Enhancing selective ammonium transport in membrane electrochemical systems.

Recovering ammonia nitrogen from wastewater is a sustainable strategy that simultaneously addresses both nitrogen removal and fertilizer production. Membrane electrochemical system (MES), which utilizes electrochemical redox reactions to transport ammonium ions through cation exchange membranes, has been considered as an effective technology for ammonia recovery from wastewater. In this study, we develop a mathematical model to systematically investigate the impact of co-existing ions on the transport of ammonium (NH4+) ions in MES. Our analysis elucidates the importance of pH values on both the NH4+ transport and inert ion (Na+) transport. We further comprehensively assess the system performance by varying the concentration of Na+ in the system. We find that while the inert cation in the initial anode compartment competes with NH4+ transport, NH4+ dominates the cation transport in most cases. The transport number of Na+ surpasses NH4+ only if the fraction of Na+ to total cation is extremely high (>88.5%). Importantly, introducing Na+ ions into the cathode compartment significantly enhances the ammonia transport due to the Donnan dialysis. The analysis of selective ion transport provides valuable insights into optimizing both selectivity and efficiency in ammonia recovery from wastewater.

Removal of PAHs, TSS, oils and fats from ammonium-rich coke wastewater by granular filtration.

Coke wastewater is a complex industrial wastewater due to its high content of toxic compounds such as cyanides, thiocyanates, phenols, tar, oils, and fats. After a series of treatments, wastewater with a high ammonium content is obtained (around 4,150 mg·L-1). A stripping process is used to reduce it. Certain pollutants in the influent, such as tar, polycyclic aromatic hydrocarbons (PAHs), oils, fats and total suspended solids (TSS), interfere with stripping and therefore must be previously removed. In this study, the performance of a pilot-scale airlift sand filter was evaluated under real conditions for the reduction of the concentration of tar, PAHs, oils, fats and TSS, before stripping. Prior to the sand filter, a cationic flocculant was added to the influent (2 ppm). High (10 mm.min-1), medium (7.5 mm.min-1) and low sand speeds (1.9-2.6 mm.min-1) were assessed. The latter conditions gave the best results: a decrease of 98.2% in TSS, 99.7% in oils, fats and grease and 97.6% in PAHs. The final effluent (≤ 1.6 mg PAHs·L-1, ≤ 5 mg TSS·L-1 and ≤ 0.05 mg·L-1 of fats, oils and grease) was suitable for the stripping process.

Ammonium depletion associated with the COVID-19 pandemic in the Mexican Caribbean.

The Mexican Caribbean contributes significantly to Mexico's gross national product. The number of tourists declined from 16.7 million in 2019 to 8.8 million in 2020 due to the COVID-19 pandemic, with a rapid recovery of 13.5 million in 2021. Wastewater discharge is the primary contamination source associated with the tourism sector's demand for goods and services. Water quality could improve due to fewer tourists arriving during the COVID-19 sanitary emergency. This study aimed to quantify ammonium concentrations at eleven locations to evaluate water quality during the sanitary restriction due to the pandemic in the Mexican Caribbean. The ammonium concentrations were 85 % (Nov-2019), 89 % (Feb-2020), and 86 % (Feb-2021) higher than in Nov-2020, where six of the eleven sampled stations were below the detection limit (0.15 µM). Lower ammonium concentrations coincide with the sanitary restriction period and a decrease in affluent tourists.

Nitrogen isotopic characteristics of aerosol ammonium in a Chinese megacity indicate the reduction from vehicle emissions during the lockdown period.

The role of agricultural versus vehicle emissions in urban atmospheric ammonia (NH3) remains unclear. The lockdown due to the outbreak of COVID-19 provided an opportunity to assess the role of source emissions on urban NH3. Concentrations and δ15N of aerosol ammonium (NH4+) were measured before (autumn in 2017) and during the lockdown (summer, autumn, and winter in 2020), and source contributions were quantified using SIAR. Despite the insignificant decrease in NH4+ concentrations, significantly lower δ15N-NH4+ was found in 2020 (0.6 ± 1.0‰ in PM2.5 and 1.4 ± 2.1‰ in PM10) than in 2017 (15.2 ± 6.7‰ in PM2.5), which indicates the NH3 from vehicle emissions has decreased by∼50% during the lockdown while other source emissions are less affected. Moreover, a reversed seasonal pattern of δ15N-NH4+ during the lockdown in Changsha has been revealed compared to previous urban studies, which can be explained by the dominant effect of non-fossil fuel emissions due to the reductions of vehicle emissions during the lockdown period. Our results highlight the effects of lockdown on aerosol δ15N-NH4+ and the importance of vehicle emissions to urban atmospheric NH3, providing conclusive evidence that reducing vehicle NH3 emissions could be an effective strategy to reduce PM2.5 in Chinese megacities.

Large Seasonal Variation in Nitrogen Isotopic Abundances of Ammonia Volatilized from a Cropland Ecosystem and Implications for Regional NH3 Source Partitioning.

Ammonia (NH3) volatilization from agricultural lands is a main source of atmospheric reduced nitrogen species (NHx). Accurately quantifying its contribution to regional atmospheric NHx deposition is critical for controlling regional air nitrogen pollution. The stable nitrogen isotope composition (expressed by δ15N) is a promising indicator to trace atmospheric NHx sources, presupposing a reliable nitrogen isotopic signature of NH3 emission sources. To obtain more specific seasonal δ15N values of soil NH3 volatilization for reliable regional seasonal NH3 source partitioning, we utilized an active dynamic sampling technique to measure the δ15N-NH3 values volatilized from maize cropping land in northeast China. These values varied from -38.0 to -0.2‰, with a significantly lower rate-weighted value observed in the early period (May-June, -30.5 ± 6.7‰) as compared with the late period (July-October, -8.5 ± 4.3‰). Seasonal δ15N-NH3 variations were related to the main NH3 production pathway, degree of soil ammonium consumption, and soil environment. Bayesian isotope mixing model analysis revealed that without considering the seasonal δ15N variation in soil-volatilized NH3 could result in an overestimate by up to absolute 38% for agricultural volatile NH3 to regional atmospheric bulk ammonium deposition during July-October, further demonstrating that it is essential to distinguish seasonal δ15N profile of agricultural volatile NH3 in regional source apportionment.

Atmospheric organic nitrogen deposition around the Danjiangkou Reservoir: Fluxes, characteristics and evidence of agricultural source.

Dissolved organic nitrogen (DON) deposition was the substantial component of dissolved total nitrogen (DTN) deposition in the world's nitrogen deposition hot spots areas. However, the information on the importance for DON deposition and its sources was still scarce, which limited the comprehensive assessment of the ecological threat from nitrogen deposition. Six sampling sites around the Danjiangkou Reservoir were set up to collect the dry and wet deposition samples from October 2017 to September 2021. The results showed that dry and wet DTN deposition averaged 34.72 kg ha-1 yr-1 and 22.27 kg ha-1 yr-1, respectively. Dry NH4+-N, NO3--N and DON deposition averaged 14.28 kg ha-1 yr-1, 5.91 kg ha-1 yr-1 and 14.53 kg ha-1 yr-1, respectively. Wet NH4+-N, NO3--N and DON deposition averaged 11.14 kg ha-1 yr-1, 3.89 kg ha-1 yr-1and 7.24 kg ha-1 yr-1, respectively. The contributions of DON to DTN were 41.85% (in dry deposition) and 32.50% (in wet deposition), respectively. Dry DON deposition varied between 26.44 kg ha-1 yr-1 and 9.11 kg ha-1 yr-1, and significantly differed among six sampling sites (P < 0.05). The different intensity of agricultural activities disturbance at the sampling sites was the important reason for the spatial variations of DON deposition. DON deposition was significantly correlated with ammonium nitrogen (NH4+-N) deposition (P < 0.05). According to the results of positive matrix factorization (PMF) model, agriculture source contributed significantly to the DON deposition, the contributions at six sampling sites ranged from 45.8% to 73.7% in dry deposition, and from 56.8% to 81.6% in wet deposition. In summary, our findings found that agricultural activities were the important factors influencing the spatial patterns of DON deposition around Danjiangkou Reservoir and provided new evidence for the anthropogenic source of DON deposition in China.

Manganese oxide-loaded activated carbon for ammonium removal from wastewater: the roles of adsorption and oxidation.

The urgent need to address the severe issue of nitrogen pollution has prompted the search for a functional and easy recycling material. In this study, manganese oxides (MnOx) were loaded on activated carbon (AC), resulting in a composite known as AC-MnOx, for efficient ammonium removal from aqueous solutions. The results indicated a remarkable 15.6-fold increase in ammonium removal efficiency and a fivefold enhancement in removal capacity for AC-MnOx (3.20 mg/g) compared to AC. Under specific conditions (initial NH4+-N concentration of 15 mg/L, adsorbent dose of 2.5 g, pH of 6.5, and temperature of 35 ℃), the highest achieved ammonium removal efficiency reached 94.6%. Furthermore, the study distinguishes the contributions of catalytic oxidation and adsorption in the removal process. The adsorption process was effectively modeled using pseudo-second-order kinetics and Langmuir isotherm models. Interestingly, the amount of oxidation conversion (Ntur) exhibited a linear relationship with the dosage when the initial ammonium concentration was sufficiently high, while the relationship between initial ammonium concentration and the ratio of Ntur to adsorption capacity (Nsur) followed a negative exponential trend. The removal mechanisms involved electrostatic interaction between ammonium and the negatively charged dehydrogenated hydroxyl groups (- OHsur) or cation tunnel in crystal structures of MnOx, ion exchange adsorption, and the oxidation impact of MnOx. This research provides valuable insights into the application of immobilized MnOx media for ammonium removal. Moreover, filling AC-MnOx into constructed wetlands (CW) proved to be an effective method for reducing ammonium pollution, demonstrating its potential in the field of engineering wastewater treatment.

Revisiting the dynamics of gaseous ammonia and ammonium aerosols during the COVID-19 lockdown in urban Beijing using machine learning models.

The concentration of atmospheric ammonia (NH3) in urban Beijing substantially decreased during the COVID-19 lockdown (24 January to 3 March 2020), likely due to the reduced human activities. However, quantifying the impact of anthropogenic interventions on NH3 dynamics is challenging, as both meteorology and chemistry mask the real changes in observed NH3 concentrations. Here, we applied machine learning techniques based on random forest models to decouple the impacts of meteorology and emission changes on the gaseous NH3 and ammonium aerosol (NH4+) concentrations in Beijing during the lockdown. Our results showed that the meteorological conditions were unfavorable during the lockdown and tended to cause an increase of 8.4 % in the NH3 concentration. In addition, significant reductions in NOx and SO2 emissions could also elevate NH3 concentrations by favoring NH3 gas-phase partitioning. However, the observed NH3 concentration significantly decreased by 35.9 % during the lockdown, indicating a significant reduction in emissions or enhanced chemical sinks. Rapid gas-to-particle conversion was indeed found during the lockdown. Thus, the observed reduced NH3 concentrations could be partially explained by the enhanced transformation into NH4+. Therefore, the sum of NH3 and NH4+ (collectively, NHx) is a more reliable tracer than NH3 or NH4+ alone to estimate the changes in NH3 emissions. Compared to that under the scenario without lockdowns, the NHx concentration decreased by 26.4 %. We considered that this decrease represents the real decrease in NH3 emissions in Beijing due to the lockdown measures, which was less of a decrease than that based on NH3 only (35.9 %). This study highlights the importance of considering chemical sinks in the atmosphere when applying machine learning techniques to link the concentrations of reactive species with their emissions.

Effective abatement of ammonium and nitrate release from sediments by biochar coverage.

Inorganic forms of N from sediments and runoff water, among others, remain some of the key sources of pollution of water bodies. However, the release of NH4+-N from sediment to water can be effectively reduced by biochar coverage due to high adsorption capacity, unlike NO3-N, where biochar has a low affinity. The feasibility of biochar coverage to abate NO3--N release needs to be evaluated. This study collected four sediments from Lake Taihu (China). Three types of biochar pyrolyzed from ordinary wastes, coconut shell (coBC), algal and excess sludge, were prepared to cover them and were incubated for 90 days. Results showed that the terminal total nitrogen (TN) and NO3--N concentrations decreased from 5.35 to 2.31-3.04 mg/L, 3.05 to 0.34-1.11 mg/L, respectively. CoBC coverage showed the best performance for reducing NO3--N release flux from 26.99 ± 0.19 to 9.30 ± 0.02 mg/m2·d (63.6 %). Potential denitrifiers, such as Flavobacterium and Exiguobacterium, were enriched in the biochar-coverage layer, and the absolute abundance of N-related functional genes (narG, nirS, nosZ and anammox) was increased by 1.76-4.21 times (p < 0.05). Jar tests by 15N isotope labeling further indicated that biochar addition increased the denitrification and anammox rates by 53.5-83.4 %. Experiments combining exogenous organic­carbon addition and 15N labeling demonstrated that biochar's key role was regulating organic matter's bioavailability. Analysis with partial least square path modeling (PLS-PM) implied biochar with higher adsorption enhanced the denitrification and anammox processes in sediments via modifying the niche with suitable DOC, TN, and pH. This study suggested that biochar coverage could effectively abate NO3--N release from sediments by affecting the denitrification and anammox processes.

The performance and mechanism of tetracycline and ammonium removal by Pseudomonas sp. DX-21.

To remove ammonium and tetracycline (TC) from wastewater, a new strain, DX-21, was isolated and exhibited simultaneous removal ability. The performance of DX-21 in TC removal, its removal mechanism, and the potential toxicities of the degradation products were investigated with genomics, mass spectrometry, density functional theory calculations, quantitative structure-activity relationship analyses, and Escherichia coli exposure experiments. DX-21 exhibited removal of ammonium (9.64 mg·L-1·h-1) via assimilation, and TC removal (0.85 mg·L-1·h-1) primarily occurred through cell surface bio-adsorption and biodegradation. Among the 12 identified degradation products, the majority exhibited lower toxicities than TC. Moreover, potential degradation pathways were proposed, including hydroxylation and deamination. Furthermore, DX-21 possessed TC resistance genes, various oxygenases and peroxidases that could potentially contribute to TC degradation. DX-21 colonized activated sludge and significantly enhanced the biodegradation of TC. Therefore, DX-21 showed potential for treating wastewater containing both ammonium and TC.

From Soil to River: Revealing the Mechanisms Underlying the High Riverine Nitrate Levels in a Forest Dominated Catchment.

Elevated riverine nitrate (NO3-) levels have led to increased eutrophication and other ecological implications. While high riverine NO3- levels were generally ascribed to anthropogenic activities, high NO3- levels in some pristine or minimally disturbed rivers were reported. The drivers of these unexpectedly high NO3- levels remain unclear. This study combined natural abundance isotopes, 15N-labeling techniques, and molecular techniques to reveal the processes driving the high NO3- levels in a sparsely populated forest river. The natural abundance isotopes revealed that the NO3- was mainly from soil sources and that NO3- removal processes were insignificant. The 15N-labeling experiments also quantitatively showed that the biological NO3- removal processes, i.e., denitrification, dissimilatory NO3- reduction to ammonium (DNRA), and anaerobic ammonia oxidation (anammox), in the soils and sediments were weak relative to nitrification in summer. While nitrification was minor in winter, the NO3- removal was insignificant relative to the large NO3- stock in the catchment. Stepwise multiple regression analyses and structural equation models revealed that in summer, nitrification in the soils was regulated by the amoA-AOB gene abundances and NH4+-N contents. Low temperature constrained nitrification in winter. Denitrification was largely controlled by moisture content in both seasons, and anammox and DNRA could be explained by the competition with nitrification and denitrification on their substrate (nitrite-NO2-). We also revealed the strong hydrological control on the transport of soil NO3- to the river. This study effectively revealed the mechanisms underlying the high NO3- levels in a nearly pristine river, which has implications for the understanding of riverine NO3- levels worldwide.

Multi-parameter control-based operation strategy for mainstream deammonification in an integrated anaerobic biofilm reactor-step feed MBR.

The mainstream deammonification of municipal wastewater has been recognized as one of the greatest challenges in wastewater engineering. The conventional activated sludge process has disadvantages of high energy input and sludge production. To tackle this situation, an innovative A-B process, where an anaerobic biofilm reactor (AnBR) functioned as the A stage for energy recovery, and a step-feed membrane bioreactor (MBR) functioned as the B stage for mainstream deammonification, was constructed for carbon-neutral wastewater treatment. For addressing the challenge associated with selective retention of ammonia-oxidizing bacteria (AOB) over nitrite oxidizing bacteria (NOB), a multi-parameter control-based operation strategy was developed with synergistic control of influent COD redistribution, dissolved oxygen (DO) concentration and sludge retention time (SRT) in the innovative AnBR - step-feed MBR system. Results showed that more than 85% of wastewater COD could be removed with the direct production of methane gas in the AnBR. A relatively stable partial nitritation, which is a prerequisite of anammox, was achieved with the successful suppression of NOB, leading to 98% of ammonium-N and 73% of total nitrogen removed. Anammox bacteria could well survive and enrich in the integrated system, and the contribution of anammox to the total nitrogen removal was more than 70% at optimal conditions. Reactions network involved in the nitrogen transformation in the integrated system was further constructed through the mass balance and microbial community structure analyses. Consequently, this study demonstrated a practically feasible process configuration with high operation and control flexibility towards stable mainstream deammonification of municipal wastewater.

Detection and removal technologies for ammonium and antibiotics in agricultural wastewater: Recent advances and prospective.

With the extensive development of industrial livestock and poultry production, a considerable part of agricultural wastewater containing tremendous ammonium and antibiotics have been indiscriminately released into the aquatic systems, causing serious harms to ecosystem and human health. In this review, ammonium detection technologies, including spectroscopy and fluorescence methods, and sensors were systematically summarized. Antibiotics analysis methodologies were critically reviewed, including chromatographic methods coupled with mass spectrometry, electrochemical sensors, fluorescence sensors, and biosensors. Current progress in remediation methods for ammonium removal were discussed and analyzed, including chemical precipitation, breakpoint chlorination, air stripping, reverse osmosis, adsorption, advanced oxidation processes (AOPs), and biological methods. Antibiotics removal approaches were comprehensively reviewed, including physical, AOPs, and biological processes. Furthermore, the simultaneous removal strategies for ammonium and antibiotics were reviewed and discussed, including physical adsorption processes, AOPs, biological processes. Finally, research gaps and the future perspectives were discussed. Through conducting comprehensive review, future research priorities include: (1) to improve the stabilities and adaptabilities of detection and analysis techniques for ammonium and antibiotics, (2) to develop innovative, efficient, and low cost approaches for simultaneous removal of ammonium and antibiotics, and (3) to explore the underlying mechanisms that governs the simultaneous removal of ammonium and antibiotics. This review could facilitate the evolution of innovative and efficient technologies for ammonium and antibiotics treatment in agricultural wastewater.

Wastewater management in Motor Rest Area - A review article.

Due to the constantly developing road network, a large number of new Motor Rest Area facilities are being built. The aim of the work is a critical assessment of the current wastewater management in the MRA and the proposal of appropriate solutions capable of purifying wastewater. The analysis of the current state of the MRA facilities was carried out on the basis of maps, own observations and an assessment of interest in the subject recently by reviewing publication resources. For this purpose, analyzes of the frequency of occurrence of keywords describing the issue were used. The solutions used so far are ineffective. This is mainly due to the perception of wastewater produced in MRA facilities as domestic wastewater. This assumption leads to the selection of inappropriate solutions, which in the long run can lead to an ecological disaster by introducing untreated sewage into the environment. The authors point to the possibility of introducing a circular economy in these places to relieve their environmental impact. Since, wastewater generated in MRA facilities, due to its specificity, is very difficult to treat. They are characterized by uneven inflow, a lack of organic matter, a low C:N ratio and very high concentration of ammonium nitrogen. Conventional activated sludge methods cannot cope with this. The need for changes and the use of solutions suitable for the treatment of wastewater with a high content of ammonium nitrogen has been demonstrated. The authors presented solutions that have the potential to be used in MRA facilities. The application of the proposed solutions from that moment will undoubtedly change the impact of MRA facilities on the environment and solve the problem of wastewater management on a large scale. There is still a lack of research on this thematic scope, which is a challenge authors have taken up.

Highly Stretchable and Robust Electrochemical Sensor Based on 3D Graphene Oxide-CNT Composite for Detecting Ammonium in Sweat.

Wearable electrochemical sensors have attracted tremendous attention and have been experiencing rapid growth in recent years. Sweat, one of the most suitable biological fluids for non-invasive monitoring, contains various chemical elements relating abundant information about human health conditions. In this work, a new type of non-invasive and highly stretchable potentiometric sweat sensor was developed based on all-solid-state ion-selective electrode (ISE) coupled with poly(dimethylsiloxane; PDMS) and polyurethane (PU). This highly stretchable composite of PDMS-PU allows the sensor to be robust, with the PDMS providing a flexible backbone and the PU enhancing the adhesion between the electrodes and the substrate. In addition, graphene-carbon nanotube (CNT) network 3D nanomaterials were introduced to modify the ion selective membrane (ISM) in order to increase the charge transfer activity of the ISEs, which also could minimize the formation of water layers on the electrode surface, as such nanomaterials are highly hydrophobic. As a result, the sensor demonstrated a wide detection range of NH4+ from 10-6 M to 10-1 M with high stability and sensitivity-showing a high sensitivity of 59.6 ± 1.5 mV/log [NH4+] and an LOD lower than 10-6 M. Under a strain of 40%, the sensor still showed a sensitivity of 42.7 ± 3.1 mV/log [NH4+]. The proposed highly stretchable and robust electrochemical sweat sensor provides a new choice for wearable-device-based personal daily healthcare management beyond hospital-centric healthcare monitoring.

Paleo-Geomorphology Determines Spatial Variability of Geogenic Ammonium Concentration in Quaternary Aquifers.

Naturally occurring (i.e., geogenic) ammonium in groundwater has been widely detected globally, but the major controls on its regional distribution have been poorly characterized. Here, we identified the dominant role of paleo-geomorphology driven by paleo-climate in controlling the spatial variability of geogenic ammonium in groundwater using random forest algorithm and revealed the underlying mechanisms based on borehole sediment analysis of data obtained from the Dongting Lake Plain of the central Yangtze River basins in China. In the paleo-channel (PC) area, the aquifer depth-matched sediments were deposited during the last deglaciation when warm climate resulted in rapid filling into incised valleys, and terrestrial organic matter (OM) mainly as lignin experienced less degradation prior to sedimentation and had lower humification, higher N abundance, and nominal oxidation state of carbon (NOSC). In the paleo-interfluve (PI) area, the depth-matched sediments were deposited during the last glaciation, followed by intensive erosion in the surface during the last glacial maximum, and terrestrial OM mainly as lignin had been partly degraded into aliphatics prior to sedimentation and had higher humification, lower N abundance, and NOSC. As a result, under the present anaerobic conditions, less-humic and N-rich OM with more oxidized C tends to be more intensively mineralized into ammonium in the PC area than those in the PI area. These findings highlight the importance of paleo-geomorphology with paleo-climate in controlling the enrichment of geogenic ammonium in groundwater, which has a universal significance for understanding the genesis and distribution of high N loads in the aquatic environment worldwide.

Toward Energy Neutrality: Novel Wastewater Treatment Incorporating Acidophilic Ammonia Oxidation.

Chemically enhanced primary treatment (CEPT) followed by partial nitritation and anammox (PN/A) and anaerobic digestion (AD) is a promising roadmap to achieve energy-neutral wastewater treatment. However, the acidification of wastewater caused by ferric hydrolysis in CEPT and how to achieve stable suppression of nitrite-oxidizing bacteria (NOB) in PN/A challenge this paradigm in practice. This study proposes a novel wastewater treatment scheme to overcome these challenges. Results showed that, by dosing FeCl3 at 50 mg Fe/L, the CEPT process removed 61.8% of COD and 90.1% of phosphate and reduced the alkalinity as well. Feeding by low alkalinity wastewater, stable nitrite accumulation was achieved in an aerobic reactor operated at pH 4.35 aided by a novel acid-tolerant ammonium-oxidizing bacteria (AOB), namely, Candidatus Nitrosoglobus. After polishing in a following anoxic reactor (anammox), a satisfactory effluent, containing COD at 41.9 ± 11.2 mg/L, total nitrogen at 5.1 ± 1.8 mg N/L, and phosphate at 0.3 ± 0.2 mg P/L, was achieved. Moreover, the stable performances of this integration were well maintained at an operating temperature of 12 °C, and 10 investigated micropollutants were removed from the wastewater. An energy balance assessment indicated that the integrated system could achieve energy self-sufficiency in domestic wastewater treatment.

Global soil nitrogen cycle pattern and nitrogen enrichment effects: Tropical versus subtropical forests.

Tropical and subtropical forest biomes are a main hotspot for the global nitrogen (N) cycle. Yet, our understanding of global soil N cycle patterns and drivers and their response to N deposition in these biomes remains elusive. By a meta-analysis of 2426-single and 161-paired observations from 89 published 15 N pool dilution and tracing studies, we found that gross N mineralization (GNM), immobilization of ammonium ( I NH 4 ) and nitrate ( I NO 3 ), and dissimilatory nitrate reduction to ammonium (DNRA) were significantly higher in tropical forests than in subtropical forests. Soil N cycle was conservative in tropical forests with ratios of gross nitrification (GN) to I NH 4 (GN/ I NH 4 ) and of soil nitrate to ammonium (NO3 - /NH4 + ) less than one, but was leaky in subtropical forests with GN/ I NH 4 and NO3 - /NH4 + higher than one. Soil NH4 + dynamics were mainly controlled by soil substrate (e.g., total N), but climatic factors (e.g., precipitation and/or temperature) were more important in controlling soil NO3 - dynamics. Soil texture played a role, as GNM and I NH 4 were positively correlated with silt and clay contents, while I NO 3 and DNRA were positively correlated with sand and clay contents, respectively. The soil N cycle was more sensitive to N deposition in tropical forests than in subtropical forests. Nitrogen deposition leads to a leaky N cycle in tropical forests, as evidenced by the increase in GN/ I NH 4 , NO3 - /NH4 + , and nitrous oxide emissions and the decrease in I NO 3 and DNRA, mainly due to the decrease in soil microbial biomass and pH. Dominant tree species can also influence soil N cycle pattern, which has changed from conservative in deciduous forests to leaky in coniferous forests. We provide global evidence that tropical, but not subtropical, forests are characterized by soil N dynamics sustaining N availability and that N deposition inhibits soil N retention and stimulates N losses in these biomes.

Optimization of a compact on-site stormwater runoff treatment system: Process performance and reactor design.

Stormwater runoff has become a major anthropogenic urban pollution source that threatens water quality. In this study, coagulation-sedimentation, and ammonium ion exchange and regeneration (AIR) modules were coupled as a CAIR system to efficiently treat stormwater runoff. In the coagulation module, 99.3%, 91.7%, and 97.0% of turbidity, total phosphorus, and chemical oxygen demand could be removed at an optimized poly-aluminum ferric chloride dosage of 30 mg/L, and the continuous experiment confirmed that the full load mode was more suitable for its rapid start-up. In the AIR module, dynamic ammonium removal indicated that the breakthrough time decreased with the rising initial concentration and superficial velocity. The Modified Dose Response (MDR) model described the ammonium exchange behavior better than the Thomas and the Bohart-Adams models. Then, a design flow of the ion exchange reactor was constructed by correlating constants in the MDR model with engineering parameters, and the ion exchange reactor was designed for continuous operation of the CAIR system. The average concentrations of chemical oxygen demand, total phosphorus, ammonium nitrogen, and total nitrogen in the effluent of the CAIR system were 7.22 ± 2.26, 0.17 ± 0.05, 1.49 ± 0.01, and 1.62 ± 0.02 mg/L, respectively. The almost unchanged exchange capacity and physicochemical properties after the multicycle operation confirmed the durability of zeolite for ion exchange. Techno-economic analysis suggested that the CAIR system is practically promising for stormwater management with efficient pollutants removal, small footprint, and acceptable operating cost.

Tracking anthropogenic nitrogen-compound sources of surface and groundwater in southwestern Nile Delta: hydrochemical, environmental isotopes, and modeling approach.

This research aims to assign the specific and potential sources that control migration and transformation mechanisms of ammonium/nitrate contaminants of surface and groundwater systems in the southwestern Nile Delta, Egypt. To achieve that, an integration of hydrogeochemistry, multiple environmental stable isotopes (δ2H-H2O, δ18O-H2O, δ15N-NH4, and δ15N-NO3) coupled with three-dimensional nitrogen transport numerical model (MODFLOW-MT3D) was done. A set of representative water samples (20 canals and drainage water) and 14 groundwater samples were collected and analyzed for physical, chemical, and stable isotope analysis. NH4+ and NO3- concentrations in surface water samples varied from 0.29 to 124 mg/l and 0.52 to 39.67 mg/l, respectively. For groundwater samples, NH4+ and NO3- concentrations varied from 0.21 to 1.75 mg/l and 0.33 to 32.8 mg/l, respectively. Total risk quotient (THQ) level of nitrate (oral and dermal effects) from drinking water exceeds unity for all water samples indicating a potential noncancer risk for the southwestern Nile Delta residents. The potential sources of nitrogen compound pollution are water from sewage treatment plants used for irrigation, sludge and animal manure, septic tanks, soil nitrogen, and artificial fertilizers according to results of δ15N values. Results of ammonium/nitrate modeling in shallow groundwater aquifers are compared with observed concentrations and are found to be in good agreement. Some recommendations are given to decrease nitrogen loads in the study area through suggested a need for adoption of N-fertilizer management practices and treatment of sewage water before to application in agricultural activities.