Low-bias conductance of single benzene molecules contacted by direct Au-C and Pt-C bonds.

The electronic transport properties of a single benzene molecule connected to gold and platinum electrodes through the direct Au-C or Pt-C bond are investigated by using a self-consistent ab initio approach that combines the non-equilibrium Green's function (NEGF) formalism with density functional theory (DFT). Our calculations show that the benzene molecule can bind to the Au(111) surface via direct Au-C bond at the adatom, atop and bridge sites. The largest zero-bias conductance is calculated for the bridge site but it is only G = 0.37G(0) (G(0) = 2e(2)/h). In contrast benzene binds to the Pt(111) surface via direct Pt-C bond only at the adatom and atop sites. When the binding site is the adatom a stable molecular junction forms with a zero-bias conductance as large as 1.15G(0). This originates from the efficient coupling between the extended π-type highest occupied molecular orbital of benzene and the conducting states of the Pt electrodes via the 5d(xz) atomic orbital of the adatoms. The calculated transmission is robust to the choice of DFT functionals, illustrating the potential of the Pt-C bond for constructing future molecular electronic devices.

Spin transport properties of 3d transition metal(II) phthalocyanines in contact with single-walled carbon nanotube electrodes.

The spin transport properties of a series of 3d transition metal(ii) phthalocyanines (MPc, M = Mn, Fe, Co, Ni, Cu and Zn) sandwiched between two semi-infinite armchair single-walled carbon nanotube electrodes are investigated by using a self-consistent ab initio approach that combines the non-equilibrium Green's function formalism with spin density functional theory. Our calculations show that among the six molecules only MnPc and FePc can act as nearly perfect spin filters and at the same time have a large transmission around the Fermi level. This is dominated by the highest occupied molecular orbital (HOMO) of the corresponding MPc molecule. In contrast to the other four MPc molecules, whose HOMO is the a(1u) orbital located over the Pc ring, the HOMO of MnPc and FePc is a doubly degenerate pi-type orbital composed of the 3d(xz) and 3d(yz) atomic orbitals of the metal center. The spin polarization of MnPc and FePc is independent of the size of the SWCNT electrodes and can be tuned by chemisorption at the metal center, demonstrating that MPc and carbon nanotubes are a promising materials platform for applications in molecular spintronics.

Electronic transport calculations for the conductance of Pt-1,4-phenylene diisocyanide-Pt molecular junctions.

The low-bias transport properties of a single 1,4-phenylene diisocyanide (PDI) molecule connected to two platinum (Pt) electrodes are investigated using a self-consistent ab initio approach that combines the non-equilibrium Green's function formalism with density functional theory. Our calculations demonstrate that the zero-bias conductance of an asymmetric Pt-PDI-Pt junction, where the PDI molecule is attached to the atop site at one Pt(111) electrode and to a Pt adatom at the other, is 2.6 x 10( - 2)G(0), in good agreement with the experimental value (3 x 10( - 2)G(0)) measured with break junctions. Although the highest occupied and the lowest unoccupied molecule orbitals in PDI are both pi-type, delocalized along the entire molecule, their electronic coupling with the highly conducting states of the Pt electrode is blocked at the atop site, leading to the small transmission. This indicates that more efficient electronic contacts are needed to fabricate molecular devices with a high conductance using Pt electrodes and aromatic isocyanides such as PDI.

Effects of spin-orbit coupling on the conductance of molecules contacted with gold electrodes.

The effects of spin-orbit coupling on the conductance of molecular devices made with Au electrodes are investigated using a fully self-consistent ab initio approach, which combines the non-equilibrium Green's function formalism with density functional theory. In general, we find that the extent to which spin-orbit interaction affects the transport depends on the specific materials system investigated and on the dimensionality of the electrodes. For one-dimensional electrodes contacting benzene-dithiol molecules the spin-orbit coupling induces changes in the low-bias conductance up to about 20%. These originate mostly from changes in the electrode band structure. In contrast when three-dimensional electrodes are used, the bands near the Fermi level are only weakly modified by spin-orbit coupling and most of the variations are due to symmetry changes at the molecule-electrode interface. For this reason strongly coupled systems, such as Au atomic nanowires sandwiched between Au (100) surfaces and benzene-dithiol molecules bonded at the Au (111) hollow site, are rather insensitive to spin-orbit effects. In contrast, in junctions where the coupling between the molecule and the electrodes is weaker, as in the case of benzene-dithiol bonded to Au (111) at adatom positions, the transmission coefficient at the Fermi level can be modified by as much as 14%.