Two-Stage Micropyramids Enhanced Flexible Piezoresistive Sensor for Health Monitoring and Human-Computer Interaction.

High-performance flexible piezoresistive sensors are becoming increasingly essential in various novel applications such as health monitoring, soft robotics, and human-computer interaction. The evolution of the interfacial contact morphology determines the sensing properties of piezoresistive devices. The introduction of microstructures enriches the interfacial contact morphology and effectively boosts the sensitivity; however, the limited compressibility of conventional microstructures leads to rapid saturation of the sensitivity in the low-pressure range, which hinders their application. Herein, we present a flexible piezoresistive sensor featuring a two-stage micropyramid array structure, which effectively enhances the sensitivity while widening the sensing range. Owing to the synergistic enhancement effect resulting from the sequential contact of micropyramids of various heights, the devices demonstrate remarkable performance, including boosting sensitivity (30.8 kPa-1) over a wide sensing range (up to 200 kPa), a fast response/recovery time (75/50 ms), and an ultralong durability of 15,000 loading-unloading cycles. As a proof of concept, the sensor is applied to detect human physiological and motion signals, further demonstrating a real-time spatial pressure distribution sensing system and a game control system, showing great potential for applications in health monitoring and human-computer interaction.

Wrinkle Clamp Down on Structure Crack Strain Sensor Based on High Poisson's Ratio Material for Home Health Monitoring and Human-Machine Interaction.

Flexible wearable crack strain sensors are currently receiving significant attention because they can be used in a wide range of physiological signal monitoring and human-machine interaction applications. However, sensors with high sensitivity, great repeatability, and wide sensing range remain challenging. Herein, a tunable wrinkle clamp down structure (WCDS) crack strain sensor based on high Poisson's ratio material with high sensitivity, high stability, and wide strain range is proposed. Based on the high Poisson's ratio of the acrylic acid film, the WCDS was prepared by a prestretching process. The wrinkle structures can clamp down the crack to improve the cyclic stability of the crack strain sensor while maintaining its high sensitivity. Moreover, the tensile properties of the crack strain sensor are improved by introducing wrinkles in the bridge-like gold stripes connecting each separated gold flake. Owing to this structure, the sensitivity of the sensor can reach 3627, stable operation over 10 000 cycles is achieved, and the strain range can reach about 9%. In addition, the sensor exhibits low dynamic response and good frequency characteristics. Because of its demonstrated excellent performance, the strain sensor can be used in pulse wave and heart rate monitoring, as well as posture recognition and game control.

Miniaturized Flexible Non-Contact Interface Based on Heat Shrinkage Technology.

High-performance miniaturized flexible sensors are becoming increasingly important in wearable electronics. However, miniaturization of devices often requires high-precision manufacturing processes and equipment, which limits the commercialization of flexible sensors. Therefore, revolutionary technologies for manufacturing miniaturized flexible sensors are highly desired. In this work, a new method for manufacturing miniaturized flexible humidity sensor by utilizing heat shrinkage technology is presented. This method successfully achieves much smaller sensor and denser interdigital electrode. Utilizing this method, a miniaturized flexible humidity sensor and array are presented, fabricated by anchoring nano-Al2 O3 into carbon nano-tube as the humidity sensitive film. This heat shrinkage technology, forming wrinkle structure on the humidity sensitive film, endows the sensor with a high sensitivity over 200% (ΔR/R0 ) at humidity levels ranging from 0 to 90%RH and a fast recovery time (0.5 s). The sensor allows non-contact monitoring human respiration and alerting in case of an asthma attack and the sensor array can be adaptively attached to the wrist as a non-contact human-machine interface to control the mechanical hand or computer. This work provides a general and effective heat shrinkage technology for the development of smaller and more efficient flexible circuits and sensor devices.

A highly adaptive real-time water wave sensing array for marine applications.

The ocean accounts for about 70% of the Earth's surface area. In recent years, there has been increasing research into large-scale power generation device networks for ocean energy and the number of mobile sensing nodes in the ocean is expected to increase with the operation of the Internet of Things (IoT). Since water waves are low-frequency intermittent energy, they are suitable for harvesting and sensing by a triboelectric nanogenerator (TENG) with high conversion efficiency, flexible structural design, and environmental friendliness. Furthermore, TENG-units are suitable for large-scale water waves. We proposed a 6 × 4 cross-vertical double-layer electrode array device to sense and restore the water wave state. The design of this structure can refine the waveform display while reducing the electrode interfaces and achieving efficient and accurate sensing of the water wave. Then we developed a complete display system combined with the device and demonstrated the superior performance of each unit and the whole array both on a curved surface and underwater. It can be expected that the device and the system will have great potential in maritime applications.

Flexible Triboelectric Tactile Sensor Based on a Robust MXene/Leather Film for Human-Machine Interaction.

With the rapid development of Internet of Things (IoT) technology in recent years, self-actuated sensor systems without an external power supply such as flexible triboelectric nanogenerator (TENG)-based strain sensors have received wide attention due to their simple structure and self-powered active sensing properties. However, to satisfy the practical applications of human wearable biointegration, flexible TENGs impose higher requirements for establishing a balance between material flexibility and good electrical properties. In this work, the strength of the MXene/substrate interface was greatly improved by utilizing leather with a unique surface structure as the substrate material, resulting in a mechanically strong and electrically conductive MXene film. Due to the natural fiber structure of the leather surface, the surface of the MXene film with a rough structure was obtained, which improved the electrical output performance of the TENG. The electrode output voltage of MXene film on leather based on single-electrode TENG can reach 199.56 V and the maximum output power density can reach 0.469 mW/cm2. Combined with laser-assisted technology, the efficient array preparation of MXene and graphene was achieved and applied to various human-machine interface (HMI) applications.

Flexible alternating current electroluminescent devices integrated with high voltage triboelectric nanogenerators.

Flexible alternating current electroluminescent (ACEL) devices have attracted growing interest as promising wearable displays for their uniformity of light emission, low power consumption, and excellent reliability. However, the requirement of high-voltage power sources for driving ACEL devices greatly impedes their portability and commercialization. Here, we developed flexible ACEL devices integrated with high output-voltage triboelectric nanogenerators (TENG) using easy and low-cost crumpled Al electrodes. The output voltage and current could reach as high as 490 V and 71.74 µA, corresponding to the maximum instantaneous output power density of 1.503 mW cm-2, which was demonstrated to power an integrated flexible ACEL patterned display. In addition, through signal acquisition and transmission, ACEL can display the compression frequency of TENG in real time. Such self-powered ACEL devices are very promising as flexible displays in wearable electronics.