Recent trends and future perspectives of thermoelectric materials and their applications.

This review explores the ever-evolving landscape of thermoelectric materials, focusing on the latest trends and innovations in ceramics, thermally conductive gel-like materials, metals, nanoparticles, polymers, and silicon. Thermoelectric materials have garnered significant attention for their capability to convert waste heat into electrical power, positioning them as promising candidates for energy harvesting and cooling applications. This review distinguishes itself by highlighting recent advancements in synthesis methods, advanced doping strategies, and nanostructuring techniques that have markedly enhanced material performance. It provides a comprehensive analysis of the controlled properties concerning their synthesis parameters, such as electrical conductivity, Seebeck coefficient, and thermal conductivity. Furthermore, this work delves into the emerging applications of thermoelectric devices across diverse fields, including automotive, aerospace, wearable electronics, and industrial waste heat recovery. By offering forward-looking insights, this review outlines thermoelectric devices' challenges and future prospects, underscoring their potential to contribute to sustainable energy solutions and efficient thermal management systems. By integrating current trends with future projections, this review offers a timely and comprehensive roadmap for researchers and engineers dedicated to advancing next-generation thermoelectric technologies.

Recent developments in sunscreens based on chromophore compounds and nanoparticles.

Sunscreen formulations have undergone significant advancements in recent years, with a focus on improving UV radiation protection, photostability, and environmental sustainability. Chromophore compounds and nanoparticles have emerged as key components in these developments. This review highlights the latest research and innovations in chromophore compounds and nanoparticle-based sunscreens. It discusses the role of nanoparticles, such as zinc oxide and titanium dioxide, in scattering and absorbing UV radiation while remaining cosmetically acceptable. Chromophore compounds, encapsulated in nanoparticles, are explored for their potential to enhance UV protection by absorbing specific wavelengths of light. Additionally, advances in photo-stability, broad-spectrum protection, antioxidant inclusion, and biodegradability are discussed. The evolving landscape of sunscreen technology aims to provide more effective and environment-friendly solutions for safeguarding skin from the sun's harmful effects.

Retraction: Gel scaffolds and emerging applications in biomedicine.

[This retracts the article DOI: 10.1039/D2RA00924B.].

Review of photoresponsive and glycoside dendrimers in biomaterials and sensors applications.

Dendrimers are branched molecules with well-defined lengths, shapes, molecular weights, and monodispersity in comparison to linear polymers. The dual effect of the chromophore luminescence and the morphology of the synthesized dendrimers has drawn a lot of interest towards the design of dendrimers with different chromophores. Furthermore, the stimulus-responsive systems can sequester drug molecules under a preset set of parameters and release them in a different environment in response to either an exogenous or endogenous stimulus. The addition of photoresponsive moieties to different dendrimer components, such as the core or branches, magnifies the importance of the dendrimer in several related sectors of nanotechnology, such as sensors, photoswitches, electronic gadgets, and drug delivery systems. This review article focused on photoresponsive/glycoside dendrimer structures and their biomaterial applications.

Gel scaffolds and emerging applications in biomedicine.

Nowadays, gels are formed by small molecules self-assembling under the influence of various non-covalent interactions. They can be easily perturbed, which allows for the careful tweaking of their properties. They are kinetically confined, and following production, they usually do not demonstrate time-variable changes in material properties. When exposed to external stimuli such as temperature, pH, light, enzymes, redox, and chemical analytes, such materials may become switchable, leading to the reconfiguration of the gel matrix into a different type of network. The transformations allow gel-to-gel transitions, while the changes in the molecular aggregation result in the alteration of the physical and chemical properties of the gel with time. Here, we discuss various methods used to achieve gel-to-gel transitions by modifying a pre-formed gel material through external perturbation. The dynamic modification of gels allows the construction of an array of gels with various properties from a single material, which eventually extends the limit of application of the gels.

Synthesis and characterization of hesperetin derivatives and toxicity level of the zebrafish model.

Hesperetin derivatives were synthesized through the esterification of acid chlorides with hesperetin under ambient reaction conditions with good yields. The product was confirmed using different spectral techniques. It was treated on zebrafish embryos to study the lethality, phenotypic deformities, and toxicity level of the compound. In that assessment, embryos showed lethality towards 3e at the minimal concentration. It assesses slow heartbeat since the compound loaded, the curvature on the back, upcurved fish, Cardiac chamber bulging, and poor survival rate in 72 h. 3a shows less toxicity more than other compounds. It shows only pericardial edema at higher concentration and 3c induced pericardial edema and upcurved tail at a medium range of the concentration. But both compounds were shown a good survival ratio at the minimal concentration.

Self-assembly of sugar based glyco-lipids: Gelation studies of partially protected d-glucose derivatives.

A series of sugar-based glycolipid derivatives were prepared by N-glycosylamines, and their organogelation property has been analyzed. We have observed the efficient gelation for some of the anilines substituted glycolipids derivatives in different aromatic and aliphatic solvents. It was found that the gelation occurred predominantly in aliphatic solvents with CGC of 0.8% (w/v) attributed to the presence of long alkyl chain in the glycolipids. The structural and morphological properties of the xerogels were investigated by NMR, powder XRD, and FE-SEM respectively. Furthermore, the thermal stability was analyzed by DSC.

In vivo safety evaluation of antibacterial silver chloride nanoparticles from Streptomyces exfoliatus ICN25 in zebrafish embryos.

Silver chloride nanoparticles were synthesized from the cell-free culture supernatant of Streptomyces strain using green synthesis approach with good yield. The nanoparticles were characterized by UV-Vis, IR, SEM, AFM and XRD techniques. These nanoparticles exhibited broad spectrum of antibacterial activity towards Methicillin-resistant Staphylococcus aureus, Methicillin sensitive S. aureus, Escherichia coli, Pseudomonas aeruginosa and Klebsiella pneumonia at ≤ 2 µg/ml minimal inhibitory concentrations. In vivo bioassay in nanoparticles treated zebrafish embryos exhibited 16 µg/ml dose as maximal cardiac safety concentration and further increases in concentration revealed adverse effects such as pericardial bulging, mouth protrudation, hemorrhage and yolk sac elongation. The less toxicity of nanoparticles treated embryos in terms of cardiac assessment and lethality analysis was observed. The dose below 5 µg/ml is concluded as an in vitro and in vivo therapeutic dose. The properties of this biosynthesized nanoparticle suggest a path towards developing antibiotic nanoparticles that are likely to avoid development of multidrug resistance.

Synthesis and antioxidant activity of a novel class of fluorescein-based ß-C-glycosides.

A series of fluorescein-based ß-C-glycosyl ketones were synthesized through aldol condensation of ß-C-glycosyl ketones with fluorescein monoaldehyde under ambient reaction conditions in good yields. Formation of the expected product has been confirmed through different spectral techniques. Fluorescein-based ß-C-glycosides show moderate anti-oxidant activities with maximum inhibitory activity of 60%.

Studies on the synthesis and the antimicrobial and antioxidant activities of a novel class of fluorescein-based glycosides.

Facile glycosylation of a fluorescein diol derivative with per-O-acetyl/benzoyl sugar derivatives using BF(3)·Et(2)O catalyst resulted in the formation of the expected glycosides in 54-66% yield. The biological screening of the glycosides against different microbes shows good inhibitory activity. The antioxidant activity of the fluorescein-based glycosides shows remarkable inhibition (IC(50) ∼80%).

Design, synthesis, and biological evaluation of a novel class of fluorescein-based N-glycosylamines.

A series of fluorescein-based N-glycosylamines was synthesized from the corresponding fluorescein amine and a partially protected d-glucose. The physiochemical investigation of these compounds by spectral and morphological studies reveals their gelation potential. The exclusive localization of fluorescence in the cytoplasm through cell imaging studies reveals the anti-cancer potentials of N-glycosylamines.