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Carbohydr Polym ; 98(2): 1311-6, 2013 Nov 06.
Artículo en Inglés | MEDLINE | ID: mdl-24053808

RESUMEN

Cyclodextrin glycosyltransferase (CGTase) from Thermoanaerobacter sp. was covalently immobilized on glutaraldehyde-activated chitosan spheres and used in a packed bed reactor to investigate the continuous production of ß-cyclodextrin (ß-CD). The optimum temperatures were 75 °C and 85 °C at pH 6.0, respectively for free and immobilized CGTase, and the optimum pH (5.0) was the same for both at 60 °C. In the reactor, the effects of flow rate and substrate concentration in the ß-CD production were evaluated. The optimum substrate concentration was 4% (w/v), maximizing the ß-CD production (1.32 g/L) in a flow rate of 3 mL/min. In addition, the biocatalyst had good operational stability at 60 °C, maintaining 61% of its initial activity after 100 cycles of batch and 100% after 100 h of continuous use. These results suggest the possibility of using this immobilized biocatalyst in continuous production of CDs.


Asunto(s)
Proteínas Bacterianas/química , Enzimas Inmovilizadas/química , Glucosiltransferasas/química , Almidón/química , beta-Ciclodextrinas/síntesis química , Biocatálisis , Quitosano/química , Glutaral/química , Concentración de Iones de Hidrógeno , Cinética , Temperatura , Thermoanaerobacter/química , Thermoanaerobacter/enzimología
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