Assessment of water resources for livestock in the Wilaya of Naama, Southwest Algeria: a GIS-based approach.

This study employs Geographic Information Systems (GIS) tools and spatial data to evaluate water resource availability for livestock watering in Algeria's southwestern Wilaya of Naama. The research adopts a two-stage approach, starting with the creation of seven thematic maps encompassing livestock water needs, proximity to water sources, water quantities from boreholes, hillside reservoirs, wells, and springs, precipitation, and land use/land cover (LULC). Subsequently, an Analytic Hierarchy Process (AHP) is utilized to identify suitable areas within the Wilaya for livestock watering. Beyond its primary objective of establishing a benchmark for water resources to facilitate optimal and sustainable livestock management, this study also aims to assess suitable sites for livestock and provide a comprehensive evaluation of water resources for grazing. The findings reveal that the majority of the area is unsuitable for grazing due to limited water resources, with approximately 2.43% being "highly suitable" (S1), 13.42% "moderately suitable" (S2), and the remaining 84.15% categorized as "marginally suitable" (S3), "temporarily unsuitable" (N1), or "permanently unsuitable" (N2). These results underscore the significance of GIS and spatial analysis in natural resource management and emphasize the need for further research to refine the methodology. The data generated in this study will be invaluable to researchers and water stakeholders for informed decision-making in this sensitive zone.

Multifunctional polysaccharide structure as green adsorbent for efficient removal and preconcentration of chlorophenols from the aqueous medium: experimental and modeling approaches.

The growing concerns about water pollution have prompted researchers to explore new materials for remediating and purifying it. In recent years, there has been a focus on polysaccharides as eco-friendly polymers that exhibit high efficiency in removing chlorophenols from waste water. This study aims to develop a trifunctional polysaccharide structure using a biodegradable matrix. The chitosan/alginate-polyethyleneimine-phenyl-phosphonamidic acid (CHIT/ALG-PEIPPAA) matrix was employed for removing chlorophenols from water. The study carefully examined the impact of various physicochemical parameters such as pH, reaction time, chlorophenols concentration, temperature, and ionic strength to determine the optimal conditions for the adsorption process. Several techniques were used to confirm the morphology, physicochemical properties, structure, and functionalization of the polymer. Scanning electron microscopy (SEM) images revealed a heterogeneous morphology with agglomerates of different particle sizes, ranging from a few micrometers with irregular shapes. The FTIR spectrum and zeta potential characterization indicated the presence of hydrophilic groups and a highly positive charge (around 31.4 mV) on the surface of the CHIT/ALG-PEIPPAA adsorbent. The optimal pH for chlorophenols removal was found to be approximately 4.4. The kinetic data supported the pseudo-second-order kinetic model, which accurately described the adsorption behavior of both chlorophenol molecules. The fitting of the isotherm analysis revealed that the Langmuir model provided a better representation of the adsorption process. The maximum adsorption capacities for 4-chlorophenol and 2,4-chlorophenol were approximately 118 mg.g-1 and 249 mg.g-1, respectively. The calculated thermodynamic functions confirmed an exothermic and spontaneous adsorption process for chlorophenols, with ∆H values of -6.98 kJ.mol-1 and -2.74 kJ.mol-1 for 4-chlorophenol and 2,4-chlorophenol, respectively. The regeneration process of the CHIT/ALG-PEIPPAA adsorbent showed higher efficacy in the presence of hydrochloric acid (2.0 mol.L-1), resulting in up to 91% desorption of chlorophenols. The CHIT/ALG-PEIPPAA adsorbent demonstrated good reusability after regeneration, with only a slight decrease in extraction efficiency: 34.63% for 4-chlorophenol and 79.03% for 2,4-chlorophenol, under the same optimal conditions as the initial adsorption cycle.