Cross-linked cellulose beads as an eco-friendly support for ZnO/SnO2/carbon xerogel hybrid photocatalyst: Exploring the synergy between adsorption and photocatalysis under simulated sunlight.

This paper explores the application of cross-linked cellulose beads as a sustainable and cost-effective support for the ZnO/SnO2/carbon xerogel hybrid photocatalyst. The application of the developed photocatalytic beads, named CB-Cat, was directed at a simultaneous adsorption/photocatalysis process, which was carried out under simulated sunlight. The characterization of the CB-Cat indicated a good dispersion of the photocatalyst of choice throughout the cellulose matrix, confirming its incorporation into the cellulose beads. Furthermore, it is possible to observe the presence of the photocatalyst on the surface of the CB-Cat, confirming its availability for the photonic activation process. The results showed that the simultaneous adsorption/photocatalysis process was optimal for enhancing the efficiency of methylene blue (MB) removal, especially when compared to the isolated adsorption process. Additionally, the regeneration of the CB-Cat between cycles was favorable toward the maintenance of the MB removal efficiency, as the process carried out without regeneration displayed significant efficiency drops between cycles. Finally, the mechanism evaluation evidenced that hydroxyl and superoxide radicals were the main responsible for the MB photocatalytic degradation during illumination with simulated sunlight.

Electrochemically enhanced iron oxide-modified carbon cathode toward improved heterogeneous electro-Fenton reaction for the degradation of norfloxacin.

In this work, different iron-based cathode materials were prepared using two different approaches: a novel one-step approach, which involved the incorporation of iron oxide with Printex® L6 carbon/PTFE (PL6C/PTFE) on bare carbon felt (CF) and a two-step approach, where iron oxide is deposited onto CF previously modified with PL6C/PTFE. The results obtained from the physical characterization indicated that the presence of iron oxide homogeneously dispersed on the felt fibers with the CF 3-D network kept intact in the one-step approach; whereas the formation of iron oxide aggregates between the felt fibers for material obtained using the two-step approach. Among the iron oxide-based cathodes investigated, the iron-incorporated electrode exhibited the greatest efficiency in terms of the removal and mineralization of norfloxacin (NOR) under neutral pH (complete NOR removal in less than 30 min with around 50% mineralization after 90 min). The findings of this study show that the low cost and simple-to-prepare iron-modified carbon-based materials in HEF process led to the enhanced degradation of organic contaminants in aqueous solutions.

New diamond coatings for a safer electrolytic disinfection.

In this work, a new coating of boron-doped diamond ultra-nanocrystalline (U-NBDD), tailored to prevent massive formation of perchlorates during disinfection, is evaluated as electrode for the reclaiming of treated secondary wastewater by the electrochemically assisted disinfection process. Results obtained are compared to those obtained by using a standard electrode (STD) that was evaluated as a standard in previous research showing outstanding performance for this application. First tests were carried out to evaluate the chlorine speciation obtained after the electrolysis of synthetic chloride solutions at two different ranges of current densities. Concentrations of hypochlorite obtained using the U-NBDD anode at 25 mA cm-2 were 1.5-fold higher, outperforming STD anode; however, at 300 mA cm-2, an overturn on the behavior of anodes occurs where the amount of hypochlorite produced on STD anode was 1.5-fold higher. Importantly, at low current density the formation of chlorates and perchlorates is null using U-NBDD. Then, the disinfection of the real effluent of the secondary clarifier of a municipal wastewater treatment facility is assessed, where inactivation of Escherichia coli is achieved at low charge applied per volume electrolyzed (0.08 A h L-1) at 25 mA cm-2 using the U-NBDD. These findings demonstrate the appropriateness of the strategy followed in this work to obtain safer electro-disinfection technologies for the reclaiming of treated wastewater.

Solar-based photocatalytic ozonation employing novel S-scheme ZnO/Cu2O/CuO/carbon xerogel photocatalyst: effect of pH, salinity, turbidity, and temperature on salicylic acid degradation.

This paper proposes the study of a solar-based photocatalytic ozonation process for the degradation of salicylic acid (SA) using a novel S-scheme ZnO/Cu2O/CuO/carbon xerogel photocatalyst. The incorporation of CuO and Cu2O aims to enhance charge mobility through the formation of p-n heterojunctions with ZnO, whereas the carbon xerogel (XC) was selected due to its eco-friendly nature, capacity to stabilize S-scheme heterojunctions as a solid-state electron mediator, and ability to function as a reducing agent under high temperatures. The characterization of the composites demonstrates that the presence of the XC during the calcination step led to the reduction of a fraction of the CuO into Cu2O, forming a ternary semiconductor heterojunction system. In terms of photocatalysis, the XC/ZnO-CuxO 5% composite achieved the best efficiency for salicylic acid degradation, mainly due to the stabilization of the S-scheme charge transfer pathway between the ZnO/CuO/Cu2O semiconductors by the XC. The total organic carbon (TOC) removal during heterogeneous photocatalysis was 80% for the solar-based process and 68% for the visible light process, after 300 min. The solar-based photocatalytic ozonation process was highly successful regarding the degradation of SA, achieving a 75% increase in the apparent reaction rate constant when compared to heterogeneous photocatalysis. Furthermore, a 78% TOC removal was achieved after 150 min, which is half the time required by the heterogeneous photocatalysis to obtain the same result. Temperature, salinity, and turbidity had major effects on the efficiency of the photocatalytic ozonation process; the system's pH did not cause any major performance variation, which holds relevance for industrial applications.

Black-wattle tannin/kraft lignin H3PO4-activated carbon xerogels as excellent and sustainable adsorbents.

This work proposed new black-wattle tannin/kraft lignin H3PO4-activated carbon xerogels as sustainable and efficient adsorbents. The precursors were chosen based on their eco-friendly and cost-effective nature, aiming to achieve adsorbents with high adsorption capacities. Carbon xerogels were synthesized through polycondensation with formaldehyde and alkaline catalyst in a simple one-pot procedure. Activation was performed using H3PO4 in a tubular furnace (500 °C), under a nitrogen atmosphere. Results show that the inclusion of the kraft lignin led to changes in the morphology of the materials, facilitating the development of their porous structure and increasing specific surface area and pore volume. The best adsorbent (XLT 50 %) was synthesized using a 1:1 tannin/kraft lignin mass ratio. This material presented an adsorption capacity of nearly 1150 mg g-1 of methylene blue (pH = 5 and T = 298 K), which was linked to its high specific surface area of 1348 m2 g-1. The adsorption process followed the pseudo-second-order kinetic model, whereas the adsorption isotherms were best fitted by the Sips model. The XLT 50 % presented good reusability properties, maintaining its adsorption capacity for 3 cycles. Finally, the XLT 50 % presented good adsorptive properties toward other pollutants (methyl orange, 4-chlorophenol, and hexavalent chromium), indicating its versatility for adsorption processes.

Kraft lignin-based carbon xerogel/zinc oxide composite for 4-chlorophenol solar-light photocatalytic degradation: effect of pH, salinity, and simultaneous Cr(VI) reduction.

Considering the ever-increasing need for efficient wastewater treatment, this study focused on the development of new kraft lignin-based carbon xerogel/zinc oxide (XCL/ZnO w) photocatalysts. The inclusion of the carbon xerogel is expected to cause an improvement in charge transfer throughout the photoactivation process, consequently enhancing its overall photocatalytic efficiency. Characterization shows that the materials developed are composed of both zinc oxide and carbon xerogel. The addition of the lignin-based carbon xerogel caused a significant morphological modification to the composite materials, resulting in a greater specific surface area. Regarding the photocatalytic efficiency, the optimized composite (XCL/ZnO 1.0) displayed superior efficiency to the pure zinc oxide, especially when calcined at 700 °C, with an increase of 20% in the overall photodegradation capacity for the 4-chlorophenol (4CP) molecule. The XCL/ZnO 1.0 also displayed better performance than its tannin counterpart, previously reported in the literature, obtaining a 60% increase in the apparent reaction rate constant. The XCL/ZnO 1.0 also displayed better performance for the simultaneous hexavalent chrome (Cr (VI)) reduction/4CP oxidation reaction. Salinity and system pH had a significant influence on the efficiency of the 4CP photodegradation, as higher values of salinity and lower pHs caused a decrease in the overall efficiency of the process. At last, chronoamperometry and open-circuit potential tests confirmed the superiority of the XCL/ZnO 1.0 over the pure ZnO, highlighting the beneficial impact of the carbon xerogel on the charge transport dynamics of the composite.

UV-irradiation and BDD-based photoelectrolysis for the treatment of halosulfuron-methyl herbicide.

This paper reports the development of a novel photoelectrochemical (PEC) oxidation technique based on UV-C irradiation and boron-doped diamond (BDD) anode and its application for the effective removal of the commercial herbicide halosulfuron-methyl (HSM). The study evaluated the influence of the following key operating variables in the photoelectrochemical process: current density, pH, temperature, and initial HSM concentration. With regard to HSM degradation/mineralization, the application of high current densities was found to be more advantageous once it promoted a more rapid degradation and mineralization, with 96% of total organic carbon removal, though the process became more energy-demanding over time. The initial concentration of HSM did not modify the relative degradation rate, though the degradation process became more efficient as expected in a mass-transfer controlled process. The use of acidic pH (pH 3) was found to be more suitable than neutral conditions; this is probably because an anionic resonant form of HSM may be formed in neutral conditions. The temperature level was also found to affect the rate of HSM removal and the degradation efficiency. Finally, the substitution of Na2SO4 by NaCl promoted a more rapid and effective degradation; this is attributed to high production of powerful oxidants. However, only 70% mineralization was reached after 3 h of treatment; this is probably related to the formation of recalcitrant chlorinated sub-products.