Probing the Helium Dimer by Relativistic Highly Charged Projectiles.

We study the fragmentation of He_{2} dimers into He^{+} ions by relativistic highly charged projectiles. We demonstrate that the interaction between an ultrafast projectile with an extremely extended object-the helium dimer-possesses interesting features that are absent in collisions with "normal" molecules. We also show that such projectiles, due to their enormous interaction range, can accurately probe the ground state of the dimer and even be used for a determination of its binding energy.

Relativistic transfer ionization and the Breit interaction.

We consider correlated transfer ionization in relativistic collisions between a highly charged ion and a light atom. In this process two quasifree electrons of the atom interact with each other during the short collision time that results in the capture of one of them by the ion and emission of the other. We show that this process is strongly influenced by the generalized Breit interaction already at modest relativistic impact energies.

Two-center interferences in dielectronic transitions in H2(+) + He collisions.

Molecular two-center interferences in a collision induced excitation of H2(+) projectile ions, with simultaneous ionization of helium target atoms, are investigated in a kinematically complete experiment. In the process under investigation, the helium atom is singly ionized and simultaneously the molecular hydrogen ion is dissociated. Different collision mechanisms are identified and interference fringes emerging from a correlated first-order mechanism and from an independent second-order process are observed.

Transfer ionization in collisions with a fast highly charged ion.

Transfer ionization in fast collisions between a bare ion and an atom, in which one of the atomic electrons is captured by the ion whereas another one is emitted, crucially depends on dynamic electron-electron correlations. We show that in collisions with a highly charged ion a strong field of the ion has a very profound effect on the correlated channels of transfer ionization. In particular, this field weakens (strongly suppresses) electron emission into the direction opposite (perpendicular) to the motion of the ion. Instead, electron emission is redirected into those parts of the momentum space which are very weakly populated in fast collisions with low charged ions.

Electron- and proton-impact excitation of hydrogenlike uranium in relativistic collisions.

The K shell excitation of H-like uranium (U(91+)) in relativistic collisions with different gaseous targets has been studied at the experimental storage ring at GSI Darmstadt. By performing measurements with different targets as well as with different collision energies, we were able to observe for the first time the effect of electron-impact excitation (EIE) process in the heaviest hydrogenlike ion. The large fine-structure splitting in H-like uranium allowed us to unambiguously resolve excitation into different L shell levels. State-of-the-art calculations performed within the relativistic framework which include excitation mechanisms due to both protons (nucleus) and electrons are in good agreement with the experimental findings. Moreover, our experimental data clearly demonstrate the importance of including the generalized Breit interaction in the treatment of the EIE process.

Polarization and interference effects in ionization of Li by ion impact.

We present initial-state selective fully differential cross sections for ionization of lithium by 24 MeV O8+ impact. The data for ionization from the 2s and 2p states look qualitatively different from each other and from 1s ionization of He. For ionization from the 2p state, to which in our study the m(L)=-1 substate predominantly contributes, we observe orientational dichroism and for 2s ionization pronounced interference which we trace back to the nodal structure of the initial-state wave function.

Strongly enhanced backward emission of electrons in transfer and ionization.

We studied three-dimensional angular distributions and longitudinal momentum spectra of electrons ejected in transfer plus ionization (TI), i.e., the ejection of one and the capture of a second target electron, for ion-helium collisions. We observe a pronounced structure strongly focused opposite to the projectile beam direction, which we associate with a new correlated TI mechanism proposed recently. This process contributes significantly to the total cross sections over a broad range of perturbations η, even at η as large as 0.5, where uncorrelated TI mechanisms were thought to be dominant.

Resonant two-photon single ionization of two identical atoms.

Resonant two-photon single ionization in a system consisting of two spatially well-separated identical atoms is studied. Because of two-center electron-electron correlations, the ionization may also proceed through photoexcitation of both atoms with subsequent interatomic Coulombic decay. We show that this channel may qualitatively change the dependence of the photoionization on the field intensity as well as the spectra of emitted electrons.

Young-type interference in projectile-electron loss in energetic ion-molecule collisions.

Under certain conditions an electron bound in a fast projectile ion, colliding with a molecule, interacts mainly with the nuclei and inner shell electrons of atoms forming the molecule. Because of their compact localization in space and distinct separation from each other, these molecular centers play in such collisions a role similar to that of optical slits in light scattering leading to pronounced interference in the spectra of the electron emitted from the projectile.

Strongly enhanced recombination via two-center electronic correlations.

In the presence of a neighboring atom, electron-ion recombination can proceed resonantly via excitation of an electron in the atom, with subsequent relaxation through radiative decay. It is shown that this two-center dielectronic process can largely dominate over single-center radiative recombination at internuclear distances as large as several nanometers. The relevance of the predicted process is demonstrated by using examples of water-dissolved alkali cations and warm dense matter.

Two-center resonant photoionization.

Photoionization of an atom A, in the presence of a neighboring atom B, can proceed both directly and via resonant excitation of B with subsequent energy transfer to A through two-center electron-electron correlation. We show that in such a case the photoionization process can be very strongly enhanced and acquire interesting characteristic features, both in its time development and the electron spectrum.

Two-center double-capture interference in fast He2+ + H2 collisions.

We report the first observation of Young-type interference effects in a two-electron transfer process. These effects change strongly as the projectile velocity changes in fast (1.2 and 2.0 MeV) He(2+) + H(2) collisions as manifested in strong variations of the double-electron capture rates with the H(2) orientation. This is consistent with fully quantum mechanical calculations, which ignore sequential electron transfer, and a simple projectile de Broglie wave picture assuming that two-electron transfer probabilities are higher in collisions where the projectile passes close to either one of the H(2) nuclei.

Inelastic collisions of relativistic electrons with atomic targets in a laser field.

We consider collisions of relativistic electrons with atomic targets in a laser field assuming that the parameters of the latter are such that the field does not influence the target directly. Concentrating on target transitions we show that they can be substantially affected by the presence of the laser field. This may occur either via strong modifications in the motion of the relativistic electrons caused by the laser field or via the Compton effect when the incident electrons convert laser photon(s) into photons with frequencies equal to target transition frequencies.

Recoil-ion momentum distributions for two-photon double ionization of He and Ne by 44 eV free-electron laser radiation.

Recoil-ion momentum distributions for two-photon double ionization of He and Ne (variant Planck's over omega=44 eV) have been recorded with a reaction microscope at FLASH (the free-electron laser at Hamburg) at an intensity of approximately 1 x 10(14) W/cm2 exploring the dynamics of the two fundamental two-photon-two-electron reaction pathways, namely, sequential and direct (or nonsequential) absorption of the photons. We find strong differences in the recoil-ion momentum patterns for the two mechanisms pointing to the significantly different two-electron emission dynamics and thus provide serious constraints for theoretical models.

Doubly inelastic collisions with relativistic heavy ions and target recoil momentum spectroscopy.

We consider relativistic collisions of heavy hydrogenlike ions with hydrogen and helium atoms in which the ion-atom interaction causes both colliding particles to change their internal states. Concentrating on the study of the longitudinal momentum spectrum of the atomic recoil ions, we discuss the role of relativistic and higher order effects, predict a surprisingly strong influence of the projectile's electron on the momentum transfer, and show that the important information about the doubly inelastic collisions could be obtained in experiment merely by measuring the recoil momentum spectrum.

Radiation field and resonant two-center dielectronic transitions in relativistic ion-atom collisions.

We consider projectile-electron excitation and loss in relativistic collisions of ionic projectiles with excited atoms. We show that under certain conditions electron transitions in the ion and atom can be resonantly coupled in the collision via the radiation field. The resonance becomes possible due to the Doppler effect, has a well-defined impact energy threshold, and clearly manifests itself in the cross sections. Since the range of the ion-atom interaction in the resonance case is very long, the presence of other atoms in the target medium as well as the size of the space occupied by the medium have to be taken into account. As a result, the cross section may become dependent on the density of the target atoms and/or the target size.

Mutual projectile-target ionization via the two-center dielectronic interaction in relativistic ion-atom collisions.

We study mutual ionization in relativistic collisions between hydrogenlike projectiles and helium atoms: X(Z+)(1s)+He(1s(2))-->X((Z+1)+)+ He+(1s)+2e(-). At high collision velocities and for not too heavy projectiles, 2Z/v<<1 (v is the collision velocity), the mutual ionization proceeds via the direct interaction between two electrons bound (initially) to different colliding particles. Considering for the first time this fundamental process in the case of relativistic collisions, we calculate ionization cross sections and discuss manifestations of relativistic effects. In particular, we predict two novel and interesting phenomena: (i) considerable relativistic effects in collisions with low Lorentz factors gamma and (ii) the rapid saturation of these effects at higher gamma. Estimates show that the predicted effects can be experimentally tested using existing facilities and spectrometers.

Nonlinear bound-free pair creation in the strong electromagnetic fields of a heavy nucleus and an intense x-ray laser.

We study e(-)e(+) pair creation in the collision of a heavy nucleus with an intense x-ray laser, where the produced e(-) is simultaneously captured into the K shell of the projectile nucleus. The parameters of the colliding system are chosen such that the absorption of at least two photons from the laser wave is required in order to surmount the energy threshold of the reaction. Considering this fundamental nonlinear strong-field process for the first time, we estimate the total production rate as well as the angular and energetic distributions of the emitted positrons. According to our results, the process of nonlinear bound-free pair creation could become observable by the aid of the upcoming x-ray laser facilities.