High efficiency diode-pumped Pr:LiLuF4 visible lasers in femtosecond-laser-written waveguides.

In this work we investigate the power scaling of diode-pumped Pr:LiLuF4 waveguide lasers produced by direct femtosecond writing. The waveguides studied consisted in depressed cladding waveguides with different geometries. We observed laser emission at 604 nm, achieving a maximum output power of 275 mW and a slope efficiency of 40%, and 721 nm, demonstrating 310 mW of output power and a slope efficiency of 50%. Moreover, we obtained, what we believe is for the first time in a diode-pumped waveguide, laser emission at 523 nm, with a maximum output power of 65 mW and a slope efficiency of 11%. In the end, we also demonstrated the first diode-pumped operation of a single-transverse-mode waveguide laser at 721 nm, reaching a maximum output power of 28 mW and maintaining a high quality beam with an M2 of 1.1.

Luminescence properties of CdF2 single crystals co-doped with Er3+ and Y3+ ions.

The luminescence properties of erbium and yttrium co-doped cadmium difluoride with three different concentrations of yttrium were investigated. First, we synthesized single crystal samples with good optical quality using the Bridgman technique. From the optical absorption spectra, recorded at room temperature, both in the ultraviolet-visible and infrared spectral ranges, Judd-Ofelt analysis was performed based on yttrium concentrations to predict the radiative properties of Er3+ luminescent ions. For the 10% optimum concentration of yttrium, a detailed photoluminescence investigation was carried out. We mainly explored green, red, and near-infrared fluorescence under different excitation wavelengths and presented their highlight spectroscopic characteristics. The desired transitions had relatively high emission cross-sections both under visible and near-infrared excitation. Optical gain followed a similar trend. Furthermore, the dynamic fluorescence study showed a significant increase in the measured lifetime under an 800 nm infrared excitation. The upconversion process under an 800 nm excitation produced quantum efficiency greater than 100% due to the contribution of more than one energy transfer mechanism.

Er3+:YLiF4 channeled waveguide laser near 2.7-2.8†µm fabricated by femtosecond laser inscription.

We report, for the first time to our knowledge, a demonstration of robust waveguide lasing near 2.7-2.8 µm in an erbium-doped fluoride host. Femtosecond laser inscription was employed to fabricate 50- and 70-µm diameter channeled waveguides inside an Er3+:YLiF4 crystal. The best power performance was obtained with the 70-µm diameter waveguide and 16% transmitting output coupler. The propagation loss and refractive index contrast were measured as 0.23 dB/cm and 7.1 × 10-4, respectively, for the 70-µm diameter waveguide. Both self-Q-switched (SQS) and continuous-wave (CW) operations could be obtained. During the SQS operation, as short as 240-ns pulses with average power of 51 mW, repetition rate of 368 kHz, and power slope efficiency of 15.2% were generated at the wavelength of 2717 nm with 465 mW of the pump power. During the CW operation, as high as 66 mW of output power was achieved at 2808 nm by using 460 mW of pump power at 798 nm, with a power slope efficiency of 19.6%.

Diode-pumped visible lasing in femtosecond-laser-written Pr:LiLuF4 waveguide.

In this Letter we report the realization of a femtosecond-laser-written diode-pumped Pr:LiLuF4 visible waveguide laser. The waveguide studied in this work consisted of a depressed-index cladding, whose design and fabrication were optimized to minimize the propagation loss. Laser emission has been achieved at 604 nm and 721 nm, with output power of 86 mW and 60 mW, respectively, and slope efficiencies of 16% and 14%. In addition, we obtained, for the first time in a praseodymium-based waveguide laser, stable continuous-wave laser operation at 698 nm (3 mW of output power and 0.46% of slope efficiency), corresponding to the wavelength necessary for the clock transition of the strontium-based atomic clock. The waveguide laser emission at this wavelength is mainly in the fundamental mode (i.e., the larger propagation constant mode) showing a nearly Gaussian intensity profile.

Operation of a fiber-coupled laser-cooler down to cryogenic temperatures.

We report on the optical cooling of a 7.5%Yb:LiYF4 crystal down to 125 K in a multi-pass Herriott absorption cell, coupled via a single mode polarization maintaining optical fiber to the laser source. This configuration, never exploited before, is more practical for potential applications, in particular for spaceborne cryogenics setups. Moreover, the temperature reached is exactly the one needed in many setup embarked in small and medium satellites. We evaluate the heat load on the crystal at the minimum attainable temperature, which is comparable to state of the art systems.

Operation of a fiber-coupled laser-cooler down to cryogenic temperatures: publisher's note.

This publisher's note contains a correction to [Opt. Express30, 12929 (2022)10.1364/OE.448930].

Deep Red Tunability and Output Power Performances of Visible Laser Emission in a Pr:Ba(Y1-xLux)2F8 Single Crystal.

The demand for tunable visible laser sources with high power and high beam quality, for application ranging from metrology to remote sensing, is constantly increasing. In this work, we report on the details of crystal growth, via the Czochralski method, and laser characterization of a Pr-doped Ba(Y1-xLux)2F8 (BYLF) single crystal, which is a promising candidate for fulfilling these requirements, both in terms of tunability and high-power capabilities. We measured for the first time the laser tunability curve in the deep red region obtaining a continuous range of 17 nm. The laser emission of the three main Pr3+ lines in the visible (orange, red, and deep red) was tested under increased pump power with respect to previous studies on this material, demonstrating output powers of more than 360 mW and no thermal rolloff, up to 1.9 W of absorbed power.

Tunable continuous-wave laser operation of Tm3+:BaY2F8 near 2.3 µm.

We report, for the first time to our knowledge, tunable continuous-wave laser action in the Tm3+:BaY2F8 (BYF) crystal near 2.3 µm. In the experiments, a BYF crystal doped with 3 at. % thulium was end pumped with a narrow-linewidth, tunable Ti3+:sapphire laser with up to 920 mW of incident power. Lasing was achieved for the two pump polarizations of E//x and E//y. The best power performance was obtained in the case of E//x, double-end pumping, where 100 mW of output power was obtained at 2290 nm with 920 mW of pump power and 1% output coupler. The laser could be continuously tuned from 2233 to 2385 nm. Excitation spectra for E//x and E//y pumping were measured in the 760-810 nm range, and the optimum pumping wavelength was determined to be 779 nm for E//x. By using the lifetime and lasing threshold data, the stimulated emission cross section at 2290 nm was further determined to be (0.66±0.06)×10-24m2.

First demonstration of optical refrigeration efficiency greater than 4% at room temperature.

In this work, we present the cooling efficiency of a LiYF4 (lithium yttrium fluoride,YLF) sample co-doped with 10at.% ytterbium (Yb3+) and 0.0040at.% thulium (Tm3+). For the first time at room temperature, the cooling efficiency of a sample overcomes the 4%-barrier, and it must be compared with the best values reported in literature, about 3%, obtained with a YLF:10at.%Yb sample. We also investigated the frequency behaviour of energy transfer mechanisms between Yb and Tm ions in order to have a better understanding of the contribution of phonons to the cooling cycle. These mechanisms can explain the cooling efficiency enhancement in the co-doped system.

Upconversion pumping of a 2.3 µm Tm3+:KY3F10 laser with a 1064 nm ytterbium fiber laser.

We report efficient lasing of the isotropic ${{\rm Tm}^{3 + }}\!:\!{{\rm KY}_3}{{\rm F}_{10}}$Tm3+:KY3F10 crystal near 2.3 µm via upconversion pumping with a 1064 nm ytterbium fiber laser as the pump source. When pumped at 1064 nm, an x-cavity ${{\rm Tm}^{3 + }}\!:\!{{\rm KY}_3}{{\rm F}_{10}}$Tm3+:KY3F10 laser operated at the free-running wavelength of 2344 nm. Lasing was obtained with output couplers having transmissions in the range of 1-3%, and as high as 124 mW of continuous-wave (cw) output power was generated with 604 mW of absorbed pump power by using the 3% output coupler. Broadly tunable cw lasing could be obtained in the 2268-2373 nm wavelength range. An analysis of the experimental power efficiency data shows that nearly all of the absorbed pump photons were converted to 2.3 µm laser output after accounting for the quantum defect of the laser transition and resonator losses. We expect that higher lasing efficiency should be possible by using longer crystals to increase the pump absorption.

Graphene mode-locked operation of Tm3+:YLiF4 and Tm3+:KY3F10 lasers near 2.3 µm.

We report experimental demonstration of graphene mode-locked operation of ${{\rm Tm}^{3 + }}\!:\!{{\rm YLiF}_4}$Tm3+:YLiF4 (YLF) and ${{\rm Tm}^{3 + }}\!:\!{{\rm KY}_3}{{\rm F}_{10}}$Tm3+:KY3F10 (KYF) lasers near 2.3 µm. To scale up the intracavity pulse energy, the cavity was extended, and double-end pumping was employed with a continuous-wave, tunable ${{\rm Ti}^{3 + }}\!:\!{\rm sapphire}$Ti3+:sapphire laser delivering up to 1 W near 780 nm. The extended ${{\rm Tm}^{3 + }}\!:\!{\rm KYF}$Tm3+:KYF laser cavity was purged with dry nitrogen to eliminate pulsing instabilities due to atmospheric absorption lines, but this was not needed in the case of the ${{\rm Tm}^{3 + }}\!:\!{\rm YLF}$Tm3+:YLF laser. Once initiated by graphene, stable uninterrupted mode-locked operation could be maintained with both lasers. With the extended cavity ${{\rm Tm}^{3 + }}\!:\!{\rm YLF}$Tm3+:YLF laser, 921 fs pulses were generated at a repetition rate of 17.2 MHz at 2304 nm. 739 fs pulses were obtained at the repetition rate of 54 MHz from the ${{\rm Tm}^{3 + }}\!:\!{\rm KYF}$Tm3+:KYF laser at 2340 nm. The corresponding pulse energy and peak power were 2.4 nJ and 2.6 kW for the ${{\rm Tm}^{3 + }}\!:\!{\rm YLF}$Tm3+:YLF laser, and 1.2 nJ and 1.6 kW for the ${{\rm Tm}^{3 + }}\!:\!{\rm KYF}$Tm3+:KYF laser. We foresee that it should be possible to generate shorter pulses at higher pump levels.

Super-quadratic upconversion luminescence among lanthanide ions.

We explore the arguably most fundamental aspect of energy-transfer upconversion (ETU), namely the dependence of upconversion luminescence from a higher-energy level, following ETU excitation from a metastable lower-energy level, on direct luminescence from that metastable level. We investigate ETU among neighboring Nd3+ ions in single crystals of GdVO4 and LaSc3(BO3)4 with different doping concentrations by measuring, after short-pulse laser excitation with different pump energies, the infrared luminescence decay from the metastable 4F3/2 level and the yellow upconversion luminescence decay from the 4G7/2 level. We observe a highly super-quadratic dependence of upconversion on direct luminescence intensity. We conclude that the commonly assumed quadratic law of ETU, as proposed by Grant's model and frequently employed in rate-equation simulations, is inadequate to the description of ETU processes. Whereas Zubenko's model, which considers a finite migration rate, provides significantly better fits to the experimental luminescence-decay curves, also this model cannot accurately reproduce the measured decay curves, partly because it does not take the non-homogeneous distribution of active ions into account.

Optical refrigeration: the role of parasitic absorption at cryogenic temperatures.

Optical cooling of a YLF:Yb single crystal to 87 K, well below the minimum achievable temperature predicted from existing theory, has been observed. This discrepancy between theory and data has motivated us to revisit the current model of optical refrigeration, in particular the critical role of parasitic background absorption. Challenging experiments that measured the cooling efficiency as a function of temperature reveal that the background absorption coefficient decreases with temperature, resulting in a significant enhancement of the cooling efficiency at cryogenic temperatures. These discoveries emphasize the high sensitivity of optical cooling to impurity-mediated processes and show the necessity of formulating a cooling model that includes the temperature dependence of the background absorption. To properly characterize the cooling properties of any sample, it is necessary to measure its low-temperature performance.

Multi-watt amplification in a birefringent Yb:LiLuF4 single crystal fiber grown by micro-pulling-down.

We present, to the best of our knowledge, the first demonstration of a single crystal fiber solid-state amplifier based on a birefringent Yb3+-doped thin crystal grown by the micro-pulling-down method. We measured a small signal gain >30 in a four-passes Yb:LiLuF4 amplifier pumping with a 120-W maximum power fiber-coupled laser diode. At an absorbed pump power of 80 W, a maximum output power of 8.4 W was obtained seeding the 42-mm-long, 2%Yb3+-doped single crystal fiber sample with 0.8 W at 1021 nm. Even at the maximum incident pump power, the amplified laser beam polarization and spatial quality were excellent (M2=1.15×1.06).

Kerr-lens mode-locked Pr3+:LuLiF4 laser.

We demonstrate the Kerr-lens mode-locked Pr3+:LuLiF4 (Pr:LLF) laser pumped by a blue laser diode (LD). By theoretical calculation of the group velocity dispersion in the laser gain, the compensation was employed for the realization of the continuous-wave mode-locked laser at the wavelength of 604 nm with the pulse width of 1.1 ps which, to the best of our knowledge, is the shortest pulse width in the Pr3+ ion doped crystal lasers pumped with LDs. It can be believed that the present Pr:LLF laser should provide some inspiration for the development of the blue LD pumped visible lasers, especially in the mode-locking laser operation.

Continuous-wave mid-infrared laser operation of Tm3+:KY3F10 at 2.3 µm.

We report continuous-wave lasing demonstration of a Tm3+:KY3F10 crystalline gain medium at 2343 nm. A narrow-linewidth, tunable, continuous-wave Ti3+:sapphire laser was used to end pump a Tm3+:KY3F10 crystal with thulium doping of 8 at. %. With 1 W of pump power, the resonator with a 1% output coupler generated output powers of 31 and 122 mW in single-pumping and double-pumping configurations, respectively. Excitation efficiency of the laser was investigated for pump wavelengths in the 765-806 nm range. Four pump bands were identified in this wavelength range, with the two most efficient pump bands centered at 773 and 778 nm. The output of the laser could be tuned smoothly and continuously over a spectral width of 125 nm from 2260 to 2385 nm. The lifetime of the H43 level was further measured to be 16 µs, and the emission cross section was determined based on lasing threshold measurements.

Tm-doped crystals for mid-IR optical cryocoolers and radiation balanced lasers.

We report the complete characterization of various cooling-grade Tm-doped crystals including, to the best of our knowledge, the first demonstration of optical refrigeration in Tm:YLF crystals. Room temperature laser cooling efficiencies of 1% and 2% (mol) Tm:YLF and 1% Tm:BYF crystals at different excitation polarizations are measured, and their external quantum efficiency and background absorption are extracted. By performing detailed low-temperature spectroscopic analysis of the samples, global minimum achievable temperatures of 160 to 110 K are estimated. The potential of Tm-doped crystals to realize mid-IR optical cryocoolers and radiation balanced lasers (RBLs) in the eye-safe region of the spectrum is discussed, and a promising two-tone RBL in a tandem structure of Tm:YLF and Ho:YLF crystals is proposed.

Diode-pumped solid-state laser platform for compact and long-lasting strontium-based optical clocks.

Optical clocks based on strontium (Sr) atoms and ions are currently used to provide precise standards for measuring time. These devices require several narrow-band visible laser sources at specific wavelengths to operate. We report on the diode-pumped continuous-wave laser operation at 674, 688, 689, 698, and 707 nm of a single crystal of Pr3+:LiGdF4 (Pr:GLF). To the best of our knowledge, Pr:GLF is the only active medium suitable for solid-state laser operation at all the wavelengths of interest for Sr-based clocks in the deep-red region. We also investigated the spectral tunability of this source, achieving an uninterrupted tuning range of 17 nm, between 697 and 714 nm.

Laser investigation of Yb:YLF crystals fabricated with the micro-pulling-down technique.

Fiber rods of 10% doped Yb:YLF were fabricated with the micro-pulling-down technique and characterized. The crystal a axis was oriented along the rod length, allowing polarized emission with the largest cross section available in the c direction. Laser experiments showed that these fiber samples perform similarly to crystals grown by the standard Czochralski method. Intrinsic slope efficiency of ∼50% was measured in both cases, with small comparable intracavity losses, proving the good quality of the fiber material.

Widely tunable, efficient 2 µm laser in monocrystalline Tm3+:SrF2.

We report on the growth, spectroscopy, and laser operation of monocrystalline Tm3+:SrF2. Spectroscopic investigations confirmed the presence of broad absorption and emission bands caused by inequivalent doped sites, introduced by charge compensation effects which also caused the clusterization of doping ions in the lattice. We obtained continuous-wave laser emission at about 2 µm, with efficiencies comparable with other Tm-doped crystals. We also achieved an uninterrupted tuning range of 180 nm between 1.8 and 2 µm. This characterization indicates that SrF2 enhances the cooperative mechanisms between Tm ions, helping to obtain remarkable laser performances at low doping concentrations.