Advances in the characterisation and identification of mastic (Pistacia sp.) resin in archaeological samples by GC-QToF-MS.

The optimisation and application of an analytical method based on gas chromatography coupled to quadrupole time-of-flight mass spectrometry (GC-QToF-MS) is proposed for the first time for the characterisation and identification of mastic (Pistacia sp.) resin in archaeological samples. The GC-QToF-MS method demonstrated higher sensitivity compared to single quadrupole GC-MS and enabled enhanced structural elucidation power to be exploited, particularly due to the high mass resolution and accuracy, the possibility to use standard and low ionisation energies as well as its tandem MS capabilities. The heat-induced degradation of the resin was also studied in open air conditions, showing that 28-norolean-17-en-3-one forms upon heating, but then progressively degrades. This makes it a reliable marker for heating of Pistacia resin; however, the lack of detection does not imply that the resin was not heated. These observations were used to interpret the results of a large number of archaeological samples containing Pistacia resin in different formulations, from various archaeological contexts and exposed to different environmental conditions. Lumps of relatively pure resin found in marine waterlogged conditions (Uluburun shipwreck, Turkey), residues on ceramics from Sai Island (Nubia, Sudan) as well as varnish and coating layers on Egyptian coffins from the collections of the British Museum (London, UK) and Fitzwilliam Museum (Cambridge, UK) were analysed to understand what the molecular profiles reveal about the use of the resin. The results showed that the resin was often mixed with a drying or semi-drying oil in ancient varnish formulations, thus suggesting that oil was used as a medium to dissolve the resin, which would have been impossible to apply as a layer using simple heat. These new observations significantly add to our understanding of ancient Egyptian technology and provide museum scientists and conservators with key information to accurately identify Pistacia resin and preserve objects containing it.

Tin from Uluburun shipwreck shows small-scale commodity exchange fueled continental tin supply across Late Bronze Age Eurasia.

This paper provides the first comprehensive sourcing analysis of the tin ingots carried by the well-known Late Bronze Age shipwreck found off the Turkish coast at Uluburun (ca. 1320 BCE). Using lead isotope, trace element, and tin isotope analyses, this study demonstrates that ores from Central Asia (Uzbekistan and Tajikistan) were used to produce one-third of the Uluburun tin ingots. The remaining two-thirds were derived from the Taurus Mountains of Turkey, namely, from stream tin and residual low-grade mineralization remaining after extensive exploitation in the Early Bronze Age. The results of our metallurgical analysis, along with archaeological and textual data, illustrate that a culturally diverse, multiregional, and multivector system underpinned Eurasian tin exchange during the Late Bronze Age. The demonstrable scale of this connectivity reveals a vast and disparate network that relied as much on the participation of small regional communities as on supposedly hegemonic institutions of large, centralized states.