Gradiently Foaming Ultrasoft Hydrogel with Stop Holes for Highly Deformable, Crack-Resistant and Sensitive Conformal Human-Machine Interfaces.

Hydrogels are considered as promising materials for human-machine interfaces (HMIs) owing to their merits of tailorable mechanical and electrical properties; nevertheless, it remains challenging to simultaneously achieve ultrasoftness, good mechanical robustness and high sensitivity, which are the pre-requisite requirements for wearable sensing applications. Herein, for the first time, this work proposes a universal phase-transition-induced bubbling strategy to fabricate ultrasoft gradient foam-shaped hydrogels (FSHs) with stop holes for high deformability, crack-resistance and sensitive conformal HMIs. As a typical system, the FSH based on polyacrylamide/sodium alginate system shows an ultralow Young's modulus (1.68 kPa), increased sustainable strain (1411%), enhanced fracture toughness (915.6 J m-2), improved tensile sensitivity (21.77), and compressive sensitivity (65.23 kPa-1). The FSHs are used for precisely acquiring and identifying gesture commands of the operator to remotely control a surgical robot for endoscopy and an electric ship in a first-person perspective for cruising, feeding crabs and monitoring the environmental change in real-time.

Green financing and environmental risk mitigation: is environmental protection tax law that important?

This research examines green finance's role in mitigating environmental concerns in China. The significance of the tax code for environmental protection is examined in detail. The research examines the association between green financing and lowering environmental hazards using regression analysis tests, dummy estimation techniques, and robustness analysis on data collected between 2003 and 2018. This research demonstrates that the Environmental Protection Tax Law is a valuable policy instrument for advancing environmentally responsible financing and addressing environmental issues. Green money was shown to be associated with lower environmental hazards. This study's results imply that tax legislation has been implemented to safeguard the environment in China, and more money has been placed into environmentally beneficial initiatives. The impact of environmental protection legislation on greenhouse gas emissions, urbanization, and CO2 emissions is also highlighted. These findings are significant for environmentalists, policymakers, and the financial and banking sectors because they demonstrate how to develop effective strategies to advance green finance and mitigate ecological threats.

Rheology Engineering for Dry-Spinning Robust N-Doped MXene Sediment Fibers toward Efficient Charge Storage.

MXene nanosheets are believed to be an ideal candidate for fabricating fiber supercapacitors (FSCs) due to their metallic conductivity and superior volumetric capacitance, while challenges remain in continuously collecting bare MXene fibers (MFs) via the commonly used wet-spinning technique due to the intercalation of water molecules and a weak interaction between Ti3 C2 TX nanosheets in aqueous coagulation bath that ultimately leads to a loosely packed structure. To address this issue, for the first time, a dry-spinning strategy is proposed by engineering the rheological behavior of Ti3 C2 TX sediment and extruding the highly viscose stock directly through a spinneret followed by a solvent evaperation induced solidification. The dry-spun Ti3 C2 TX fibers show an optimal conductivity of 2295 S cm-1 , a tensile strength of 64 MPa and a specific capacitance of 948 F cm-3 . Nitrogen (N) doping further improves the capacitance of MFs to 1302 F cm-3 without compromising their mechanical and electrical properties. Moreover, the FSC based on N-doped MFs exhibits a high volumetric capacitance of 293 F cm-3 , good stability over 10 000 cycles, excellent flexibility upon bending-unbending, superior energy/power densities and anti-self-discharging property. The excellent electrochemical and mechanical properties endow the dry-spun MFs great potential for future applications in wearable electronics.

Nacre-Inspired Strong MXene/Cellulose Fiber with Superior Supercapacitive Performance via Synergizing the Interfacial Bonding and Interlayer Spacing.

MXene fibers are promising candidates for weaveable and wearable energy storage devices because of their good electrical conductivity and high theoretical capacitance. Herein, we propose a nacre-inspired strategy for simultaneously improving the mechanical strength, volumetric capacitance, and rate performance of MXene-based fibers through synergizing the interfacial interaction and interlayer spacing between Ti3C2TX nanosheets. The optimized hybrid fibers (M-CMC-1.0%) with 99 wt % MXene loading exhibit an improved tensile strength of ∼81 MPa and a high specific capacitance of 885.0 F cm-3 at 1 A cm-3 together with an outstanding rate performance of 83.6% retention at 10 A cm-3 (740.0 F cm-3). As a consequence, the fiber supercapacitor (FSC) based on the M-CMC-1.0% hybrid delivers an output capacitance of 199.5 F cm-3, a power density of 1186.9 mW cm-3, and an energy density of 17.7 mWh cm-3, respectively, implying its promising applications as portable energy storage devices for future wearable electronics.

Universal Strategy for Preparing Highly Stable PBA/Ti3C2Tx MXene toward Lithium-Ion Batteries via Chemical Transformation.

Prussian blue analogues (PBAs) are believed to be intriguing anode materials for Li+ storage because of their tunable composition, designable topologies, and tailorable porous structures, yet they suffer from severe capacity decay and inferior cycling stability due to the volume variation upon lithiation and high electrical resistance. Herein, we develop a universal strategy for synthesizing small PBA nanoparticles hosted on two-dimensional (2D) MXene or rGO (PBA/MX or PBA/rGO) via an in situ transformation from ultrathin layered double hydroxides (LDH) nanosheets. 2D conductive nanosheets allow for fast electron transport and guarantee the full utilization of PBA even at high rates; at the meantime, PBA nanoparticles effectively prevent 2D materials from restacking and facilitate rapid ion diffusion. The optimized Ni0.8Mn0.2-PBA/MX as an anode for lithium-ion batteries (LIBs) delivers a capacity of 442 mAh g-1 at 0.1 A g-1 and an excellent cycling robustness in comparison with bare PBA bulk crystals. We believe that this study offers an alternative choice for rationally designing PBA-based electrode materials for energy storage.