity. The as synthesized cobalt iron phosphate having composition ratio (50:50 of Co:Fe) exhibits excellent electrochemical OER and HER catalytic water splitting performance. Best performing electrode exhibits smallest overpotentials of 251.9 mV and 55.5 mV for OER and HER respectively at 10 mA/cm2 current density. To split water molecule into the H2 and O2 by overall water splitting in same alkaline medium, the potential of 1.75 V was required after long duration (100 h) catalysis. Overall analysis confirms the cobalt iron phosphate thin films are outstanding and robust for the hydrogen production as clean renewable energy source.
In the present study, cobalt manganese phosphate (H-CMP-series) thin films with different compositions of Co/Mn are prepared on stainless steel (SS) substrate via a facile hydrothermal method and employed as binder-free cathode electrodes in a hybrid supercapacitor. The XRD study reveals a monoclinic crystal structure, and the FE-SEM analysis confirmed that H-CMP-series samples displayed a nano/microarchitecture (microflowers to nanoflakes) on the surface of SS substrate with excess available surfaces and unique sizes. Interestingly, the synergy between cobalt and manganese species in the cobalt manganese phosphate thin film electrode demonstrates a maximum specific capacitance of 571 F g-1 at a 2.2 A g-1 current density in 1 M KOH. Besides, the nano/microstructured cobalt manganese phosphate was able to maintain capacitance retention of 88% over 8000 charge-discharge cycles. More importantly, the aqueous/all-solid-state asymmetric supercapacitor manufactured with the cobalt manganese phosphate thin film as the cathode and reduced graphene oxide (rGO) as the anode displays a high operating potential window of 1.6 V. The aqueous asymmetric device exhibited a maximum specific capacitance of 128 F g-1 at a current density of 1 A g-1 with an energy density of 45.7 Wh kg-1 and a power density of 1.65 kW kg-1. In addition, the all-solid-state asymmetric supercapacitor device provides a high specific capacitance of 37 F g-1 at 1 A g-1 with 13.3 Wh kg-1 energy density and 1.64 kW kg-1 power density in a polymer gel (PVA-KOH) electrolyte. The long cyclic life of both devices (87 and 84%, respectively, after 6000 cycles) and practical demonstration of the solid-state device (lighting of a LED lamp) suggest another alternative choice for cathode materials to develop stable energy storage devices with high energy density. Furthermore, the aforementioned study paves the way to investigate phosphate-based materials as a new class of materials for supercapacitor applicability.
This work addresses the fabrication of an efficient, novel, and economically viable immunosensing armamentarium that will detect the carcinoembryonic antigen (CEA) typically associated with solid tumors (sarcomas, carcinomas, and lymphomas) and is used as a clinical tumor marker for all these malignancies. We synthesized silver nanoparticles by single-step chemical reduction and coated with silica using a modified Stober method to fabricate silica-coated silver core-shell nanoparticles. The morphologies, structure, and size of the nanoparticles were characterized by Transmission Electron Microscopy (TEM), UV-Visible spectroscopy, X-ray diffraction (XRD), Raman spectroscopy, Fourier Transform Infra-Red Spectroscopy (FTIR), and Dynamic Light Scattering (DLS), respectively. The results indicated that the average size of Ag nanoparticles and silica-coated Ag nanoparticles is 50 nm and 80 nm, respectively. Our TEM results indicate that the silica-shell uniformly encapsulates silver core particles. Further, a disposable electrochemical immunosensor for carcinoembryonic antigen (CEA) was proposed based on the antigen immobilized in a silica-coated silver core-shell nanoparticle film on the surface of an indium-tin-oxide (ITO) flat substrate. The morphological characteristics of the constructed biosensor were observed by scanning electron microscopy (SEM) and electrochemical methods. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) were employed for the characterization of the proposed bioelectrode. The cyclic voltammogram appears to be more irreversible on silica coated silver core-shell nanoparticles. It is found that the fabricated immunosensor shows fast potentiometric response under the optimized conditions. The CEA could be determined in the linear range from 0.5 to 10 ng mL-1 with a detection limit of 0.01 ng mL-1 using the interface. The developed flat substrate of ITO for CEA detection (the model reagent) is a potentially promising immunosensing system, manifests good stability, and allows batch fabrication because of its economic feasibility.
The current paper describes enhanced electrochemical capacitive performance of chemically grown Cobalt hydroxide (Co(OH)2) nanorods (NRs) decorated porous three dimensional graphitic carbon foam (Co(OH)2/3D GCF) as a supercapacitor electrode. Freestanding 3D porous GCF is prepared by carbonizing, high internal phase emulsion (HIPE) polymerized styrene and divinylbenzene. The PolyHIPE was sulfonated and carbonized at temperature up to 850 °C to obtain graphitic 3D carbon foam with high surface area (389 m2 g-1) having open voids (14 µm) interconnected by windows (4 µm) in monolithic form. Moreover, entangled Co(OH)2 NRs are anchored on 3D GCF electrodes by using a facile chemical bath deposition (CBD) method. The wide porous structure with high specific surface area (520 m2 g-1) access offered by the interconnected 3D GCF along with Co(OH)2 NRs morphology, displays ultrahigh specific capacitance, specific energy and power. The Co(OH)2/3D GCF electrode exhibits maximum specific capacitance about ~1235 F g-1 at ~1 A g-1 charge-discharge current density, in 1 M aqueous KOH solution. These results endorse potential applicability of Co(OH)2/3D GCF electrode in supercapacitors and signifies that, the porous GCF is a proficient 3D freestanding framework for loading pseudocapacitive nanostructured materials.
Chemical growth of mixed cobalt-nickel hydroxides (CoxNi1-x(OH)2), decorated on graphene foam (GF) with desirable three-dimensional (3D) interconnected porous structure as electrode and its potential energy storage application is discussed. The nanostructured CoxNi1-x(OH)2 films with different Ni:Co (x) compositions on GF are prepared by using the chemical bath deposition (CBD) method. The structural studies (X-ray diffraction and X-ray photoelectron spectroscopy) of electrodes confirm crystalline nature of CoxNi1-x(OH)2/GF and crystal structure consists of Ni(OH)2 and Co(OH)2. The morphological properties reveal that nanorods of Co(OH)2 reduce in size with increases in nickel content and are converted into Ni(OH)2 nanoparticles. The electrochemical performance reveals that the Co0.66Ni0.33(OH)2/GF electrode has maximum specific capacitance of â¼1847 F g(-1) in 1 M KOH within a potential window 0 to 0.5 V vs Ag/AgCl at a discharge current density of 5 A g(-1). The superior pseudoelectrochemical properties of cobalt and nickel are combined and synergistically reinforced with high surface area offered by a conducting, porous 3D graphene framework, which stimulates effective utilization of redox characteristics and communally improves electrochemical performance with charge transport and storage.
