Insight into the selection of oxidant in persulfate activation system: The effect of the target pollutant properties.

As a rising branch of advanced oxidation processes, persulfate activation has attracted growing attention. Unlike catalysts that have been widely studied, the selection of persulfate is previously overlooked. In this study, the affecting factors of persulfates were studied. The effect of target pollutant properties on superior persulfate species (the species with a higher degradation efficiency) was investigated by multiwalled carbon nanotube (MWCNT)/persulfate catalytic systems. Innovatively, the EHOMO (or vertical ionization potential (VIP)) value of the target pollutant was proposed to be an index to judge the superior persulfate species, and the threshold is VIP= 6.397-6.674 eV, EHOMO= -8.035∼- 7.810 eV, respectively. To be specific, when the VIP of phenolic compounds is higher (or EHOMO of phenolic compounds is lower) than the threshold, the catalytic performance of peroxymonosulfate would be higher than that of peroxydisulfate. Moreover, the effects of coexisting cations on peroxydisulfate superior species were further investigated. It was illustrated that the hydrated cation radius of coexisting cations would influence the pollutant degradation efficiency under some circumstances. This study provides a new approach to improve the cost of persulfate activation systems and promotes the underlying downstream application of persulfate activation systems.

Biochar-compost as a new option for soil improvement: Application in various problem soils.

Due to the synergistic effects of biochar and compost/composting, the combined application of biochar and compost (biochar-compost) has been recognized as a highly promising and efficient method of soil improvement. However, the willingness to apply biochar-compost for soil improvement is still low compared to the use of biochar or compost alone. This paper collects data on the application of biochar-compost in several problem soils that are well-known and extensively investigated by agronomists and scientists, and summarizes the effects of biochar-compost application in common problem soils. These typical problem soils are classified based on three different characteristics: climatic zones, abiotic stresses, and contaminants. The improvement effect of biochar-compost in different soils is assessed and directions for further research and suggestions for application are made. Generally, biochar-compost mitigates the high mineralization rate of soil organic matter, phosphorus deficiency and aluminum toxicity, and significantly improves crop yields in most tropical soils. Biochar-compost can help to achieve long-term sustainable management of temperate agricultural soils by sequestering carbon and improving soil physicochemical properties. Biochar-compost has shown positive performance in the remediation of both dry and saline soils by reducing the threat of soil water scarcity or high salinity and improving the consequent deterioration of soil conditions. By combining different mechanisms of biochar and compost to immobilize or remove contaminants, biochar-compost tends to perform better than biochar or compost alone in soils contaminated with heavy metals (HMs) or organic pollutants (OPs). This review aims to improve the practicality and acceptability of biochar-compost and to promote its application in soil. Additionally, the prospects, challenges and future directions for the application of biochar-compost in problem soil improvement were foreseen.

Constructing functional metal-organic frameworks by ligand design for environmental applications.

Metal-organic frameworks (MOFs) with unique physical and chemical properties are composed of metal ions/clusters and organic ligands, including high porosity, large specific surface area, tunable structure and functionality, which have been widely used in chemical sensing, environmental remediation, and other fields. Organic ligands have a significant impact on the performance of MOFs. Selecting appropriate types, quantities and properties of ligands can well improve the overall performance of MOFs, which is one of the critical issues in the synthesis of MOFs. This article provides a comprehensive review of ligand design strategies for functional MOFs from the number of different types of organic ligands. Single-, dual- and multi-ligand design strategies are systematically presented. The latest advances of these functional MOFs in environmental applications, including pollutant sensing, pollutant separation, and pollutant degradation are further expounded. Furthermore, an outlook section of providing some insights on the future research problems and prospects of functional MOFs is highlighted with the purpose of conquering current restrictions by exploring more innovative approaches.

Unveiling the roles of dissolved organic matters derived from different biochar in biochar/persulfate system: Mechanism and toxicity.

Biochar has been frequently used as a persulfate (PS) activator due to its attractive properties, but dissolved organic matter (DOM) derived from the non­carbonized part of biochar has received less attention, not to mention its specific role and impact in biochar/PS systems. In this study, wheat straw, municipal sludge, and swine bone were selected as the representative feed stocks of biochar. Subsequently, these three types of biochar were adopted to explore the roles of DOM in biochar/PS systems. Although the composition and amount of DOM derived from different biochar were discrepant, they exhibited similar effect in biochar/PS systems. To be specific, the pore-clogging effect of DOM on biochar suppressed the adsorption capacity and catalytic performance of the three biochar. Furthermore, the removal of DOM decreased the environmental risk of these biochar/PS systems and enhanced the stability of the involved biochar. With respect to the variation in degradation mechanism, the removal of DOM increased the proportion of electron transfer pathway in unison, but the diminution in the roles of O2•¯ and 1O2 was more remarkable in bone-derived-biochar/PS systems. Additionally, the toxicity test illustrated that the leakage and accumulation of DOM were toxic to Chlorella sp., and the DOM from sludge-derived-biochar presented the highest toxicity. Overall, this study analyzes the roles of DOM derived from different biochar in biochar/PS systems and evaluates their environmental risk, which contributes to a comprehensive understanding of the fate of DOM derived from biochar.