ABSTRACT
This study explored the alteration of naturally occurring radioactive materials (NORMs: 226Ra (≈238U), 232Th, 40K) in an anthropogenically disrupted urban river-basin (Turag, Bangladesh) in terms of constitutional substances (Sc, Ti, V, Fe, La, Ce, Sm, Eu, Tb, Dy, Ho, Yb, Lu, Hf, Ta, W, Th, U) of heavy-minerals. Average activity concentrations of 226Ra (≈238U), 232Th, and 40K were 41.5 ± 12.9, 72.1 ± 27.1, and 639 ± 100 Bqkg-1, respectively which were relatively higher compared to crustal origin. ∑REEs, Ta, W, Th, and U were ~2 times higher compared to crustal values with Ce and Eu-anomalies. APCS-MLR and PMF receptor models were used to determine the various anthropogenic and/or geogenic sources of NORMs and elements. Layer-wise variations of NORMs and elements were observed to trace the response of sedimentary processes towards the incoming pollution load. Presence of REEs indicates moderate degree of ecological risk to aquatic biota. However, carcinogenic risk (3.84 × 10-4 Sv-1) were significantly higher than threshold limit.
Subject(s)
Radiation Monitoring , Rivers , Rivers/chemistry , Risk Assessment , Bangladesh , Water Pollutants, Radioactive/analysis , Thorium/analysis , Minerals/analysis , Potassium Radioisotopes/analysis , RadiumABSTRACT
To investigate the interplay between varying anthropogenic activities and sediment dynamics in an urban river (Turag, Bangladesh), this study involved 37-sediment samples from 11 different sections of the river. Neutron activation analysis and atomic absorption spectrometry were utilized to quantify the concentrations of 14 metal(oid)s (Al, Ti, Co, Fe, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Zn). This study revealed significant toxic metal trends, with Principal coordinate analysis explaining 62.91 % of the variance from upstream to downstream. The largest RSDs for Zn(287 %), Mn(120 %), and Cd(323 %) implies an irregular regional distribution throughout the river. The UNMIX-model and PMF-model were utilized to identify potential sources of metal(oid)s in sediments. â¼63.65-66.7 % of metal(oid)s in sediments originated from anthropogenic sources, while remaining attributed to natural sources in both models. Strikingly, all measured metal(oid)s' concentrations surpassed the threshold effect level, with Zn and Ni exceeding probable effect levels when compared to SQGs.
Subject(s)
Environmental Monitoring , Geologic Sediments , Rivers , Water Pollutants, Chemical , Geologic Sediments/chemistry , Rivers/chemistry , Water Pollutants, Chemical/analysis , Bangladesh , Metals/analysis , Metals, Heavy/analysisABSTRACT
Naturally occurring radioactive materials (NORMs: 232Th, 226Ra, 40K) can reach our respiratory system by breathing of road dust which can cause severe health risks. Targeting the pioneering consideration of health risks from the NORMs in road dust, this work reveals the radioactivity abundances of NORMs in road dust from a megacity (Dhaka) of a developing country (Bangladesh). Bulk chemical compositions of U, Th, and K obtained from neutron activation analysis were converted to the equivalent radioactivities. Radioactivity concentrations of 226Ra, 232Th, and 40K in road dust ranged from 60-106, 110-159, and 488-709 Bq kg-1 with an average of 84.4 ± 13.1, 126 ± 11, and 549 ± 48 Bq kg-1, respectively. Estimated 226Ra, 232Th, and 40K radioactivities were, respectively, 1.7-3.0-, 3.7-5.3-, and 1.2-1.8-folds greater than the affiliated world average values. Mechanistic pathway of NORMs' enrichment and fractionation relative to the major origin (pedosphere) were evaluated concerning the water logging, relative solubility-controlled leaching and translocation, climatic conditions, and aerodynamic fractionations (dry and wet atmospheric depositions). Computation of customary radiological risk indices invokes health risks. Noticing the ingress of NOMR-holding dust into the human respiratory system along with the associated ionizing radiations, the computed radiological indices represent only the least probable health hazards. Nevertheless, in real situations, α-particles from the radioactive decay products of 232Th and 238U can create acute radiation damages of respiratory system. Policymakers should emphasize on limiting the dust particle evolution, and public awareness is required to alleviate the health risks.
Subject(s)
Radiation Monitoring , Radioactivity , Soil Pollutants, Radioactive , Humans , Dust/analysis , Bangladesh , Soil Pollutants, Radioactive/analysis , Thorium/analysisABSTRACT
Human beings are continuously bathed in radiation coming from natural and artificial sources. Although the use of radiation in medical applications is beneficial to patients, it also contributes significantly to the health hazard for radiation workers and the public if radiation-generating equipment and radioactive sources are not handled properly. 96% dose contributed from medical uses of ionizing radiation in the US population among man-made sources as per NCRP Report No. 160. There is no extensive study conducted on the large hospitals in Bangladesh following the In-Situ method. We used a real-time digital portable radiation monitor with Garmin eTrex Global Positioning System at 320 monitoring points for radiation monitoring and positioning around the ten largest hospitals in central & western Bangladesh from September to November 2021. The mean radiation dose rates around Bangabandhu Sheikh Mujib Medical University, Dhaka Medical College Hospital, Evercare Hospital, Khulna Medical College Hospital, Mitford Hospital, National Institute of Cancer Research Hospital, Popular Hospital, Rajshahi Medical College Hospital, Shaheed Suhrawardy Medical College Hospital, and Square Hospitals were measured as 0.145 ± 0.012 µSv/h, 0.135 ± 0.009 µSv/h, 0.148 ± 0.008 µSv/h, 0.139 ± 0.01 µSv/h, 0.133 ± 0.007 µSv/h, 0.153 ± 0.011 µSv/h, 0.144 ± 0.012 µSv/h, 0.137 ± 0.008 µSv/h, 0.145 ± 0.01 µSv/h, and 0.153 ± 0.009 µSv/h, respectively. The mean excess lifetime cancer risk (ELCR) of the public who lives nearby the hospital's boundary was estimated at 1.05 × 10-3, 0.983 × 10-3, 1.071 × 10-3, 1.004 × 10-3, 0.964 × 10-3, 1.084 × 10-3, 1.043 × 10-3,0.996 × 10-3, 1.051 × 10-3 & 1.112 × 10-3 respectively. ELCR in most of the locations around the ten largest hospitals in central & western Bangladesh is higher than the global average value. Radiation monitoring is significant for minimizing the public's radiation risk and keeping hospital environments as radiation-free as possible.
ABSTRACT
Tannery-effluent is one of the top-ranked hazardous waste which is generally discharged into the river. To study the fluvial response toward the tannery-effluents and to trace anthropogenic foot-prints in the fluvial-system, a suite of systematically collected sediment and water samples were analyzed for radioactive (226Ra, 232Th, and 40K) and non-radioactive elements (Al, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Cd, Sb, Hg, and Pb). Neutron activation analysis and atomic absorption spectroscopy were used for elemental analysis, whereas HPGe-gamma-detector was used for measuring the primordial-radionuclides. Ranges of Cr-abundances in sediment and water were 63-4373 µg.g-1 and 15.6-52.2 µg.L-1, respectively which were â¼4-14 times higher than the geological background. Radioactivity concentrations of 226Ra, 232Th, and 40K ranged from 17.7-48.5, 36.1-81.6, and 687-1041 Bq.kg-1, respectively which were significantly depleted in effluent discharge point. Hence, primordial-radionuclides were used as natural tracers for tracing anthropogenic foot-prints which were explained in terms of dilution effect, redox environment and differential geo-environmental events/characteristics. From statistical-approaches and geochemical reasoning, elemental sources and responses in fluvial system were explored. Surprisingly, ecological & radiological risks were reduced while sediment quality guideline-based ecotoxicity & water-mediated health risks were increased by the incorporation of tannery effluents. This study describes the sedimentary response toward the received tannery effluents which is particularly explored by the primordial radionuclides.
Subject(s)
Metals, Heavy , Water Pollutants, Chemical , Environmental Monitoring/methods , Rivers/chemistry , Water Pollutants, Chemical/analysis , Water/analysis , Radioisotopes/analysis , Metals, Heavy/analysis , Geologic Sediments/chemistryABSTRACT
This study was carried out on a negligible anthropogenically impacted Indo-Bangla transboundary river basin (Atrai, Bangladesh) to elicit radionuclides' and elemental distributions. Thirty sediment samples were collected from the Bangladesh portion of the river, and instrumental neutron activation analysis and HPGe γ-Spectrometry techniques were used to determine environmental radionuclides (e.g., 232Th, 226Ra, 40K) and associated elemental concentrations, respectively. Metal concentrations (Sc, V, Fe, Eu, Sm, La, Yb, Ce, Lu, Ta, Hf) were determined to comprehend the genesis of greater radioactivity. Recognizing the mean concentration of absorbed gamma dose rate (158.7 hGyh-1) is 2.88-times more than the recommended value (55 hGyh-1) that describes ionizing radiation concerns regarding potential health risks to the surrounding communities and the houses of native residents, which are constructed by Atrai river sediment. This work will assist relevant policymakers in exploring valuable heavy minerals and provide information regarding radiological health risks from a fluvial system.
Subject(s)
Radiation Exposure , Radioactivity , Metals/analysis , Rivers/chemistry , Radioisotopes/analysis , Radiation Exposure/analysis , Environmental MonitoringABSTRACT
This study utilized surface sediments from a potentially less polluted transboundary Himalayan River (Brahmaputra: China-India-Bangladesh) to investigate the abundance of 15 geochemically and ecologically significant elements and to predict their sources and ecological consequences. INAA was applied to determine the elemental concentrations. The average abundances (µg.g-1) of Rb (94.20), Cs (4.49), Th (20.31), & U (2.73) were 1.12-2.26 folds elevated than shale. Environmental indices disclosed a pollution status ranging from "uncontaminated to moderately contaminated," with minimal Rb, U, and Th enrichment in the downstream zone. Consensus-based sediment quality guideline (SQG) threshold values suggested that only Cr (60% samples > TEL) may impose rare biological effects. Ecological risk indices suggested "minor to no" possible eco-toxicological risks for the accounted elements (Cr, Co, Mn, Zn, Sb, & As). The positive matrix factorization (PMF) model predicated the predominance of geogenic or crustal contributions (â¼72.69%) for Al, K, Na, Ti, Co, Zn, Ba, Cs, As, Rb, Th, & U derived from elemental fractionations, mineral weathering, and bio-geo-chemical mobilization. The relative contributions of anthropogenic sources (â¼27.31%; such as the construction of roads, settlement expansion, litter disposal, municipal waste discharge, mining activities, agricultural encroachment, etc.) on elemental distribution were significantly lower. The abundance of Cr and Mn was mainly influenced by anthropogenic sources. This study demonstrated the effectiveness of utilizing geo-environmental guidelines and receptor models in discriminating the natural & anthropogenic origins of metals in the complex riverine sediments of a less anthropogenically affected river.