Analysis of a neutron-induced conversion electron spectrum of gadolinium.

A 100-nm-thick gadolinium layer deposited on a pixelated silicon sensor was activated in a neutron field to measure the internal conversion electron (ICE) spectrum generated by neutron capture products of 155Gd and 157Gd. The experiment was performed at the ISIS neutron and muon facility, using a bespoke version of the HEXITEC spectroscopic imaging camera. Signals originating from internal conversion electrons, Auger electrons, x rays and gamma rays up to 150 keV were identified. The ICE spectrum has an energy resolution of 1.8-1.9 keV at 72 keV and shows peaks from the K, L, M, N+ ICEs of the 79.51 keV and 88.967 keV 2+-0+ gamma transitions from the first excited states in 158Gd and 156Gd, respectively, as well as the K ICEs of the 4+-2+ transitions at 181.931 keV and 199.213 keV from the respective second excited states. Spectrum analysis was performed using a convolution of a Gaussian with exponential functions at the low and high energy side as the peak shaping function. Relative ICE intensities were derived from the fitted peak areas and compared with internal conversion coefficient (ICC) values calculated from the BrIcc database. Relative to the dominant L shell contribution, the K ICE intensity conforms to BrIcc and the M, N, O+ ICE intensities are somewhat higher than expected.

Air humidity and annual oscillations in 90Sr/90Y and 60Co decay rate measurements.

Parkhomov published decay rate measurements of 90Sr/90Y and 60Co beta decay sources with Geiger-Müller counters which showed annual cyclic deviations with less than 0.2% amplitude from a purely exponential slope. He investigated instrument instability induced by environmental parameters, yet did not find a clear coincidence with local temperature, atmospheric pressure, and relative humidity. Parkhomov hypothesised that gravitationally-focussed 'slow' cosmic neutrinos influenced beta decay. In the current work, environmental conditions in the Moscow area at the time of the experiment are presented. There appears to be a resemblance of the shape of the annual 90Sr/90Y decay rate anomalies with the inverse of the absolute air humidity, albeit with an apparent time shift of 0.05-0.15 year. Humidity may have influenced the range of beta particles in air, as well as geometric and electronic properties of the detection set-up, however causality could not be unambiguously demonstrated. The instabilities in the 60Co data were more difficult to correlate with environmental data, except for some similarities with temperature and external dew point.

Measurement of the 145Sm half-life.

The half-life of 145Sm has been measured by means of the reference source method with a HPGe detector. The long-lived radionuclide 44Ti was mixed into the source for reference. The time-dependency of the 145Sm/44Ti activity ratio was followed by assessing the count-rate ratio of their characteristic gamma-ray emissions at 61.2 keV (145Sm) and 67.9/78.3 keV (44Ti) in spectra recorded over periods of typically one day. In total, 220 measurements were performed over a period of 384 days or about one half-life period. The experiment and ensuing uncertainty budget are discussed in detail. Different error propagation is applied for random uncertainties, autocorrelated structures in the fit residuals, and potential systematic errors. The result for the 145Sm half-life, 345 (16) d, is compatible with the scarce literature values, however the experimental details of the old measurements were barely documented.

On the interpretation of annual oscillations in 32Si and 36Cl decay rate measurements.

The 32Si decay rate measurement data of Alburger et al. obtained in 1982-1986 at Brookhaven National Laboratory have been presented repeatedly as evidence for solar neutrino-induced beta decay. The count rates show an annual sinusoidal oscillation of about 0.1% amplitude and maximum at February-March. Several authors have claimed that the annual oscillations could not be explained by environmental influences on the set-up, and they questioned the invariability of the decay constant. They hypothesised a correlation with changes in the solar neutrino flux due to annual variations in the Earth-Sun distance, in spite of an obvious mismatch in amplitude and phase. In this work, environmental conditions at the time of the experiment are presented. The 32Si decay rate measurements appear to be inversely correlated with the dew point in a nearby weather station. Susceptibility of the detection set-up to local temperature and humidity conditions is a likely cause of the observed instabilities in the measured decay rates. Similar conclusions apply to 36Cl decay rates measured at Ohio State University in 2005-2012.

Derivation of an uncertainty propagation factor for half-life determinations.

An analytical equation is derived for the uncertainty propagation factor for a half-life determination from a least-squares fit to equidistant activity measurements performed with identical relative uncertainties. The obtained formula applies to a purely random statistical uncertainty component. It is equivalent to the solution published by Parker in Nucl. Instr. Meth. A 286, 502. A more general equation for weighted least-squares fitting is derived and presented in a compact manner. It is used as a benchmark to verify the applicability of Parker's solution to non-equidistant data with unequal uncertainties.

Alpha-particle emission probabilities of 231Pa derived from first semiconductor spectrometric measurements.

The nuclide 231Pa is a member of the 235U decay chain. It is a complex alpha emitter with 25 identified alpha emissions. Formerly published alpha-particle emission probabilities were derived from measurements taken with magnetic spectrometers. This work presents the first measurements made with semiconductor detectors. High-resolution alpha-particle spectrometry was carried out at CIEMAT and JRC using ion-implanted planar silicon detectors. Alpha-particle emission probabilities of 23 transitions were derived from deconvolutions of the spectra. For the major lines, uncertainties are lower than 1%, a significant improvement to existing data. The new data set will allow a more accurate evaluation of the decay scheme of 231Pa.

Automated optical distance measurements for counting at a defined solid angle.

Two optical distance measurement devices have been compared for accurately defining the source-detector geometry of alpha-particle counters. The first consists of a travelling microscope with unifocal lens, to which a linear distance gauge is attached. The focusing is done by human eye. The second is a modern 3D coordinate measurement machine, equipped with a CMOS colour camera as the sensor. Focusing is performed automatically by software. With both devices, distance measurements of various drop-deposited sources on glass and stainless steel disks have been performed. There is a good mutual agreement of results. Even though the new device can sample more reference points, the accuracy of the measurements has not improved drastically due to the imperfect flatness of the sources. The main advantages of the new system are its ease of use and the lower health risk involved due to the larger distance between the performer and the source.

Conversion electron spectroscopy of the 59.54 keV transition in 241Am alpha decay.

A windowless Peltier-cooled silicon drift detector (SDD) was used to measure internal conversion electron (ICE) spectra of thin 241Am sources. The ICE peaks associated with the 59.54 keV gamma transition in 237Np were deconvoluted and relative ICE intensities were derived from the fitted peak areas. Corrections were made for energy dependence of the full-energy-peak counting efficiency, based on Monte Carlo simulations. As expected for this anomalous E1 transition, a significant discrepancy was found with the theoretical internal conversion coefficient (ICC) values calculated from the BrIcc database. Penetration effects are known to cause such anomalies in highly retarded transitions. The measured ICE intensities are in good agreement with a specific combination of literature data obtained with magnetic spectrometers.

The 55Fe half-life measured with a pressurised proportional counter.

The half-life of 55Fe has been measured accurately by following the decay curve of three sources with a large pressurised proportional counter. An argon(90%)-methane(10%) mixture was used as counter gas, at atmospheric pressure (∼1 × 105 Pa) and at enhanced pressures of 5 × 105 Pa and 8 × 105 Pa (for 1 source), respectively. The first measurements were performed in 2001, but the experiment was executed more systematically between 2005 and 2018, covering a period of about 5 half-lives. The residuals from an exponential decay curve were of the order of 0.1% to 0.2% at 1 × 105 Pa, and 0.03% at 5 × 105 Pa and 8 × 105 Pa. The gain of stability with increased gas pressure was due to asymptotically reaching the maximum counting efficiency, resulting in lower sensitivity to pressure variations. The deduced half-life value of T1/2(55Fe) = 1006.70 (15) d or 2.7563 (4) a is more accurate than other data in literature, which are mutually discrepant. It is consistent with previous measurements at JRC with an X-ray defined solid angle counter.