Mn²+-bonded reduced graphene oxide with strong radiative recombination in broad visible range caused by resonant energy transfer.

The photoluminescence (PL) characteristics of Mn(2+)-bonded reduced graphene oxide (rGO) are studied in details. The Mn(2+)-bonded rGO is synthesized using MnO(2)-decorated GO as the intermediate products and ideal tunable PL is obtained by enhancing the long-wavelength (450-550 nm) emission. The PL spectra excited by different wavelengths are analyzed to elucidate the mechanism, and the resonant energy transfer between Mn(2+) and sp(2) clusters of the rGO appears to be responsible for the enhanced long-wavelength emission. To examine the effect of Mn(2+) on the long-wavelength emission from the Mn(2+)-bonded rGO, the PL characteristics of Mn(2+)-bonded rGO with smaller Mn concentrations are studied and weaker emission is observed. Our theoretical calculation corroborates the experimental results.

Green light stimulates terahertz emission from mesocrystal microspheres.

The discovery of efficient sources of terahertz radiation has been exploited in imaging applications, and developing a nanoscale terahertz source could lead to additional applications. High-frequency mechanical vibrations of charged nanostructures can lead to radiative emission, and vibrations at frequencies of hundreds of kilohertz have been observed from a ZnO nanobelt under the influence of an alternating electric field. Here, we observe mechanical resonance and radiative emission at ∼ 0.36 THz from core-shell ZnO mesocrystal microspheres excited by a continuous green-wavelength laser. We find that ∼ 0.016% of the incident power is converted into terahertz radiation, which corresponds to a quantum efficiency of ∼ 33%, making the ZnO microspheres competitive with existing terahertz-emitting materials. The mechanical resonance and radiation stem from the coherent photo-induced vibration of the hexagonal ZnO nanoplates that make up the microsphere shells. The ZnO microspheres are formed by means of a nonclassical, self-organized crystallization process, and represent a straightforward route to terahertz radiation at the nanoscale.

Glycerol-bonded 3C-SiC nanocrystal solid films exhibiting broad and stable violet to blue-green emission.

We have produced glycerol-bonded 3C-SiC nanocrystal (NC) films, which when excited by photons of different wavelengths, produce strong and tunable violet to blue-green (360-540 nm) emission as a result of the quantum confinement effects rendered by the 3C-SiC NCs. The emission is so intense that the emission spots are visible to the naked eyes. The light emission is very stable and even after storing in air for more than six months, no intensity degradation can be observed. X-ray photoelectron spectroscopy and absorption fine structure measurements indicate that the Si-terminated NC surfaces are completely bonded to glycerol molecules. Calculations of geometry optimization and electron structures based on the density functional theory for 3C-SiC NCs with attached glycerol molecules show that these molecules are bonded on the NCs causing strong surface structural change, while the isolated levels in the conduction band of the bare 3C-SiC NCs are replaced with quasi-continuous bands that provide continuous tunability of the emitted light by changing the frequencies of exciting laser. As an application, we demonstrate the potential of using 3C-SiC NCs to fabricate full-color emitting solid films by incorporating porous silicon.

Theoretical study of Y(n)O(2) and Y(n)O(2)(-) (n = 1-8) clusters.

The structural, electronic, and magnetic properties of Y(n)O(2) and Y(n)O(2)(-) clusters, up to n = 8, have been systematically investigated by using the density-functional approach. Our theoretical results show that the geometries of the ground-state neutral and anionic clusters are similar, except for n = 2. For the lowest-energy structures of the two systems, a two-dimensional to three-dimensional structural transition is identified. In addition, the ionization potentials, electron affinities, electron detachment energies, and gaps are carefully investigated. Here, the calculated electron affinities and electron detachment energies are in good agreement with the experimental data, implying that the predictions of the ground-state configurations of these clusters are reliable. On the basis of the optimized structures, we investigate and discuss the magnetic properties of the two systems for the first time. (PACS numbers: 75.50.Xx. 36.40.Cg,73.22.-f.).

Identification of surface structures on 3C-SiC nanocrystals with hydrogen and hydroxyl bonding by photoluminescence.

SiC nanocrystals (NCs) exhibit unique surface chemistry and possess special properties. This provides the opportunity to design suitable surface structures by terminating the surface dangling bonds with different atoms thereby boding well for practical applications. In this article, we report the photoluminescence properties of 3C-SiC NCs in water suspensions with different pH values. Besides a blue band stemming from the quantum confinement effect, the 3C-SiC NCs show an additional photoluminescence band at 510 nm when the excitation wavelengths are longer than 350 nm. Its intensity relative to the blue band increases with the excitation wavelength. The 510 nm band appears only in acidic suspensions but not in alkaline ones. Fourier transform infrared, X-ray photoelectron spectroscopy, and X-ray absorption near-edge structure analyses clearly reveal that the 3C-SiC NCs in the water suspension have Si-H and Si-OH bonds on their surface, implying that water molecules only react with a Si-terminated surface. First-principle calculations suggest that the additional 510 nm band arises from structures induced by H(+) and OH(-) dissociated from water and attached to Si dimers on the modified (001) Si-terminated portion of the NCs. The size requirement is consistent with the observation that the 510 nm band can only be observed when the excitation wavelengths are relatively large, that is, excitation of bigger NCs.

Tin oxide nanoribbons with vacancy structures in luminescence-sensitive oxygen sensing.

Vacancy structures in tin oxide nanoribbons fabricated via thermal evaporation and post-processing are probed by luminescence spectroscopy, and interesting properties that bode well for oxygen sensing are observed. Besides a broad 620-nm band, the fabricated tin oxide nanoribbons show a photoluminescence band at 480 nm when the measurement temperature is <100 K. The blue band appears from nanoribbons synthesized under high oxygen pressure or annealed under oxygen. The dependence suggests that the oxygen interstitial and vacancy densities determine the electronic states that produce the blue band. Calculation of the electron structures based on the density functional theory shows that decreased oxygen vacancies or increased oxygen interstitials enhance the 480-nm band but suppress the 620-nm band. The results reported here indicate that the tin oxide nanoribbons with vacancy structures have potential applications in luminescence-sensitive oxygen sensing.

Spectral features of LO phonon sidebands in luminescence of free excitons in GaN.

In the paper a combined experimental and theoretical investigation of the longitudinal optical phonon sidebands (PSBs) in the luminescence of free excitons in GaN at moderately high temperatures was reported. The spectral features, including line broadening, shift, and asymmetry of the one- and two-phonon PSBs, were revealed both experimentally and theoretically. It is found that the linewidth of the one-phonon PSB is surprisingly always larger than that of the two-phonon PSB in the interested temperature range. Moreover, the thermal broadening rates of the one- and two-phonon PSBs are considerably different. We adopted the Segall-Mahan theory [B. Segall and G. D. Mahan, Phys. Rev. 171, 935 (1968)] to compute the PSB spectra of the free excitons in GaN. Only one adjustable parameter, the effective mass of the holes, was used in the calculations. For the one-phonon PSB, an excellent agreement between theory and experiment is achieved when an adequate effective mass of the holes was used.

Optical emission from excess Si defect centers in Si nanostructures.

Four groups of Si nanostructures with and without beta-SiC nanocrystals were fabricated for clarifying the origin of a blue emission with a double-peak structure at 417 and 436 nm. Spectral analyses and microstructural observations show that the blue emission is related to the existence of excess Si atoms in these Si nanostructures. The energy levels of electrons in Si nanocrystals with vacancy defects formed from the excess Si atoms are calculated and the characteristics of the obtained density of states coincide with the observed double-peak emission. The present work provides a possible mechanism of the blue emission in various Si nanostructures.