Co4S3 Nanoparticles Confined in an MnS Nanorod-Grafted N, S-Codoped Carbon Polyhedron for Highly Efficient Sodium-Ion Batteries.

Sodium-ion batteries (SIBs) suffer from limited ion diffusion and structural expansion, generating the urgent demand for Na+ accommodable materials with promising architectures. In this work, the rational exploration for Co4S3 nanoparticles confined in an MnS nanorod-grafted N, S-codoped carbon polyhedron (Co-Mn-S@N-S-C) is achieved by the in situ growth of MOF on MnO2 nanorod along with the subsequent carbonization and sulfurization. Benefiting from the distinctive nanostructure, the Co-Mn-S@N-S-C anode delivers excellent structural stability, resulting in prolonged cycling stability with a capacity retention of 90.2% after 1000 cycles at 2 A g-1. Moreover, the reaction storage mechanism is clarified by the in situ X-ray diffraction (XRD) and transmission electron microscopy (TEM) measurements. The results indicate that properly designed electrode materials have huge potential applications for highly efficient energy storage devices.

Ultrahigh areal capacity and long cycling stability of sodium metal anodes boosted using a 3D-printed sodiophilic MXene/rGO microlattice aerogel.

Sodium metal has emerged as a highly promising anode material for sodium-based batteries, owing to its intrinsic advantages, including its high theoretical capacity, low working plateau and low cost. However, the uncontrolled formation of sodium dendrites accompanied by unrestricted volume expansion severely limits its application. To tackle these issues, we propose an approach to address these issues by adopting a three-dimensional (3D) structure of Ti3C2Tx/reduced graphene oxide (Ti3C2Tx/rGO) constructed by a direct-ink writing (DIW) 3D printing technique as the Na metal anode host electrode. The combination of the 3D-printed rGO skeleton offering artificial porous structures and the incorporation of sodiophilic Ti3C2Tx nanosheets provides abundant nucleation sites and promotes uniform sodium metal deposition. This specially designed architecture significantly enhances the Na metal cycling stability by effectively inhibiting dendrite formation. The experimental results show that the designed Ti3C2Tx/rGO electrode can achieve a high coulombic efficiency (CE) of 99.91% after 1800 cycles (3600 h) at 2 mA cm-2 with 2 mA h cm-2. Notably, the adopted electrodes exhibit a long life span of more than 1400 h with a high CE over 99.93% when measured with an ultra-high capacity of 50 mA h cm-2 at 5 mA cm-2. Furthermore, a 3D-printed full cell consisting of a Na@Ti3C2Tx/rGO anode and a 3D-printed Na3V2(PO4)3C-rGO (NVP@C-rGO) cathode was successfully demonstrated. This 3D-printed cell could provide a notable capacity of 85.3 mA h g-1 at 100 mA g-1 after 500 cycles. The exceptional electrochemical performance achieved by the 3D-printed full cell paves the way for the development of practical sodium metal anodes.

Longevous Sodium Metal Anodes with High Areal Capacity Enabled by 3D-Printed Sodiophilic Monoliths.

Sodium metal anode, featured by favorable redox voltage and material availability, offers a feasible avenue toward high-energy-density devices. However, uneven metal deposition and notorious dendrite proliferation synchronously hamper its broad application prospects. Here, a three-dimensional (3D) porous hierarchical silver/reduced graphene oxide (Ag/rGO) microlattice aerogel is devised as a sodiophilic monolith, which is realized by a direct ink writing 3D printing technology. The thus-printed Na@Ag/rGO electrode retains a durable cycling lifespan over 3100 h at 3.0 mA cm-2/1.0 mAh cm-2, concurrently harvesting a high average Coulombic efficiency of 99.80%. Impressively, it can be cycled for 340 h at a stringent condition of 6.0 mA cm-2 with a large areal capacity of 60.0 mAh cm-2 (∼1036.31 mAh g-1). Meanwhile, the well-regulated Na ion flux and uniform deposition kinetics are systematically probed by comprehensive electroanalytical analysis and theoretical simulations. As a result, assembled Na metal full battery delivers a long cycling sustainability over 500 cycles at 100 mA g-1 with a low per-cycle decay of 0.85%. The proposed strategy might inspire the construction of high-capacity Na metal anodes with appealing stability.

Altering the Alkaline Metal Ions in Lepidocrocite-Type Layered Titanate for Sodium-Ion Batteries.

The relatively large ionic radius of the Na ion is one of the primary reasons for the slow diffusion of Na ions compared to that of Li ions in de/intercalation processes in sodium-ion batteries (SIBs). Interlayer expansion of intercalation hosts is one of the effective techniques for facilitating Na-ion diffusion. For most ionic layered compounds, interlayer expansion relies on intercalation of guest ions. It is important to investigate the role of these ions for material development of SIBs. In this study, alkali-metal ions (Li+, Na+, K+, and Cs+) with different sizes were intercalated into lepidocrocite-type layered titanate by a simple ion-exchange technique to achieve interlayer modulation and those were then evaluated as anode materials for SIBs. By controlling the intercalated alkaline ion species, basal spacings of layered titanates (LTs) in the range of 0.68 to 0.85 nm were obtained. Interestingly, the largest interlayer spacing induced by the large size of Cs did not yield the best performance, while the Na intercalated layered titanate (Na-ILT) demonstrated a superior performance with a specific capacity of 153 mAh g-1 at a current density of 0.1 A g-1. We found that the phenomena can be explained by the high alkaline metal ion concentration and the efficient utilization of the active sites in Na-ILT. The detailed analysis indicates that large intercalating ions like Cs can hamper sodium-ion diffusion although the interlayer spacing is large. Our work suggests that adopting an appropriate interlayer ion species is key to developing highly efficient layered electrode materials for SIBs.

Electrochemical detection of alkaline phosphatase activity via atom transfer radical polymerization.

Alkaline phosphatase (ALP) activity is a diagnostic indicator for a variety of clinical diseases. In this study, an electrochemical method for detecting ALP activity through activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) was developed. Specifically, 3-mercaptopropionic (MPA) was firstly fixed on the electrode through sulfur-gold bonding. Subsequently, α-bromophenylacetic acid (BPAA) as initiator was attached to MPA through the recognized carboxylate-Zr4+-phosphate chemistry. Finally, in the existence of ALP, L-Ascorbic acid 2-phosphate sesquimagnesium salt hydrate (AAPS) was hydrolyzed to produce ascorbic acid (AA) which participated in the ARGET ATRP reaction, grafting polymer containing plenty of ferrocene electroactive probes on the surface of electrode. Under optimal experimental conditions, this method had a linear scope of 20-200 mU mL-1, and a limit of detection (LOD) of 1.64 mU mL-1. In addition, the proposed method had good selectivity as well as anti-interference capability, with satisfactory results in inhibition rate and human serum experiments. By merits of good analytical performance, easy operation, and low cost, such a method for ALP activity detection has promising applications in ALP-related disease detection and inhibitor screening.

Regulating Na deposition by constructing a Au sodiophilic interphase on CNT modified carbon cloth for flexible sodium metal anode.

Na metal anode has attracted increasing attentions as the anode of sodium ion batteries (SIBs) due to its high theoretical capacity, low redox potential and high abundance. However, the formation of uncontrollable Na dendrite during repeated plating/stripping cycles hinders its further development and application. Herein, a sodiophilic Na metal anode host is developed by sputtering gold nanoparticles (Au NPs) into interconnected carbon nanotube modified carbon cloth (CNT/CC) to form a Au-CNT/CC architecture. Sodiophilic Au NPs effectively guide the Na metal uniform deposition and three-dimensional (3D) microporous structure offers a large surface area for nucleation and reducing the current densities. The regulated uniform Na metal deposition mechanism is investigated by the in-situ optical microscopy and simulation analysis. As a result, Au-CNT/CC electrode exhibits a low nucleation overpotential (2.2 mV) and stable cycle performance for 1600 h at 1 mA cm-2 with 2 mAh cm-2. Moreover, it even exhibits a long cycle stability for more than 800 h at 5 mA cm-2 with 2 mAh cm-2. To explore its application, a full cell coupled with a sodium vanadium phosphate coated with carbon layer (NVP@C) cathode is assembled and delivers an average discharge capacity of 80.6 mAh g-1 and coulombic efficiency of 99.6% for 400 cycles at 100 mAh g-1. Furthermore, a flexible pouch cell with Na@Au-CNT/CC as the anode is fabricated and demonstrated good flexibility and future application of wearable electronics.

Efficient learning-based blur removal method based on sparse optimization for image restoration.

In imaging systems, image blurs are a major source of degradation. This paper proposes a parameter estimation technique for linear motion blur, defocus blur, and atmospheric turbulence blur, and a nonlinear deconvolution algorithm based on sparse representation. Most blur removal techniques use image priors to estimate the point spread function (PSF); however, many common forms of image priors are unable to exploit local image information fully. In this paper, the proposed method does not require models of image priors. Further, it is capable of estimating the PSF accurately from a single input image. First, a blur feature in the image gradient domain is introduced, which has a positive correlation with the degree of blur. Next, the parameters for each blur type are estimated by a learning-based method using a general regression neural network. Finally, image restoration is performed using a half-quadratic optimization algorithm. Evaluation tests confirmed that the proposed method outperforms other similar methods and is suitable for dealing with motion blur in real-life applications.