Multifunctional polysaccharide structure as green adsorbent for efficient removal and preconcentration of chlorophenols from the aqueous medium: experimental and modeling approaches.

The growing concerns about water pollution have prompted researchers to explore new materials for remediating and purifying it. In recent years, there has been a focus on polysaccharides as eco-friendly polymers that exhibit high efficiency in removing chlorophenols from waste water. This study aims to develop a trifunctional polysaccharide structure using a biodegradable matrix. The chitosan/alginate-polyethyleneimine-phenyl-phosphonamidic acid (CHIT/ALG-PEIPPAA) matrix was employed for removing chlorophenols from water. The study carefully examined the impact of various physicochemical parameters such as pH, reaction time, chlorophenols concentration, temperature, and ionic strength to determine the optimal conditions for the adsorption process. Several techniques were used to confirm the morphology, physicochemical properties, structure, and functionalization of the polymer. Scanning electron microscopy (SEM) images revealed a heterogeneous morphology with agglomerates of different particle sizes, ranging from a few micrometers with irregular shapes. The FTIR spectrum and zeta potential characterization indicated the presence of hydrophilic groups and a highly positive charge (around 31.4 mV) on the surface of the CHIT/ALG-PEIPPAA adsorbent. The optimal pH for chlorophenols removal was found to be approximately 4.4. The kinetic data supported the pseudo-second-order kinetic model, which accurately described the adsorption behavior of both chlorophenol molecules. The fitting of the isotherm analysis revealed that the Langmuir model provided a better representation of the adsorption process. The maximum adsorption capacities for 4-chlorophenol and 2,4-chlorophenol were approximately 118 mg.g-1 and 249 mg.g-1, respectively. The calculated thermodynamic functions confirmed an exothermic and spontaneous adsorption process for chlorophenols, with ∆H values of -6.98 kJ.mol-1 and -2.74 kJ.mol-1 for 4-chlorophenol and 2,4-chlorophenol, respectively. The regeneration process of the CHIT/ALG-PEIPPAA adsorbent showed higher efficacy in the presence of hydrochloric acid (2.0 mol.L-1), resulting in up to 91% desorption of chlorophenols. The CHIT/ALG-PEIPPAA adsorbent demonstrated good reusability after regeneration, with only a slight decrease in extraction efficiency: 34.63% for 4-chlorophenol and 79.03% for 2,4-chlorophenol, under the same optimal conditions as the initial adsorption cycle.

A new alternative of a green polymeric matrix chitosan/alginate-polyethyleniminemethylene phosphonic acid for pharmaceutical residues adsorption.

A new generation of a green polymeric matrix, chitosan/alginate-polyethyleniminemethylene phosphonic acid (CHIT/ALG-PEIMPA) was examined in comparative study of adsorption and preconcentration of non-steroidal anti-inflammatory drugs (NSAIDs), diclofenac and ibuprofen. The influences of experimental parameters like pH, time reaction, initial concentration, ionic strength were investigated. The scanning electron microscopy (SEM) images showed heterogeneous morphology with different particle sizes of agglomerates from few micrometers to a hundred micrometers and irregular particles shape, before pharmaceuticals products adsorption. However, after adsorption, SEM micrograph reveals a smooth surface structure of agglomerate, and even in this smaller magnification, it was possible to observe the formation of homogenous and regular surface of CHIT/ALG-PEIMPA. Elementary analysis (EDX) reveals that the phosphonic acid (PEIMPA) was successfully cross-linked onto chitosan/alginate. The maximal adsorption capacity was found to be 222 mg.g-1, and 122 mg.g-1 under optimum conditions for diclofenac and ibuprofen respectively. The kinetic modeling followed the pseudo-second-order rate expression for both pharmaceutical drugs. Thermodynamics data leads to an exothermic and spontaneous adsorption processes (∆H = -34.32 KJ mol-1; ∆H =-21.59 KJ mol-1), respectively for diclofenac and ibuprofen.

Comparative study of mercury(II) species removal onto naked and modified magnetic chitosan flakes coated ethylenediaminetetraacetic-disodium: kinetic and thermodynamic modeling.

This comparative study investigates pre-concentration/separation procedure for the magnetic solid phase extraction of Hg(II) species by a new green materials: naked magnetic chitosan flakes coated Fe3O4 micro-particles (NMCFs) and magnetic chitosan flakes coated Fe3O4 micro-particles embedded ethylenediaminetetraacetic-disodium (MCFs-EDTA-Na2) in a batch process. The sorption procedure was optimized by using model solutions containing mercury(II) ions in chloride medium. The influence of experimental parameters like pH, time reaction, initial Hg(II) concentration, and ionic strength was investigated. The SEM micrograph indicates a good dispersion of magnetite micro-particles onto chitosan flakes. The FTIR spectrum reveals that EDTA-Na2 moieties have been successfully cross-linked onto magnetic chitosan flakes. Vibration magneto-metric measurements confirm the paramagnetic (without remanence) behavior of NMCFs and MCFs-EDTA-Na2. The experimental sorption data show that Hg(II) ions extraction yield decreases in acidic medium in both NMCFs and MCFs-EDTA-Na2. The found optimum pH values are near 4.5 using NMCFs and 4.7 when the Hg(II) ion sorption occurs onto MCFs-EDTA-Na2 micro-particles. The results also showed that Hg(II) ion sorption kinetic was very fast at the initial stage of contact time. The maximal sorption capacity was found to be 454 ± 13 mg g-1, under optimum conditions, using NMCFs and 495 ± 14 mg g-1 when MCFs-EDTA-Na2 was used.