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Angew Chem Int Ed Engl ; 48(8): 1447-51, 2009.
Article in English | MEDLINE | ID: mdl-19145614

ABSTRACT

Shall we dance? Within the proposed mechanism for the palladium-catalyzed title reaction, the strained alkene norbornene (or norbornadiene) enters and exits the catalytic cycle in a catalytic "square dance", acting as both a promoter and a coupling partner in the formation of four carbon-carbon bonds, two of them by challenging C--H activation processes.


Subject(s)
Alkenes/chemical synthesis , Norbornanes/chemical synthesis , Alkenes/chemistry , Carbon/chemistry , Catalysis , Hydrogen/chemistry , Norbornanes/chemistry , Palladium/chemistry
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