RESUMEN
Antibiotic resistance genes (ARGs) may be synergistic selected during bio-treatment of chromium-containing wastewater and causing environmental risks through horizontal transfer. This research explored the impact of self-screening bacterium Acinetobacter sp. SL-1 on the treatment of chromium-containing wastewater under varying environmental conditions. The findings indicated that the optimal Cr(VI) removal conditions were an anaerobic environment, 30 °C temperature, 5 g/L waste molasses, 100 mg/L Cr(VI), pH = 7, and a reaction time of 168 h. Under these conditions, the removal of Cr(VI) reached 99.10 %, however, it also developed cross-resistance to tetracycline, gentamicin, clarithromycin, ofloxacin following exposure to Cr(VI). When decrease Cr(VI) concentration to 50 mg/L at pH of 9 with waste molasses as carbon source, the expression of ARGs was down regulated, which decreased the horizontal transfer possibility of ARGs and minimized the potential environmental pollution risk caused by ARGs. The study ultimately emphasized that the treatment of chromium-containing wastewater with waste molasses in conjunction with SL-1 not only effectively eliminates hexavalent chromium but also mitigates the risk of environmental pollution.
Asunto(s)
Acinetobacter , Catecoles , Aguas Residuales , Antibacterianos/metabolismo , Melaza , Carbono/metabolismo , Acinetobacter/metabolismo , Cromo/metabolismo , Farmacorresistencia Microbiana , Biodegradación AmbientalRESUMEN
The accurate prediction of hazardous gas dispersion process is essential to air quality monitoring and the emergency management of contaminant gas leakage incidents in a chemical cluster. Conventional Gaussian-based dispersion models can seldom give accurate predictions due to inaccurate input parameters and the computational errors. In order to improve the prediction accuracy of a dispersion model, a data-driven air dispersion modeling method based on data assimilation is proposed by applying particle filter to Gaussian-based dispersion model. The core of the method is continually updating dispersion coefficients by assimilating observed data into the model during the calculation process. Another contribution of this paper is that error propagation detection rules are proposed to evaluate their effects since the measured and computational errors are inevitable. So environmental protection authorities can be informed to what extent the model output is of high confidence. To test the feasibility of our method, a numerical experiment utilizing the SF6 concentration data sampled from an Indianapolis field study is conducted. Results of accuracy analysis and error inspection imply that Gaussian dispersion models based on particle filtering and error propagation detection have better performance than traditional dispersion models in practice though sacrificing some computational efficiency.
Asunto(s)
Contaminantes Atmosféricos/análisis , Contaminación del Aire/análisis , Monitoreo del Ambiente/métodos , Gases/química , Modelos Químicos , Distribución NormalRESUMEN
Dispersion prediction plays a significant role in the management and emergency response to hazardous gas emissions and accidental leaks. Compared with conventional atmospheric dispersion models, machine leaning (ML) models have both high accuracy and efficiency in terms of prediction, especially in field cases. However, selection of model type and the inputs of the ML model are still essential problems. To address this issue, two ML models (i.e., the back propagation (BP) network and support vector regression (SVR) with different input selections (i.e., original monitoring parameters and integrated Gaussian parameters) are proposed in this paper. To compare the performances of presented ML models in field cases, these models are evaluated using the Prairie Grass and Indianapolis field data sets. The influence of the training set scale on the performances of ML models is analyzed as well. Results demonstrate that the integrated Gaussian parameters indeed improve the prediction accuracy in the Prairie Grass case. However, they do not make much difference in the Indianapolis case due to their inadaptability to the complex terrain conditions. In addition, it can be summarized that the SVR shows better generalization ability with relatively small training sets, but tends to under-fit the training data. In contrast, the BP network has a stronger fitting ability, but sometimes suffers from an over-fitting problem. As a result, the model and input selection presented in this paper will be of great help to environmental and public health protection in real applications.
Asunto(s)
Liberación de Peligros Químicos , Aprendizaje Automático , Modelos Teóricos , Gases , Sustancias Peligrosas , Distribución Normal , Máquina de Vectores de SoporteRESUMEN
Chemical production activities in industrial districts pose great threats to the surrounding atmospheric environment and human health. Therefore, developing appropriate and intelligent pollution controlling strategies for the management team to monitor chemical production processes is significantly essential in a chemical industrial district. The literature shows that playing a chemical plant environmental protection (CPEP) game can force the chemical plants to be more compliant with environmental protection authorities and reduce the potential risks of hazardous gas dispersion accidents. However, results of the current literature strictly rely on several perfect assumptions which rarely hold in real-world domains, especially when dealing with human adversaries. To address bounded rationality and limited observability in human cognition, the CPEP game is extended to generate robust schedules of inspection resources for inspection agencies. The present paper is innovative on the following contributions: (i) The CPEP model is extended by taking observation frequency and observation cost of adversaries into account, and thus better reflects the industrial reality; (ii) Uncertainties such as attackers with bounded rationality, attackers with limited observation and incomplete information (i.e., the attacker's parameters) are integrated into the extended CPEP model; (iii) Learning curve theory is employed to determine the attacker's observability in the game solver. Results in the case study imply that this work improves the decision-making process for environmental protection authorities in practical fields by bringing more rewards to the inspection agencies and by acquiring more compliance from chemical plants.
Asunto(s)
Industria Química , Contaminación Ambiental/prevención & control , Teoría del Juego , Prevención de Accidentes , Conservación de los Recursos Naturales , Toma de Decisiones , Humanos , IncertidumbreRESUMEN
The chemical industry is of paramount importance to the world economy and this industrial sector represents a substantial income source for developing countries. However, the chemical plants producing inside an industrial district pose a great threat to the surrounding atmospheric environment and human health. Therefore, designing an appropriate and available air quality monitoring network (AQMN) is essential for assessing the effectiveness of deployed pollution-controlling strategies and facilities. As monitoring facilities located at inappropriate sites would affect data validity, a two-stage data-driven approach constituted of a spatio-temporal technique (i.e. Bayesian maximum entropy) and a multi-objective optimization model (i.e. maximum concentration detection capability and maximum dosage detection capability) is proposed in this paper. The approach aims at optimizing the design of an AQMN formed by gas sensor modules. Owing to the lack of long-term measurement data, our developed atmospheric dispersion simulation system was employed to generate simulated data for the above method. Finally, an illustrative case study was implemented to illustrate the feasibility of the proposed approach, and results imply that this work is able to design an appropriate AQMN with acceptable accuracy and efficiency.