The recent inference of sulfur dioxide (SO2) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations1-3 suggests that photochemistry is a key process in high-temperature exoplanet atmospheres4. This is because of the low (<1 ppb) abundance of SO2 under thermochemical equilibrium compared with that produced from the photochemistry of H2O and H2S (1-10 ppm)4-9. However, the SO2 inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 µm and, therefore, the detection of other SO2 absorption bands at different wavelengths is needed to better constrain the SO2 abundance. Here we report the detection of SO2 spectral features at 7.7 and 8.5 µm in the 5-12-µm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)10. Our observations suggest an abundance of SO2 of 0.5-25 ppm (1σ range), consistent with previous findings4. As well as SO2, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 µm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1-8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.
Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability1. However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program2,3 found a spectral absorption feature at 4.05 µm arising from sulfur dioxide (SO2) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 MJ) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref. 4). The most plausible way of generating SO2 in such an atmosphere is through photochemical processes5,6. Here we show that the SO2 distribution computed by a suite of photochemical models robustly explains the 4.05-µm spectral feature identified by JWST transmission observations7 with NIRSpec PRISM (2.7σ)8 and G395H (4.5σ)9. SO2 is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H2S) is destroyed. The sensitivity of the SO2 feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO2 also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations.
This paper reviews past research and new studies underway of the local interstellar environment and its changing influence on the heliosphere. The size, shape, and physical properties of the heliosphere outside of the heliopause are determined by the surrounding environment - now the outer region of the Local Interstellar Cloud (LIC). The temperature, turbulence, and velocity vector of neutral atoms and ions in the LIC and other partially ionized interstellar clouds are measured from high-resolution spectra of interstellar absorption lines observed with the STIS instrument on the HST. Analysis of such spectra led to a kinematic model with many interstellar clouds defined by velocity vectors derived from radial velocity measurements. This analysis identified fifteen clouds located within about 10 pc of the Sun and their mean temperatures, turbulence, and velocity vectors. With the increasing number of sight lines now being analyzed, we find that temperatures and turbulent velocities have spatial variations within the LIC and other nearby clouds much larger than measurement uncertainties, and that these spatial variations appear to be randomly distributed and can be fit by Gaussians. The inhomogeneous length scale is less than 4,000 AU, a distance that the heliosphere will traverse in less than 600 years. The temperatures and turbulent velocities do not show significant trends with stellar distance or angle from the LIC center. If/when the Sun enters an inter-cloud medium, the physical properties of the future heliosphere will be very different from the present. For the heliosheath and the very local interstellar medium (VLISM) just outside of the heliopause, the total pressures are approximately equal to the gravitational pressure of overlying material in the Galaxy. The internal pressure in the LIC is far below that in the VLISM, but there is an uncertain ram pressure term produced by the flow of the LIC with respect to its environment. Supplementary Information: The online version contains supplementary material available at 10.1007/s11214-022-00884-5.
