Multifunctionalized Supramolecular Cyclodextrin Additives Boosting the Durability of Aqueous Zinc-Ion Batteries.

The poor cycling stability of aqueous zinc-ion batteries hinders their application in large-scale energy storage due to uncontrollable dendrite growth and harmful hydrogen evolution reactions. Here, we designed and synthesized an electrolyte additive, N-methylimidazolium-ß-cyclodextrin p-toluenesulfonate (NMI-CDOTS). The cations of NMI-CD+ are more easily adsorbed on the abrupt Zn surface to regulate the deposition of Zn2+ and reduce dendrite generation under the combined action of the unique cavity structure with abundant hydroxyl groups and the electrostatic force. Meanwhile, p-toluenesulfonate (OTS-) is able to change the Zn2+ solvation structure and suppress the hydrogen evolution reaction by the strong interaction of Zn2+ and OTS-. Benefiting from the synergistic role of NMI-CD+ and OTS-, the Zn||Zn symmetric cell exhibits superior cycling performance as high as 3800 h under 1 mA cm-2 and 1 mA h cm-2. The Zn||V2O5 full battery also shows a high specific capacity (198.3 mA h g-1) under 2.0 A g-1 even after 1500 cycles, and its Coulomb efficiency is nearly 100% during the charging and discharging procedure. These multifunctional composite strategies open up possibilities for the commercial application of aqueous zinc-ion batteries.

Seawater toilet flushing sewage treatment and nutrients recovery by marine bacterial-algal mutualistic system.

Seawater toilet flushing sewage with excess eutrophic and high salinity brought a great barrier on the municipal wastewater treatment plants. Nutrients recovery and biomass production as potential biofuel feedstock with less energy consumption will be a key challenge in wastewater treatment. In the optimal inoculation of algae and bacteria, a marine bacterial-algal mutualistic system was established to treat synthetic seawater toilet flushing sewage without extra carbon and O2 addition. It was showed that 85.5% of total nitrogen (TN) (from 200 mg/L), 91.0% of total phosphorus (TP) (from 40 mg/L) and 98.7% of chemical oxygen demand (COD) (from 1600 mg/L) were removed with 4.28 g/L of biomass yield (biomass productivity 159.3 mg/L/d) containing 16.3% lipid and 62.6% protein, which performance mainly achieved by bacteria during first six days and algae functioned subsequently. Both nitrogen and phosphorus removal of the system were mainly assimilation/accumulation. Algal facultative heterotrophia ensured dissolved organic carbon for bacterial utilization and avoiding excessive organic matter produced. The established algal-bacterial system provided a potential energy-efficient and eco-friendly approach for seawater blackwater treatment and nutrients recovery simultaneously.

Nutrients removal and recovery from saline wastewater by Spirulina platensis.

As an important alternative to alleviate the pressure of fresh water shortage, seawater application is facing a great challenge on the wastewater treatment due to the salinity brought from seawater. Spirulina platensis originated from salty lake was used to treat mixed synthetic toilet flushing wastewater of seawater with washing wastewater of freshwater. It was showed that 79.96% of TN (to 15.69mg/L), 93.35% of TP (to 1.03mg/L) and 90.02% of CODCr (to 90.24mg/L) were removed with 0.76g/L of biomass production in the optimal ratio 7:3 of the above mixed synthetic wastewater. The performance was better than that of current strategy of seawater toilet flushing treatment. With the evaluation of nutrients uptake, biomass composition and microalgal aggregation, a model of nutrients recovery and metabolism of Spirulina platensis in saline wastewater treatment was proposed. It is provided a promising strategy for saline wastewater treatment with valuable biomass yield.

Aerobic-heterotrophic nitrogen removal through nitrate reduction and ammonium assimilation by marine bacterium Vibrio sp. Y1-5.

An aerobic marine bacterium Vibrio sp. Y1-5 was screened to achieve efficient nitrate and ammonium removal simultaneously and fix nitrogen in cells without N loss. Approximately 98.0% of nitrate (100mg/L) was removed in 48h through assimilatory nitrate reduction and nitrate reductase was detected in the cytoplasm. Instead of nitrification, the strain assimilated ammonium directly, and it could tolerate as high as 1600mg/L ammonium concentration while removing 844.6mg/L. In addition, ammonium assimilation occurred preferentially in the medium containing nitrate and ammonium with a total nitrogen (TN) removal efficiency of 80.4%. The results of nitrogen balance and Fourier infrared spectra illustrated that the removed nitrogen was all transformed to protein or stored as organic nitrogen substances in cells and no N was lost in the process. Toxicological studies with the brine shrimp species Artemia naupliia indicated that Vibrio sp. Y1-5 can be applied in aquatic ecosystems safely.