Mitigation of Silicon Contamination in Fuel Cell Gasket Materials through Silica Surface Treatment.

Gaskets and seals are essential components in the operation of proton exchange membrane (PEM) fuel cells and are required for keeping hydrogen and air/oxygen within their individual compartments. The durability of these gaskets and seals is necessary, as it influences not only the lifespan but also the electrochemical efficiency of the PEM fuel cell. In this study, the cause of silicon leaching from silicone gaskets under simulated fuel cell conditions was investigated. Additionally, to reduce silicon leaching, the silica surface was treated with methyltrimethoxysilane, vinyltriethoxysilane, and (3,3,3-trifluoropropyl)trimethoxysilane. Changes in the silica surface chemistry were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis, elemental analysis, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. Inductively coupled plasma-optical emission spectroscopy analysis revealed that surface-treated silica was highly effective in reducing silicon leaching.

Mechanochemically functionalized and fibrillated microcrystalline cellulose as a filler in silicone foam: An integrated experimental and simulation investigation.

Fibrillated celluloses have gained significant attention due to their exceptional mechanical properties and eco-friendly characteristics, which make them suitable for various applications. In this study, we designed a precise approach for producing highly fibrillated microcrystalline cellulose (MCC) via ball-milling treatment using four typical silane coupling agents. The empirical data demonstrate that the fibrillization of MCC and the properties of fibrillated MCC are largely affected by the size and geometry of the functional groups of the silanes. After ball-milling, most MCC displayed enhanced e-beam tolerance and thermal stability, whereas the silane loading amount, surface area, and morphology of fibrillated MCC appeared to be random, which was exemplified by the proportional and non-proportional relationship between the loading amount and surface area of methyl silane- and phenyl silane-treated MCC, respectively. Density functional theory calculations and molecular dynamics simulations were employed to obtain the intricate details. The simulation results were in agreement with the experimental results. Finally, fibrillated MCC was incorporated into silicone foams as an additive. The thermal stability of fibrillated MCC with added silicone was greatly improved, and the tensile strength of fibrillated MCC-containing silicone foam was 44.1 and 5.4 times higher than that of the neat and MCC-containing silicone foams, respectively.