Photocatalytic synthesis of hydrogen peroxide (H2O2) from O2 and H2O under near-infrared light is a sustainable renewable energy production strategy, but challenging reaction. The bottleneck of this reaction lies in the regulation of O2 reduction path by photocatalyst. Herein, the center of the one-step two-electron reduction (OSR) pathway of O2 for H2O2 evolution via the formation of the hydroxyl-bonded Co single-atom sites on boroncarbonitride surface (BCN-OH2/Co1) is constructed. The experimental and theoretical prediction results confirm that the hydroxyl group on the surface and the electronic band structure of BCN-OH2/Co1 are the key factor in regulating the O2 reduction pathway. In addition, the hydroxyl-bonded Co single-atom sites can further enrich O2 molecules with more electrons, which can avoid the one-electron reduction of O2 to â¢O2 -, thus promoting the direct two-electron activation hydrogenation of O2. Consequently, BCN-OH2/Co1 exhibits a high H2O2 evolution apparent quantum efficiency of 0.8% at 850 nm, better than most of the previously reported photocatalysts. This study reveals an important reaction pathway for the generation of H2O2, emphasizing that precise control of the active site structure of the photocatalyst is essential for achieving efficient conversion of solar-to-chemical.
OBJECTIVE: To translate the Stressors in Breast Cancer Scale (SBCS) from English to Chinese and assess its psychometric properties. METHODS: The Brislin's translation model was applied to perform forward translation, back translation, cross-cultural adaptation, Whereas the Chinese version of the SBCS was formed by conducting pre-testing. A cohort of 878 breast cancer patients participated in this methodological study. Content validity, construct validity, convergent validity, discriminant validity, and criterion-related validity were used to establish validity. Internal consistency reliability, split-half reliability, and test-retest reliability were used to establish reliability. RESULTS: The final scale contained five dimensions and 24 items, including interpersonal relationship and healthcare strains, worries and concerns about the future, physical appearance and sex strains, daily difficulties and health. The average content validity index of the scale was 0.975. The goodness-of-fit index (χ2/DF = 2.416, RMSEA = 0.057, GFI = 0.896, CFI = 0.947, IFI = 0.947, and TLI = 0.939) indicated that the model was well-fitted. The composite reliability (CR) of the dimensions ranged from 0.825 to 0.934, the average variance extracted (AVE) ranged from 0.539 to 0.712, and the correlation coefficients of each dimension with the other dimensions were less than the square root of the AVE for that dimension. The Criterion-related validity was 0.511. The Cronbach's alpha was 0.938, and the dimensions ranged from 0.779 to 0.900. Split-half reliability was 0.853, with dimensions ranging from 0.761 to 0.892. Test-retest reliability was 0.855. CONCLUSIONS: The Chinese version of the SBCS has good reliability and validity, which can be applied to the assessment of stressors in breast cancer patients in China.
Asian People , Breast Neoplasms , Psychometrics , Female , Humans , Asian People/psychology , Breast Neoplasms/diagnosis , Breast Neoplasms/psychology , China , Reproducibility of Results , Surveys and Questionnaires , Translating , Stress, Psychological/diagnosis
The grinding method is used as the preliminary processing procedure for small aperture aspheric mirrors. Regular grinding marks produced in the grinding process significantly affect the mid-spatial frequency error; however, because of their small radius of surface curvatures and high steepness, they are difficult to polish using traditional methods. Therefore, in this study, the ultra-precision grinding and polishing process of fused quartz material was investigated, and the influence of grinding marks was analyzed, which achieved the purpose of restraining the grinding marks in the grinding process. The generation mechanisms of horizontal and vertical grinding marks were analyzed by means of simulation and experiment, and the relationship between different grinding process parameters and surface quality was explored. A magnetorheological finishing (MRF) spot method was used to explore the effects of grinding marks on subsurface damage (SSD). The elastic adaptive polishing method was used to polish an aspheric lens with high steepness and small caliber. Based on the principle of an elastic adaptive polishing mathematical model, the grinding marks were suppressed, and the mid-spatial frequency error of the lens was reduced by optimizing the polishing path and composition of the polishing fluid. The final roughness reached 10 nm Ra. In this paper, the source of wear marks and their influence on the mid-spatial frequency error of small aperture aspheric mirrors are analyzed, and the grinding marks were suppressed by elastic adaptive polishing.
In anurans, the complexity of courtship calls may affect female mate choice. The current study suggests that nonlinear phenomena (NLP) components can contribute to increasing complexity in courtship calls and attracting female attention. The results of a recent study showed that calls of large odorous frog (Odorrana graminea) contained NLP components. However, whether the nonlinear components of courtship calls in O. graminea improve male attractiveness remains unknown. We hypothesized that female O. graminea would prefer males producing calls with a higher proportion of NLP components (P-NLP-C). To test this hypothesis, we recorded the advertisement calls of 28 males and confirmed that the P-NLP-C was significantly positively related to body size. We also measured the body size of natural amplectant males and non-amplectant males in the field and found that amplectant males had larger body sizes than non-amplectant males, and the results of two-choice amplexus experiments similarly revealed a female preference for males with larger body sizes. Additionally, phonotaxis experiments also revealed that females preferred male calls with a high P-NLP-C. The results suggest that a higher P-NLP-C in calls can enhance male attractiveness, and the P-NLP-C may provide key information about male body conditions for female O. graminea. Our study provides a new insight for better understanding the role of NLP in anuran mate selection.
